He–Ar and Nd–Sr isotopic compositions of late Pleistocene felsic plutonic back arc basin rocks from Ulleungdo volcanic island, South Korea: Implications for the genesis of young plutonic rocks in a back arc basin     

Kyu Han Kim  Keisuke Nagao  Hirochika Sumino  Tsuyoshi Tanaka  Takamasa Hayashi  Toshio Nakamura  Jong Ik Lee 《Chemical Geology》2008,253(3-4):180-195

We report analyses of noble gases and Nd–Sr isotopes in mineral separates and whole rocks of late Pleistocene (< 0.2 Ma) monzonites from Ulleungdo, South Korea, a volcanic island within the back arc basin of the Japan island arc. A Rb–Sr mineral isochron age for the monzonites is 0.12 ± 0.01 Ma. K–Ar biotite ages from the same samples gave relatively concordant ages of 0.19 ± 0.01and 0.22 ± 0.01 Ma. ⁴⁰Ar/³⁹Ar yields a similar age of 0.29 ± 0.09 Ma. Geochemical characteristics of the felsic plutonic rocks, which are silica oversaturated alkali felsic rocks (av., 12.5 wt% in K₂O + Na₂O), are similar to those of 30 alkali volcanics from Ulleungdo in terms of concentrations of major, trace and REE elements. The initial Nd–Sr isotopic ratios of the monzonites (⁸⁷Sr/⁸⁶Sr = 0.70454–0.71264, ¹⁴³Nd/¹⁴⁴Nd = 0.512528–0.512577) are comparable with those of the alkali volcanics (⁸⁷Sr/⁸⁶Sr = 0.70466–0.70892, ¹⁴³Nd/¹⁴⁴Nd = 0.512521–0.512615) erupted in Stage 3 of Ulleungdo volcanism (0.24–0.47 Ma). The high initial ⁸⁷Sr/⁸⁶Sr values of the monzonites imply that seawater and crustally contaminated pre-existing trachytes may have been melted or assimilated during differentiation of the alkali basaltic magma.A mantle helium component (³He/⁴He ratio of up to 6.5 RA) associated with excess argon was found in the monzonites. Feldspar and biotite have preferentially lost helium during slow cooling at depth and/or during their transportation to the surface in a hot host magma. The source magma noble gas isotopic features are well preserved in fluid inclusions in hornblende, and indicate that the magma may be directly derived from subcontinental lithospheric mantle metasomatized by an ancient subduction process, or may have formed as a mixture of MORB-like mantle and crustal components. The radiometric ages, geochemical and Nd–Sr isotopic signatures of the Ulleungdo monzonites as well as the presence of mantle-derived helium and argon, suggests that these felsic plutonic rocks evolved from alkali basaltic magma that formed by partial melting of subcontinental lithospheric mantle beneath the back arc basin located along the active continental margin of the southeastern part of the Eurasian plate.  相似文献   

The double solid reactant method: II. An application to the shallow groundwaters of the Porto Plain,Vulcano Island (Italy)     

Matteo Lelli  Roberto Cioni  Luigi Marini 《Environmental Geology》2008,56(1):139-158

This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.

Luigi Marini (Corresponding author)Email:

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Experimental constraints on the effects of pressure and H2O on the fractional crystallization of high-Mg island arc basalt     

Morihisa Hamada  Toshitsugu Fujii 《Contributions to Mineralogy and Petrology》2008,155(6):767-790

H₂O-undersaturated melting experiments of synthesized basalt (SiO₂ = 50.7 wt.%, MgO = 8.3 wt.%, Mg# = 60) were conducted at fO₂ corresponding to NNO+1 and NNO−1 to clarify the effects of pressure (2–7 kbar) and H₂O on fractional crystallization in island arcs. H₂O content was ranged from nominally anhydrous to 4.4 wt.%. Differentiation trends, namely the liquid lines of descent, change sensitively according to pressure-H₂O relations. Tholeiitic differentiation trends are reproduced with H₂O ≤ ∼2 wt.% in primary magma. With such quantities of H₂O, fractional crystallization is controlled by olivine + plagioclase at 2 kbar. Increasing the pressure from 2 to ≥4 kbar induces early crystallization of orthopyroxene instead of olivine and therefore SiO₂ enrichment in the residual melts is suppressed. Increasing H₂O (≥ ∼2 wt.% in primary magma) stabilizes clinopyroxene relative to orthopyroxene and/or magnetite. Although the phase relations and proportions strongly depend on fO₂ and H₂O content, differentiation trends are always calc-alkaline.  相似文献   

