核废物处置试验场环境地质研究综述   总被引：1，自引：0，他引：1  

李国敏 《地质科技情报》1994,13(4):52-58

介绍了国外核废物处理试验场有关环境地质研究现状与进展。据核废物的放射性不同，目前或未来处置的方式不一样：中－低放射性废物（ＩＬＷ－ＬＬＷ）一般采用浅层处置，多置于粘土层或沉积岩层中；高放射性废物（ＨＬＷ）一般通过竖井或平巷处置于深部的花岗岩或岩盐中。根据母岩的类别不同，本文分花岗岩、岩盐、粘土及其它四部分，对不同的试验场的研究计划、内容、方法、进展等进行了评述。  相似文献   

秦岭泥盆系层控铅锌矿床成因模式探讨     

黄书俊  曾永超 《矿产与地质》1991,(3)

在论述秦岭泥盆系层控铅锌矿床的黄铁矿微量元素,硫、铅、氢、氧同位素,矿物气液包裹体均一温度及成分.区域地层元素丰度等方面特征的基础上,提出了该类型属海底含矿热泉溢出沉积和隐伏含矿热泉贯入沉淀的成因模式.  相似文献   

Crystal structure refinement of hendricksite,A Zn- and Mn-rich trioctahedral potassium mica: A contribution to the crystal chemistry of zinc-bearing minerals     

Dr. J. -L. Robert  Dr. M. Gaspérin 《Mineralogy and Petrology》1985,34(1):1-14

Summary The crystal structure of hendricksite, a trioctahedral mica of biotite type, characterized by high Zn²⁺ and Mn²⁺ contents has been refined by least square methods. The structural formula is: (K_0.89Na_0.10Ba_0.04)(Mg_1.57Zn_0.54Mn _0.40 ²⁺ Fe _0.25 ²⁺ Al_0.07Ti_0.07Cr_0.01)(Si_2.92Al_1.08)O₁₀ (OH)₂. The space group isC2/m and the cell parameters are:a=5.340(2) Å,b=9.524(2) Å,c=10.235(3) Å, =100.07(2)^o, the cell volume isV=497.98 ų. The final unweightedR=0.072. Average cation-anion distances in polyhedra are: T–O=1.659 Å, M(1)–O=2.093 Å, M(2)–O=2.088 Å, A–O_long=3.316 Å and A–O_short=3.004 Å; A is the alkaline cation. The rotation angle of tetrahedra is =6.7°. The analysis of electron densities, of the dimensions and distorsions of polyhedra shows that Zn²⁺ is exclusively in octahedral sites; there is no order between six-fold coordinated cations. A comparison between the structural features of hendricksite and those of the two main end-members of biotites, phlogopite and annite, is presented.The effect of the strong covalence of Zn–O bonds is particularly visible on the dimensions and orientations of the thermal ellipsoids of octahedral sites M(1) and M(2) which contain zinc. In all the published structures of trioctahedral micas, the ellipsoids of cationic sites are uniaxial positive, elongated parallel toc ^*. In hendricksite, this is observed only for the two zinc-free sites (T and A; in the octahedra M(1) and M(2), which contain zinc, the ellipsoids are approximately uniaxial negative, flattened parallel toa, which is a unique situation.Zinc which habitually favours the tetrahedral coordinations with oxygen, enters the octahedra only, i.e. the chemically anisotropic sites, in hendricksite. The strong polarizability of Zn²⁺ is proposed to explain this behaviour.An examination of the behaviour of Zn²⁺ in other compounds shows that this situation is general, zinc favours chemically anisotropic sites and specially those adjacent to OH or H₂O.

