化学发光分析法测定铁的进展     

王莉平  李绍卿 《地球科学与环境学报》2000,22(3):73-77

综述了化学发光分析测定铁的进展 ,叙述了化学发光法测定铁的基本原理、所用的化学发光试剂、影响因素及测定方法。初步探讨了铁的化学发光机理。  相似文献   

Monitoring active open-pit mine stability in the Rhenish coalfields of Germany using a coherence-based SBAS method     

《International Journal of Applied Earth Observation and Geoinformation》2020

With the recent progress in synthetic aperture radar (SAR) technology, especially the new generation of SAR satellites (Sentinel-1 and TerraSAR-X), our ability to assess slope stability in open-pit mines has significantly improved. The main objective of this work is to map ground displacement and slope instability over three open-pit mines, namely, Hambach, Garzweiler and Inden, in the Rhenish coalfields of Germany to provide long-term monitoring solutions for open-pit mining operations and their surroundings. Three SAR datasets, including Sentinel-1A data in ascending and descending orbits and TerraSAR-X data in a descending orbit, were processed by a modified small baseline subset (SBAS) algorithm, called coherence-based SBAS, to retrieve ground displacement related to the three open-pit mines and their surroundings. Despite the continuously changing topography over these active open-pit mines, the small perpendicular baselines of both Sentinel-1A and TerraSAR-X data were not affected by DEM errors and hence could yield accurate estimates of surface displacement. Significant land subsidence was observed over reclaimed areas, with rates exceeding 500 mm/yr, 380 mm/yr, and 310 mm/yr for the Hambach, Garzweiler and Inden mine, respectively. The compaction process of waste materials is the main contributor to land subsidence. Land uplift was found over the areas near the active working parts of the mines, which was probably due to excavation activities. Horizontal displacement retrieved from the combination of ascending and descending data was analysed, revealing an eastward movement with a maximum rate of ∼120 mm/yr on the western flank and a westward movement with a maximum rate of ∼ 60 mm/yr on the eastern flank of the pit. Former open-pit mines Fortuna-Garsdorf and Berghein in the eastern part of Rhenish coalfields, already reclaimed for agriculture, also show subsidence, at locations reaching 150 mm/yr. The interferometric results were compared, whenever possible, with groundwater information to analyse the possible reasons for ground deformation over the mines and their surroundings.  相似文献   

地质样品中硫化物形式铁的分离和测定   总被引：1，自引：0，他引：1  

周佳琦  胡超涌  马仲武  谢树成 《海洋地质与第四纪地质》2010,(2)

提出一个利用次氯酸钠氧化铁硫化物碱性磺基水杨酸提取并直接测定碳酸盐相中铁硫化物的方法。结果表明,30%的NaClO溶液浸泡样品40h以上,可以完全释放铁硫化物并形成氢氧化铁胶体。0.1g/mL的碱性磺基水杨酸溶液则较容易地溶解新生成的氢氧化铁胶体,形成黄色的铁-磺基水杨酸络合物,可被分光光度法定量测定。该方法集选择性分离、富集和测定于一体,分析流程简单,结果可靠,适合地质样品中硫化物形式铁的测定。  相似文献   

Timing of mineralization and deformation,Peak Au mine,Cobar, New South Wales∗     

C. Perkins  M. C. Hinman  J. L. Walshe 《Australian Journal of Earth Sciences》2013,60(5):509-522

The ⁴⁰Ar/³⁹Ar dating of alteration muscovite from the Peak Au mine in the Early Devonian Cobar Basin, New South Wales, has distinguished two major episodes of mineralization. Veined (Pb‐Zn‐Cu‐Au) mineralization was broadly synchronous with cleavage formation during the post‐inversion, shortening deformation of the basin sedimentary rocks, and replacive Ag‐Pb‐Zn mineralization significantly postdates the latter event. Veined base metals (Pb‐Zn‐Cu) and Au associated with silicification were coeval with three stages of cleavage formation (D₁, D₂ and D₃) after basin inversion. The Cu‐Au phase of mineralization at the Peak Au mine which was broadly contemporaneous with the culmination of the cleavage‐forming events (D₃) and with the local development of high‐strain zones occurred at 401.5 ± 1.0 Ma (⁴⁰Ar/³⁹Ar on muscovite). This date is essentially coeval with known fossil constraints on the age of basin formation, and indicates that basin inversion and deformation rapidly followed sedimentation. In contrast, replacive Ag‐Pb‐Zn mineralization occurred at 384.0 ± 1.4 Ma (⁴⁰Ar/³⁹Ar on muscovite) during an extended period of relaxation characterized by normal faulting (D₄) which followed the shortening deformation. This mineralization was associated with desilicification and chlorite‐muscovite replacement assemblages which cross‐cut the cleavages, and which may have been broadly contemporaneous with the deposition of part of the Mulga Downs Group which unconformably overlies the Cobar Supergroup. Rhyolite exposed in the core of the Peak Au mine largely contains inherited zircons that range in age from ～430–1500 Ma. A few euhedral zircons have an age of ～430 Ma and this is interpreted as a maximum date for the rock. Zircons from a syn‐D₃ chlorite‐muscovite replacement zone within the deposit have ²⁰⁶Pb/²³⁸U ages of ～410–650 Ma and are apparently inherited.  相似文献   

