Trace element diagenesis in pyrite-rich sediments of the Achterwasser lagoon, SW Baltic Sea     

Florian Scholz  Thomas Neumann 《Marine Chemistry》2007,107(4):516-532

The early diagenesis of trace elements (V, Cr, Co, Cu, Zn, As, Cd, Ba, U) in anoxic sediments of the Achterwasser, a shallow lagoon in the non-tidal Oder estuary in the Baltic Sea, was investigated in the context of pyrite formation. The dissolved major redox parameters show a two-tier distribution with transient signals in the occasionally re-suspended fluid mud layer (FM) and a permanently established diagenetic sequence in the sediment below. Intense microbial respiration leads to rapid depletion of O₂ within the uppermost mm of the FM. The reduction zones of Mn, Fe and sulfate overlap in the FM and in the permanently anoxic sediment section which appears to be a typical feature of estuarine sediments, under low-sulfate conditions. Degrees of pyritization (DOP) range from 50% in the FM to remarkably high values > 90% at 50 cm depth. Pyrite formation at the sediment surface is attributed to the reaction of Fe-monosulfides with intermediate sulfur species via the polysulfide pathway. By contrast, intense pyritization in the permanently anoxic sediment below is attributed to mineral growth via adsorption of aqueous Fe-sulfide complexes onto pyrite crystals which had originally formed in the surface layer.The studied trace elements show differential behavior patterns which are closely coupled to the diagenetic processes described above: (i) Zn, Cu and Cd are liberated from organic matter in the thin oxic layer of the sediment and diffuse both upwards across the sediment/water boundary and downwards to be trapped as monosulfides, (ii) V, Cr, Co and As are released during reductive dissolution of Mn- and Fe-oxyhydroxides, (iii) U removal from pore water occurs concomitantly to Fe reduction in the FM and is attributed to reduction of U(VI) to U(IV), (iv) the Ba distribution is controlled by reductive dissolution of authigenic barite in the sulfate reduction zone coupled with upward diffusion and re-precipitation. The incorporation of trace elements into pyrite is most intense for Co, Mn and As, intermediate for Cu and Cr and little to negligible for U, Zn, Cd, V and Ba. The observed trend is largely in agreement with previous studies and may be explained with differing rates for ligand exchange. Slow and fast ligand exchange and thus precipitation kinetics are also displayed by downcore increasing (Mn, Cr, Co and As) or constantly low (Zn, Cu, Cd) pore water concentrations. The downward increasing degrees of trace metal pyritization (DTMP) for Co, Cu, Zn and As are, in analogy to pyrite growth, assigned to adsorption of sulfide complexes or As oxyanions onto preexisting pyrite minerals.  相似文献   

大别山地区石榴石橄榄岩的岩石学和地球化学     

韩宗珠 《中国海洋大学学报(自然科学版)》1989,(4)

本文首次对我国石榴石橄榄岩类岩石进行系统的岩石学和地球化学研究。通过对大别山地区两个不同类型岩体中的石榴石橄榄岩的岩石学、岩石化学、矿物化学和稀土元素地球化学研究,表明这类岩石属钙碱性系列超基性岩;与地幔成分相比,富集易熔元素,亏损难熔元素;利用矿物地质温压计估算其形成压力为2×10~9pa,成岩温度为600～700℃具有正铕异常和轻稀土元素富集特征 推测为地壳下部的超基性岩经深成变质而成。  相似文献   

柴达木盆地昆特依盐湖的地球化学演化与古气候变化   总被引：9，自引：1，他引：9  

韩凤清  黄麒  王克俊  王华安  原力 《海洋与湖沼》1995,26(5):502-508

１９９０年用铀系年代学及古地磁对昆特依盐湖沉积物进行年代测定，探讨该湖区地球化学演化与古气候变化关系。结果表明，该区最老的盐层形成于早更新世晚期（大于７３０ｋａ），大量的盐类沉积则始于３００ｋａ左右；盐湖沉积物中元素含量变化主要受古盐度、矿物、类质同象和吸附控制；沉积物水溶Ｆ／Ｃｌ比值与古盐度成反比关系；该湖２０００ｋａ以来的古环境演变：盐层形成于干冷、偏酸性的氧化环境，泥岩层形成于湿暖、偏碱性的  相似文献   

Relationship between biogeochemical features of biogenic elements and flocculation in the Changjiang Estuary   总被引：1，自引：3，他引：1  