Pressures of Crystallization of Icelandic Magmas   总被引：1，自引：0，他引：1  

Kelley  Daniel F.; Barton  Michael 《Journal of Petrology》2008,49(3):465-492

Iceland lies astride the Mid-Atlantic Ridge and was createdby seafloor spreading that began about 55 Ma. The crust is anomalouslythick (20–40 km), indicating higher melt productivityin the underlying mantle compared with normal ridge segmentsas a result of the presence of a mantle plume or upwelling centeredbeneath the northwestern edge of the Vatnajökull ice sheet.Seismic and volcanic activity is concentrated in 50 km wideneovolcanic or rift zones, which mark the subaerial Mid-AtlanticRidge, and in three flank zones. Geodetic and geophysical studiesprovide evidence for magma chambers located over a range ofdepths (1·5–21 km) in the crust, with shallow magmachambers beneath some volcanic centers (Katla, Grimsvötn,Eyjafjallajökull), and both shallow and deep chambers beneathothers (e.g. Krafla and Askja). We have compiled analyses ofbasalt glass with geochemical characteristics indicating crystallizationof ol–plag–cpx from 28 volcanic centers in the Western,Northern and Eastern rift zones as well as from the SouthernFlank Zone. Pressures of crystallization were calculated forthese glasses, and confirm that Icelandic magmas crystallizeover a wide range of pressures (0·001 to 1 GPa), equivalentto depths of 0–35 km. This range partly reflects crystallizationof melts en route to the surface, probably in dikes and conduits,after they leave intracrustal chambers. We find no evidencefor a shallow chamber beneath Katla, which probably indicatesthat the shallow chamber identified in other studies containssilica-rich magma rather than basalt. There is reasonably goodcorrelation between the depths of deep chambers (> 17 km)and geophysical estimates of Moho depth, indicating that magmaponds at the crust–mantle boundary. Shallow chambers (<7·1 km) are located in the upper crust, and probablyform at a level of neutral buoyancy. There are also discretechambers at intermediate depths (11 km beneath the rift zones),and there is strong evidence for cooling and crystallizing magmabodies or pockets throughout the middle and lower crust thatmight resemble a crystal mush. The results suggest that themiddle and lower crust is relatively hot and porous. It is suggestedthat crustal accretion occurs over a range of depths similarto those in recent models for accretionary processes at mid-oceanridges. The presence of multiple stacked chambers and hot, porouscrust suggests that magma evolution is complex and involvespolybaric crystallization, magma mixing, and assimilation. KEY WORDS: Iceland rift zones; cotectic crystallization; pressure; depth; magma chamber; volcanic glass  相似文献   

Geochronology of Pliocene volcanism in the Dzhavakheti Highland (the Lesser Caucasus). Part 1: Western part of the Dzhavakheti Highland     

V. A. Lebedev  S. N. Bubnov  O. Z. Dudauri  G. T. Vashakidze 《Stratigraphy and Geological Correlation》2008,16(2):204-224

Isotopic-geochronological study of the Pliocene magmatic activity in western part of the Dzhavakheti Highland (northwestern region of the Lesser Caucasus) is carried out. The results obtained imply that the Pliocene magmatic activity lasted in this part of the highland approximately 2 million years from 3.75 to 1.75–1.55 Ma. As is established, the studied volcanic rocks correspond in composition mostly to K-Na subalkaline and more abundant normal basalts. Time constraints of main phases in development of basic volcanism within the study region are figured out. We assume that individual pulses of silicic to moderately silicic volcanism presumably took place in the Dzhavakheti Highland about 3.2 and 2.5 Ma ago.  相似文献   