中国航磁异常特征与铁矿床空间分布关系     

杨海  熊盛青  杨雪  范正国  李芳  贾志业  刘前坤 《矿床地质》2022,41(5):893-916

中国航磁调查已基本覆盖全国,尤其是近二十年来开展了大面积1∶5万高精度航磁调查,为铁矿的成矿规律研究及找矿预测提供了重要的基础数据。文章基于全国航磁编图（1∶100万）和大比例尺（≥1∶5万）航磁数据集,开展区域、矿集区、矿床3个不同尺度的研究,旨在总结4种主要类型铁矿在区域和局部磁场上的响应模式,指导找矿应用。研究表明,不同类型的铁矿在区域磁场上呈现出不同的特征,沉积变质型铁矿主要位于条带状磁异常边部负背景场中的局部高磁异常,岩浆型铁矿主要位于线性磁异常带,接触交代-热液型铁矿（矽卡岩型）主要沿带状或等轴状磁异常边缘分布,火山岩型铁矿通常沿带状磁异常分布。不同的区域磁异常特征通常反映了特定的控矿要素,主要刻画了火山-沉积建造、基性-超基性杂岩、中酸性侵入岩、火山岩由浅部至深部的分布特征,为成矿地质背景研究提供了大量深部信息。岩浆活动强烈的构造带,会导致地壳内基底隆起和较高的地温梯度,呈现出磁性基岩深度和居里面深度较浅的特征,有利于铁矿物的富集成矿。大比例尺航磁资料（≥1∶5万）大都能够直接反映矿体或含矿地质体的特征,磁异常都对应了铁矿体或矿化的中心,但矿体的规模、产状、埋深、品位等特征的变化都会造成磁异常幅值、形状、大小的变化,通过约束条件下2D和3D正反演计算获得深部矿体或含矿地质体的特征,对找矿勘查最具指导意义。概括来讲,中小比例尺航磁资料主要用于成矿地质背景研究,分析成矿控矿要素,达到区域成矿预测的目的。大比例尺航磁资料可用于隐伏矿体或含矿地质体预测,建立深部矿体或含矿地质体二维或三维模型,指导勘探工作。  相似文献   

矿山灾害应急救援生命保障孔钻井工艺研究          下载免费PDF全文

周兢 《探矿工程》2022,49(1):128-134

近年来国内外开展的救援钻孔实践推动了矿山和地下工程应急救援技术的发展,探索出的“小直径生命保障孔+大直径救生孔”模式是进行矿山和地下工程灾害救援的一种有效途径。本文以矿山灾害救援地面生命保障孔钻井工艺为主线,分析了小直径生命保障孔井身结构设计和套管选用方法;分别介绍了泥浆正循环钻进工艺和空气潜孔锤正循环钻进工艺,并以山东栖霞笏山金矿生命救援孔钻进实例分析了当前生命保障孔钻井工艺难点。依据轨迹设计理论,针对笏山金矿救援3号生命保障孔出现的偏斜问题,创新提出了超短距离螺旋纠偏技术,并取得了良好的应用效果,为后续生命保障孔施工积累了宝贵经验。  相似文献   