Lin Yi''an  Tang Renyou  Li Yan  Dong Henglin  Guan Xuwei  Chen Yinzu 《海洋学报(英文版)》1995,14(2):225-234

ＲｅｌａｔｉｏｎｓｈｉｐｂｅｔｗｅｅｎｂｉｏｇｅｏｃｈｅｍｉｃａｌｆｅａｔｕｒｅｓｏｆｂｉｏｇｅｎｉｃｅｌｅｍｅｎｔｓａｎｄｆｌｏｃｃｕｌａｔｉｏｎｉｎｔｈｅＣｈａｎｇｊｉａｎｇＥｓｔｕａｒｙ￥ＬｉｎＹｉ＇ａｎ；ＴａｎｇＲｅｎｙｏｕ；ＬｉＹａｎ；Ｄｏ...  相似文献   

Reanalysis of the Atmospheric Flux of Nutrient Elements to the Southern Yellow Sea and the East China Sea     

万小芳吴增茂  常志清 《海洋通报(英文版)》2003,5(1):45-51

Based on the recent research results on dry and wet deposition of nutrient elements and sulphate,we estimate the atmospheric flux of nutrient elements and sulphate to the southern Yellow Sea and the East China Sea in each season.The results suggest that the concentrations of nutrient elements and sulphate in aerosol and precipitation show an apparent seasonal cycle with the maximum values in winter and the minimum values in summer.Depositions of nitrate and sulphate are dominated by wet deposition,while the deposition for phosphate is mainly dry deposition.Moreover,compared with the riverine inputs,the atmospheric deposition may be the main source of dissolved inorganic nutrients in the southern Yellow Sea and the East China Sea.  相似文献   

福建罗源湾海滩互花米草盐沼中18种金属元素的分布   总被引：13，自引：0，他引：13  

钦佩  谢民  仲崇信 《海洋科学》1989,13(6):23-27

本文对福建罗源湾可湖海滩互花米草盐沼中的18种金属进行了测试,结果表明,罗源湾可湖海滩的环境质量基本是好的,并探讨了开发利用互花米草的新途径。  相似文献   

长江生源要素的输出通量   总被引：6，自引：2，他引：6  

沈志良  古堂秀  谢肖勃 《海洋科学》1991,15(6):67-69

长江是太平洋西岸最大的河流,它源源不断地向东海输送大量物质,是舟山渔场的重要化学物质基础,不仅对长江口海区以至整个东海有举足轻重的影响,对太平洋的影响也是不可忽视的。本文报道颗粒有机碳(POC)、溶  相似文献   

Binogeochemical process of major elements in sinking particulate of Nansha coral reef lagoons,South     

Song Jinming 《海洋学报(英文版)》1997,16(4):557-562

Ｂｉｎｏｇｅｏｃｈｅｍｉｃａｌ　ｐｒｏｃｅｓｓ　ｏｆ　ｍａｊｏｒ　ｅｌｅｍｅｎｔｓ　ｉｎ　ｓｉｎｉｎｇ　ｐａｒｔｉｃｕｌａｔｅ　ｏｆ　Ｎａｎｓｈａ　ｃｏｒａｌ　ｒｅｅｆ　ｌａｇｏｏｎｓ，Ｓｏｕｔｈ　TXＢｉｎｏｇｅｏｃｈｅｍｉｃａｌｐｒｏｃｅｓｓｏｆｍ...  相似文献   

Nonlinear dynamic analysis of deep water risers     

V.Hachemi Safai 《Applied Ocean Research》1983,5(4):215-225

The paper presents a theoretical and numerical approach to the dynamical behaviour of risers in deep water which takes into account two types of nonlinearity; that due to viscous drag forces and that due to the large displacements of the riser when submitted to strong axial loads. As the second nonlinearity may have a significant influence upon the behaviour of risers in deep water, a method for automatically updating the structural geometry during the dynamic analysis is given. A computer programme has been written for this purpose.  相似文献   

刍论大连湾底质地化环境   总被引：6，自引：0，他引：6  

鲍永恩  马嘉蕊 《海洋科学》1990,(4)

本文根据1987年的调查资料,总结阐述了大连湾底质地化环境诸要素的分布规律及其特征,运用相关分析法,通过多元回归计算求得了诸要素之间的关系。经过综合因素分析,得出了大连湾氧化还原环境分区、还原环境的成因及发展趋势。  相似文献