西藏冈底斯带措勤地区则弄群火山岩锆石U-Pb年代学格架及构造意义   总被引：29，自引：12，他引：17  

朱弟成  周肃  莫宣学  赵志丹  许继峰  周长勇  孙晨光  王立全  陈海红  董国臣 《岩石学报》2008,24(3)

大规模的则弄群火山岩呈带状近东西向展布于西藏冈底斯带中北部地区.对出露状况较好的措勤地区则弄群火山岩进行了锆石U-Pb定年,以建立其年代学格架便于区域对比.措勤地区则弄群火山岩多数锆石具有生长振荡环带,部分锆石显示核边结构.在措勤达雄北西部上覆于中二叠统下拉组灰岩的1件则弄群英安岩样品的LA-ICP-MS锆石U-Ph年龄为130±1Ma,1件则弄群流纹岩样品的SHRIMP锆石U-Pb年龄为129±3Ma;在措勤达雄北东部与下白垩统多尼组碎屑岩呈断层接触的1件则弄群英安岩样品中的锆石具有两组LA-ICP-MS锆石U-Pb年龄,最年轻的一组(包括增生边)为121±1Ma,较老的一组(包括核部)为131±1Ma;在措勤南西部1件则异群流纹岩样品的LA-ICP-MS锆石U-Pb年龄为111±1Ma,与措勤地区花岗岩类的侵位时代相当.这些高质量的锆石U-Pb年代学数据表明,措勤地区的则弄群火山作用很可能开始于约130Ma,停息于约110Ma,持续时间约20Ma.区域对比表明,东西延伸约1000km的则弄群火山作用同时发生在约130Ma.区域上目前的年代学数据结合同时代岩浆作用的分布特征表明,冈底斯带中北部地区早白垩世岩浆作用不太可能由新特提斯洋壳向北的低角度或平板俯冲产生.  相似文献   

东天山黄山-镜儿泉过铝花岗岩矿物学、地球化学及年代学研究   总被引：3，自引：0，他引：3  

唐俊华  顾连兴  张遵忠  吴昌志  三金柱  汪传胜  刘四海  黎广荣 《岩石学报》2008,24(5):921-946

对东天山黄山-镜儿泉一带黄山南、镜儿泉、图拉尔根沟三个过铝花岗岩作了岩相学、矿物学、地球化学、sr-Nd同位素和锆石U-Pb年代学研究.锆石U-Pb LA-ICP-MS原位定年测得黄山南岩体结晶年龄为259.9±1.4Ma(MSWD=0.86),图拉尔根沟岩体结晶年龄为275.4±8.3Ma(MSWD=29),均侵位于二叠纪碰撞后伸展环境.三个过铝花岗岩均具有低锶同位素初始比值(Isr=0.6969～0.70396)、高εNd(t)值( 5.5～ 7.2)以及年轻的亏损地幔单阶段模式年龄(tDM=0.48～0.56Ga),表明其岩浆源区均为来源于亏损地幔的新生地壳岩石.这种新生地壳岩石可能为偏酸性的火山岩.三个岩体的矿物学和地球化学可分为两类:一类以黄山南白云母花岗岩为代表,为强过铝花岗岩(A/CNK>1.1),强烈亏损Ba、sr和Ti而富集Cs、Rb和K,具有高的Rb/sr(2.03～14.5)和Al2O3/TiO2(110～1592),低的Nb/Ta(3.24～6.76)比值,其稀土元素配分曲线呈"V"字形,显示强烈铕亏损(Eu/Eu*=0.04～0.55),表明这类岩体的直接源岩以泥质岩为主.另一类以图拉尔根沟二云母花岗岩为代表,为弱过铝(1相似文献   