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Affinement de la structure cristalline de la hendricksite, mica trioctaédrique potassique riche en Zn et Mn; une contribution à la connaissance cristallochimique des minéraux zincifères

Résumé On a affiné par moindres carrés la structure de la hendricksite, mica trioctaédrique de type biotite, caractérisé par une teneur élevée en Zn²⁺ et Mn²⁺. La formule structurale de ce mica est: (K_0m89Na_0,10Ba_0,04)(Mg_1,57Zn_0,54Mn _0,40 ²⁺ Fe _0,25 ²⁺ Al_0,07Ti_0,07Cr_0,01)(Si_2,92Al_1,08)O₁₀(OH)₂. Le groupe spatial estC2/m et les paramètres de la maille:a=5,340(2) Å,b=9,254(2) Å,c=10,235(3) Å, =100,07(2)°; le volume de la maille estV=497,98 ų. Le résidu final non-pondéré estR=0,072. Les distances cation-anion moyennes dans les polyèdres sont les suivantes: T–O=1,659 Å, M(1)–O=2,093 Å, M(2)–O=2,088 Å, A–O_long=3,316 Å et A–O_court=3,004 Å où A désigne le cation alcalin. L'angle de rotation tétraédrique, =6,7°, est très semblable à celui de la phlogopite. L'analyse des densités électroniques, des dimensions et distorsions des polyèdres montre que Zn²⁺ est exclusivement en coordinance octaédrique et qu'il n'y a pas d'ordre entre les cations hexacoordonnés. On présente une comparaison des caractères structuraux de la hendricksite avec ceux des deux principaux pôles des biotites, la phlogopite et l'annite.L'effet de la forte covalence de la liaison Zn–O est particulièrement visible sur les dimensions et orientations des ellipsoides d'agitation thermique des deux sites octaédriques, sites zincifères. Dans toutes les structures de micas trioctaédriques publiées, les ellipsoides des sites cationiques sont uniaxes positifs, allongés parallèlement àc ^*, ce qui s' observe effectivement dans les deux sites non-zincifères (T et A) de la hendricksite, par contre, dans les octaèdres M(1) et M(2), qui contiennent le zinc, les ellipsoides sont approximativement uniaxes négatifs, applatis parallèlement àa, ce qui est une situation unique.Le zinc, qui se fixe généralement en sites tétraédriques dans les structures de type oxyde, occupe les sites octaédriques, c'est-à-dire les sites chimiquement anisotropes dans la hendricksite. La forte polarisabilité de Zn²⁺ est proposée pour expliquer ce comportement.Un examen du comportement de Zn²⁺ dans d'autres phases montre que cette situation est tout à fait générale, le zinc privilégiant les sites chimiquement anisotropes et en particulier ceux adjacents à OH où H₂O.

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甘肃西部地区高放废物处置库场址预选调查   总被引：1，自引：0，他引：1  

刘林清  余运祥 《华东地质学院学报》1995,18(1):33-39

本文根据高放废物处置库场址选择的基本要求，对区域地质及深部构造特征、新构造运动及地震分布规律进行了调查，确定北山南带地区为稳定区。在稳定区内根据处置库有利围岩的出露情况，结合岩体工程地质特征分析，初步选出了４个以花岗岩为主体的场址预选区。经综合分析，认为在４个场址预选区中，以Ｉ号预选区的条件最优，其次是Ⅱ号预选区，再次是Ⅲ号和Ⅳ号预选区。场址区的最后确定尚待进一步调查和论证。  相似文献   

Emission of aliphatic amines from animal husbandry and their reactions: Potential source of N2O and HCN     

Gunnar W. Schade  Paul J. Crutzen 《Journal of Atmospheric Chemistry》1995,22(3):319-346

We measured the emissions of volatile aliphatic amines and ammonia produced by the manure of beef cattle, dairy cows, swine, laying hens and horses in livestock buildings. The amine emissions consisted almost exclusively of the three methylamines and correlated with those of ammonia. The molar emission ratios of the methylamines to ammonia, and data on NH₃ emissions from animal husbandry in Europe, together with global statistics on domestic animals, were used to estimate the global emissions of amines. Annual global methylamine-N input to the atmosphere from animal husbandry in 1988 was 0.15±0.06 TgN (Tg=10¹² g). Almost 3/4 of these emissions consisted of trimethylamine-N. This represents about half of all methylamine emissions to the atmosphere. Other sources are marine coastal waters and biomass burning.Possible reaction pathways for atmospheric methylamines are shown. Among various speculative but possible products N₂O and HCN are of interest because the emission of methylamines could contribute to the global budgets of these compounds. Maximum atmospheric N₂O production from methylamines are below 0.4 Tg N/year, which is less than 10% of the annual N₂O growth rate. Although we do not expect the methylamine emissions to contribute in a major way to the atmospheric N₂O budget, more studies are needed to establish this conclusion beyond doubt. Similar conclusions hold for HCN.  相似文献   

