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21.
This work deals with disposal of slurries generated during the cutting and polishing processes of slabs of decorative sedimentary
carbonate rocks in the north western Sicily. At present, they are used as fillers of dismantled quarries near the sawmills
and, as a final step of reclamation, are covered with earth layers. In spite of such inexpensive solution, there is lack of
knowledge about the composition of the waste. In order to assess if there is any threat for the environment and to suggest
indications for alternative solutions, such as recycling or inactivation processes, the slurries were analysed by XR diffraction,
simultaneous thermal analysis, ICP/MS, ionic chromatography, FTIR, UV-Vis, COD and TOC measurements, grain size analysis.
Results indicate that the slurries can threaten the groundwater, because of the high chemical oxygen demand; furthermore they
can modify the mechanism of groundwater recharge, because of their grain size distribution. Some laboratory tests show that,
even in very aggressive conditions, the solid pollutants persist in the waste and slowly release into water the products of
their degradation. The slurry therefore should be subjected to inactivation treatment before disposal or, alternatively, recycled
as secondary raw material for a suitable process. 相似文献
22.
R. K. Prasad N. C. Mondal Pallavi Banerjee M. V. Nandakumar V. S. Singh 《Environmental Geology》2008,55(3):467-475
Remote Sensing and Geographic Information System has become one of the leading tools in the field of hydrogeological science,
which helps in assessing, monitoring and conserving groundwater resources. It allows manipulation and analysis of individual
layer of spatial data. It is used for analysing and modelling the interrelationship between the layers. This paper mainly
deals with the integrated approach of Remote Sensing and geographical information system (GIS) to delineate groundwater potential
zones in hard rock terrain. The remotely sensed data at the scale of 1:50,000 and topographical information from available
maps, have been used for the preparation of ground water prospective map by integrating geology, geomorphology, slope, drainage-density
and lineaments map of the study area. Further, the data on yield of aquifer, as observed from existing bore wells in the area,
has been used to validate the groundwater potential map. The final result depicts the favourable prospective zones in the
study area and can be helpful in better planning and management of groundwater resources especially in hard rock terrains. 相似文献
23.
This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental
Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software
package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters
of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was
performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e.,
without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic
glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites,
fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and
a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements
(Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations,
similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis
which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to
the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture
of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger
of Sr and Ba is emphasized.
相似文献
Luigi Marini (Corresponding author)Email: |
24.
Unconsolidated sand, gravel and clay deposits near Beihai and in the Leizhou Peninsula in southern China form an unconfined
aquifer, aquitard and a confined aquifer. Water and soil samples were collected from the two aquifers in the coastal Beihai
area for the determination of chemical compositions, minerals and soluble ions. Hydrogeochemical modeling of three flow paths
through the aquitard are carried out using PHREEQC to determine water–rock interactions along the flow paths. The results
indicate that the dissolution of anorthite, fluorite, halite, rhodochrosite and CO2, and precipitation of potash feldspar and kaolinite may be occurring when groundwater leaks through the aquitard from the
unconfined aquifer to the confined aquifer. Cation exchanges between Na and Ca can also happen along the flow paths. 相似文献
25.
Helmut Kerndorff Stephan Kühn Thomas Minden Dagmar Orlikowski Thomas Struppe 《Environmental Geology》2008,55(2):291-301
The aim of this research project is to identify, characterize and quantify natural attenuation (NA) processes in groundwater
affected by emissions of abandoned waste disposal sites in Berlin-Kladow/Gatow, Germany. It is part of the funding priority
called KORA established by the Federal Ministry for Education and Research (BMBF) to explore the extent to which NA can be
used for remedial purposes for varied forms of soil and groundwater contamination. Information on the emission behaviour of
individual parameters is generated on the basis of hydrogeochemical comparison of 20 years old and new data. Using groundwater-modelling
and CFC-analysis, information on the transport and retention of pollutants in groundwater is compiled. The microbial colonization
of contaminated aquifers is characterized by molecular biological methods [polymerase chain reaction (PCR) and denaturing
gradient gel electrophoresis (DGGE)] to differentiate between contaminated and not contaminated zones. 相似文献
26.
Shear strength characterization of municipal solid waste at the Suzhou landfill, China 总被引:5,自引:0,他引:5
The current practice of slope stability analysis for a municipal solid waste (MSW) landfill usually overlooks the dependence of waste properties on the fill age or embedment depth. Changes in shear strength of MSW as a function of fill age were investigated by performing field and laboratory studies on the Suzhou landfill in China. The field study included sampling from five boreholes advanced to the bottom of the landfill, cone penetration tests and monitoring of pore fluid pressures. Twenty-six borehole samples representative of different fill ages (0 to 13 years) were used to perform drained triaxial compression tests. The field and laboratory study showed that the waste body in the landfill can be sub-divided into several strata corresponding to different ranges of fill age. Each of the waste strata has individual composition and shear strength characteristics. The triaxial test results showed that the MSW samples exhibited a strain-hardening and contractive behavior. As the fill age of the waste increased from 1.7 years to 11 years, the cohesion mobilized at a strain level of 10% was found to decrease from 23.3 kPa to 0 kPa, and the mobilized friction angle at the same strain level increasing from 9.9° to 26°. For a confinement stress level greater than 50 kPa, the shear strength of the recently-placed MSW seemed to be lower than that of the older MSW. This behavior was consistent with the cone penetration test results. The field measurement of pore pressures revealed a perched leachate mound above an intermediate cover of soils and a substantial leachate mound near the bottom of the landfill. The measurements of shear strength properties and pore pressures were utilized to assess the slope stability of the Suzhou landfill. 相似文献
27.