河南桐柏老湾花岗岩体锆石SHRIMP U-Pb年龄及其地质意义   总被引：5，自引：0，他引：5  

刘翼飞  江思宏  方东会  刘妍 《岩石矿物学杂志》2008,27(6):519-523

通过对河南桐柏老湾花岗岩体开展锆石SHRIMP U-Pb测年,获得了一个高精度的U-Pb年龄(132.5±2.4)Ma,比较可靠地限定了老湾花岗岩体的形成时代属于燕山中期,而不是前人所认为的燕山晚期.结合区域构造-岩浆活动时间,认为在燕山中期,桐柏及其邻区存在次比较重要的构造-岩浆事件,老湾花岗岩体是这次构造-岩浆活动事件的产物.  相似文献   

试论雁荡山岩石地貌     

陶奎元  沈加林  姜杨  余明刚 《岩石学报》2008,24(11):2647-2656

雁荡山岩石地貌由叠嶂、方山、石门、柱峰、锐峰、岩洞、天生桥和峡谷、涧溪、瀑、潭、湖等岩石地貌组合而成。其形成的地质学、岩石学基础是白垩破火山岩相与构造。不同类型地貌景观反映了这一破火山构造。断裂切割、重力崩塌与流水侵蚀是形成此类地貌的主要外动力地质作用。雁荡山岩石地貌在形态、成因和审美学意义上均有别于我国砂砾岩岩石地貌、碳酸岩岩石地貌和花岗岩岩石地貌。雁荡山地貌可作为流纹质火山岩地貌的代表。  相似文献   

拉萨地体东南缘的多期深熔作用及动力学   总被引：13，自引：7，他引：6  

王金丽  张泽明  石超 《岩石学报》2008,24(7)

位于青藏高原班公湖-怒江蛇绿岩带与印度-雅鲁藏布江蛇绿岩带之间拉萨地体东南缘的前寒武纪结晶基底经历了角闪岩相-麻粒岩相区域变质作用和强烈的混合岩化.研究区可识别出两期深熔作用,第一期为斜长角闪岩部分熔融形成的花岗闪长岩脉体,其与围岩一起发生了变质与变形再造,转变成了黑云斜长片麻岩.第二期为含夕线石石榴石片麻岩部分熔融形成的含石榴石斜长石花岗岩脉体.岩石化学成分显示,第一期深熔脉体具有埃达克岩的典型地球化学特征,其SiO2=63.81%,Al2O3=16,92%,MgO=1.86%,Na2O=4.22%,K2O=1.81%,K2O/Na2O=0.43,并显示出LREE富集、无Eu异常的BEE配分模型,同时明显富Sr(366×10-6),贫Y(12×10-6)和Yb(0.4×10-6),Sr/Y=30.舍石榴石斜长石花岗岩主要由斜长石、石英和石榴石组成,含少量白云母和黑云母,其全岩SiO2=71.14%,Al2O3=14.26%,K2O=0.26%,Na2O=2.79%.CaO=2.94%.过铝指数A/CNK=1.40,为典型的过铝花岗岩.黑云斜长片麻岩脉体中的大多数锆石具有同心韵律状结晶环带和较高的Th//U比值(0.433～1.167),为典型的岩浆结晶锆石.锆石岩浆结晶域U-Pb原位定年给出了64.0±1.0Ma(MSWD=8.7)加权平均年龄;个别锆石变质交生边给出了27.9 Ma的谐和年龄,同时具有较低的Th/U比值(0.019),应代表后期叠加的变质热事件年龄.含石榴石斜长石花岗岩中的锆石均发育同心韵律状环带,而且具有较高的Th/U比值(0.196～1.212).所获得的谐和年龄在27.0～34.1Ma之间(加权平均年龄为29.3±0.9 Ma),应代表过铝花岗岩的结晶年龄.因此,我们认为拉萨地体东南缘变质基底在古近纪经历了两期深熔作用,第一期发生在约65Ma,在特提斯洋壳俯冲和印度板块与拉萨地体碰撞的动力学体制下,拉萨地体下地壳加厚和升温,发生了麻粒岩相变质和部分熔融,形成了埃达克岩质的花岗闪长岩浆;第二期混合岩化作用发生在约30Ma,在印度板块与拉萨地体碰撞后伸展的动力学体制下,高角闪岩相泥质变质岩中的含水矿物脱水熔融形成了过铝质花岗闪长岩浆.  相似文献