High resolution time series of lead and zinc in sediments of Lake Constance   总被引：3，自引：0，他引：3  

Martin Wessels  Angela Lenhard  Federico Giovanoli  Andreas Bollhöfer 《Aquatic Sciences - Research Across Boundaries》1995,57(4):291-304

Sediments in Lake Constance have been dated by radiometric methods and lamination counting. Investigations into the concentrations of lead and zinc in the sediments were carried out to get detailed information about environmental history. Maximum concentrations were found at the beginning of the 1960's. The lead maximum contamination occurred 3 years before the zinc maximum and has an unidentified source. The use of coal, leaded gasoline or the remobilization within the sediment could be excluded to result in the lead maximum. The fluctuations in zinc contamination could be explained with increasing and decreasing pollution (industry, coal burning, building of sewage plants). The greatest fluctuations of both metals occur during periods of great change in the economic history of Germany.  相似文献   

小块体重的多元线性回归方程在锡铁山铅锌矿床储量计算中的应用   总被引：1，自引：0，他引：1  

曹春祥  李能强 《矿产与地质》2005,19(2):177-183

从锡铁山铅锌矿床小块体重样品原始测定数据入手，运用数学地质中的回归分析，建立了本矿床的小块体重多元线性回归方程，为矿床储量计算提供了科学参数。利用回归方程法计算小块体重进而可以推广到所有贱金属矿床的储量计算中。  相似文献   

新疆乌恰县乌拉根铅锌矿床地质地球化学特征及其成因探讨   总被引：13，自引：0，他引：13  

李丰收  王伟  杨金明 《矿产与地质》2005,19(4):335-340

在研究矿床的地质地球化学特征的基础上,对矿床成因进行了初步探讨,认为乌拉根铅锌矿床是产于中新生代盆地中的热卤水沉积铅锌矿床.其矿质来源主要是由热卤水溶液从深部带至沉积盆地,控制盆地生成和发展的同生断裂为矿液运移提供了通道,稳定下沉的次生盆地提供了良好的矿质沉积环境.  相似文献   

黔西北猫猫厂-榨子厂铅锌矿区地质特征及找矿方向   总被引：3，自引：3，他引：3  

董家龙 《矿产与地质》2005,19(1):29-33

猫猫厂铅锌矿系黔西北铅锌银矿集区主要矿床之一，产于NW向与NE向构造交切复合部位，赋矿地层主要为石炭系白云岩、白云质灰岩。通过对矿床地质特征的总结及与邻区典型矿床类比分析，认为深部找矿潜力大，应加大找矿力度。  相似文献   

阳朔铅锌矿的环境现状与尾矿废水处理模式分析   总被引：3，自引：0，他引：3  

覃朝科  李艺  韦松  黄广宇 《矿产与地质》2005,19(1):99-102

阳朔铅锌矿的环境污染因素主要是采矿废石、选矿尾矿、废液等，主要有害物质为Pb、Cd等重金属元素和残余的选矿药剂，对环境特别是下游环境存在潜在危害。该矿通过建设规范化的尾矿库和废水处理系统，采用尾矿浆由坝体向内(上游)倒流排放沉淀尾矿砂、废水经二级多池串联自然沉淀澄清的处理模式，增强了坝体稳定安全；不使用或极少使用化学沉淀药剂，降低了治污成本。废水处理后，水质清澈无异味，达到国家工业生产污水处理二级排放标准。  相似文献