G. Diego Gatta Nicola Rotiroti Martin Fisch Milen Kadiyski Thomas Armbruster 《Physics and Chemistry of Minerals》2008,35(9):521-533
The elastic and structural behaviour of the synthetic zeolite CsAlSi5O12 (a = 16.753(4), b = 13.797(3) and c = 5.0235(17) Å, space group Ama2, Z = 2) were investigated up to 8.5 GPa by in situ single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions. No phase-transition occurs within the P-range investigated. Fitting the volume data with a third-order Birch–Murnaghan equation-of-state gives: V 0 = 1,155(4) Å3, K T0 = 20(1) GPa and K′ = 6.5(7). The “axial moduli” were calculated with a third-order “linearized” BM-EoS, substituting the cube of the individual lattice parameter (a 3, b 3, c 3) for the volume. The refined axial-EoS parameters are: a 0 = 16.701(44) Å, K T0a = 14(2) GPa (βa = 0.024(3) GPa?1), K′ a = 6.2(8) for the a-axis; b 0 = 13.778(20) Å, K T0b = 21(3) GPa (βb = 0.016(2) GPa?1), K′ b = 10(2) for the b-axis; c 0 = 5.018(7) Å, K T0c = 33(3) GPa (βc = 0.010(1) GPa?1), K′ c = 3.2(8) for the c-axis (K T0a:K T0b:K T0c = 1:1.50:2.36). The HP-crystal structure evolution was studied on the basis of several structural refinements at different pressures: 0.0001 GPa (with crystal in DAC without any pressure medium), 1.58(3), 1.75(4), 1.94(6), 3.25(4), 4.69(5), 7.36(6), 8.45(5) and 0.0001 GPa (after decompression). The main deformation mechanisms at high-pressure are basically driven by tetrahedral tilting, the tetrahedra behaving as rigid-units. A change in the compressional mechanisms was observed at P ≤ 2 GPa. The P-induced structural rearrangement up to 8.5 GPa is completely reversible. The high thermo-elastic stability of CsAlSi5O12, the immobility of Cs at HT/HP-conditions, the preservation of crystallinity at least up to 8.5 GPa and 1,000°C in elastic regime and the extremely low leaching rate of Cs from CsAlSi5O12 allow to consider this open-framework silicate as functional material potentially usable for fixation and deposition of Cs radioisotopes. 相似文献
28.
断层对盖层的破坏主要表现为两个方面:一是减小了盖层的连续封盖面积,二是减小了盖层的厚度。盖层被断层破坏的主要影响因素有断层的断距、倾角和盖层厚度。通过对影响因素研究,提出了盖层有效断接厚度的新概念和计算方法。根据我国部分与断层有关的大-中型气田气柱高度资料,发现了有效断接厚度与所能封闭的最大气柱高度的对数线性关系,并由此提出了评价被断层破坏的盖层封闭能力的新方法。通过对库车坳陷库姆格列木群膏泥岩盖层的应用研究,所得结论与勘探实践完全吻合,证明所提出的评价方法是可行的。 相似文献
29.
对华南前寒武系变质岩浆杂岩稀有气体He、Ne、Ar和Xe的系统研究表明:扬子克拉通基底为含高3He的下地壳"原始岩石层",(3He/4He)×10-6比值为2.8~4.6;而华夏板块基底变质岩浆杂岩则是在缺乏3He、低(3He/4He)×10-8比值(3.15~17.7)的构造环境下形成的大陆中-上地壳变质岩浆杂岩层,反映出两者基底性质迥然不同。华南中-新生代爆破岩筒He同位素组成相反,相对稳定的扬子克拉通(3He/4He)×10-8比值仅0.18~4.22,而郯庐-四会-吴川断裂以东,中-新生代活动地块(太平洋构造域)(3He/4He)×10-8比值高达3.7~20.5。He同位素表明郯庐-四会-吴川断裂带为切割深至地幔的边界深大断裂,是扬子克拉通与华夏板块间的边界且控制了燕山期火山-侵入岩浆向西扩展。Ar同位素组成表明华南大陆中-新生代地幔形成接近"均一"的地幔组份。136Xe/130Xe-129Xe/130Xe相关组份表明它们具有地幔柱岩石同位素组成特征。 相似文献
30.