缅甸抹谷Baw-mar矿区蓝宝石的热处理及谱学研究     

陈思明  谭红琳  祖恩东  申南玉 《岩石矿物学杂志》2022,41(4):857-864

目前缅甸抹谷矿区开采的蓝宝石原石约80%都要经过优化处理才能投入市场,其中主要为热处理。本文对缅甸抹谷Baw-mar矿区蓝宝石进行不同温度制度的热处理,并利用电子探针、X射线粉晶衍射仪(XRD)、紫外-可见-近红外光谱仪、傅里叶红外光谱仪和激光拉曼光谱仪对其热处理前后的谱学特征进行了对比研究。结果表明,1 300℃热处理后所有样品2θ<60°的XRD衍射峰开始向低角度方向偏移,晶胞参数c/a值随热处理温度升高而降低,推测与其晶体结构在高温下发生畸变有关;Baw-mar矿区蓝宝石的主要致色元素是Fe、Ti和V,其中Fe和Ti共同导致其呈蓝色,V使其略带绿色调,部分样品的灰色调主要由Ni所致;热处理后样品中Fe²⁺-Ti⁴⁺荷移增强,Fe²⁺-Fe³⁺荷移减弱,导致585 nm紫外吸收带增强,746和764 nm吸收峰减弱,同时样品颜色变蓝且灰色调减弱;红外光谱中,样品出现1 988、2 123 cm^-1硬水铝石羟基倍频振动吸收峰和3 619、3 696 cm^-1<...  相似文献   

淋溶时间对红黏土物理力学特性的影响     

张文博  柏巍  孔令伟  樊恒辉  岳秀 《岩土力学》2022,(2)

以湖北省鄂州市庙岭镇的红黏土为研究对象,以化学选择溶解法结合淋溶作用为处理手段,将原状土样中的游离氧化铁按梯度去除,获得连二亚硫酸钠-柠檬酸钠-碳酸氢钠(DCB)溶液淋溶时间与除铁率的关系,并分析了不同淋溶时间对红黏土物理力学特性及微观孔隙结构的影响。试验结果表明,DCB溶液淋溶时间与除铁率相关性较强,除铁率与时间呈先快速增长后逐渐稳定的关系。由于游离氧化铁在土颗粒间主要起胶结作用,故淋溶时间对红黏土的物理力学特性有较大影响。随着淋溶时间的增长,黏粒与胶粒含量逐渐增大,耐热性小幅提升,无侧限抗压强度显著减小,且无侧限抗压强度变化整体趋势为前期急剧降低至后期趋于平稳。核磁共振、差热分析和电镜扫描的结果表明,随着淋溶时间的增大,庙岭红黏土内部孔隙增大,自由水减少,结合水增多,微观形态上团粒结构遭到破坏,胶结物质明显减少,结构形式从紧凑的粒团堆叠结构逐渐转化为聚集体-松散颗粒状结构。  相似文献   

基于FLO-2D的矿山泥石流运动特征及危险性评价——以甘肃省岷县簸箕沟矿山泥石流为例     

刘德玉  蒋兴波  李保强 《地质与资源》2022,31(5):693-699

岷县簸箕沟金矿因人类开采活动引发了矿山泥石流灾害. 采用FLO-2D软件模拟分析了降雨强度重现期50 a及100 a条件下的簸箕沟泥石流运动特征, 进行危险性评价和分区, 并结合实际发生情况做了精度验证. 结果表明: 簸箕沟泥石流的堆积扇范围、堆积深度以及平均流速等运动特征参数随着降雨重现周期的变长而增大, 堆积扇中部的堆积深度及流速明显大于两翼及前端. 泥石流的危险区集中分布于泥石流沟道以及沟口一定范围内. 随着降雨重现周期的变长, 高危险区面积比例由48%升高至54.0%. 通过精度验证得出模拟结果与实际情况基本相符, 可信度较高.  相似文献   

基于瞬变电磁法的陇东煤矿采空区水文地质勘探技术研究     

杨华奎 《地质与勘探》2023,59(4):883-890

煤矿开采会破坏地层地质结构,造成采空区地表断裂、下沉塌陷等危害。为避免这一问题,需准确探测煤矿采空区水文地质,为此提出基于瞬变电磁法的煤矿采空区水文地质勘探技术。该方法以甘肃省陇东煤矿采空区水文地质为主,分别分析了甘肃省煤矿采空区的地形地貌、地层岩性、水文地质特征,根据分析结果估算瞬变电磁法在水文地质勘探时的最大勘探深度,确定瞬变电磁法的工作参数。依据勘探结果确定煤矿采空区水文地质的异常范围,以此实现煤矿采空区水文地质勘探研究。在实际应用中有效探测出了地层塌陷位置发生高阻半闭合异常现象,且除高压线外煤矿采空区其余位置的干扰电压较小。  相似文献