新疆准噶尔地区富硫型与贫硫型浅成低温热液金矿床成矿流体与碳、硫、铅同位素   总被引：1，自引：2，他引：1  

王莉娟  王京彬  王玉往  朱和平曲丽丽 《岩石学报》2005,21(5):1382-1388

对新疆准噶尔地区浅成低温热液型金矿床中富硫型的阔尔真阔腊金矿、贫硫型的石英滩金矿进行了流依包裹体的均一温度、爆裂温度、包裹体气液相成分、H、O 同位素、矿体围岩及脉石英包裹体 C 同位素、矿体中黄铁矿等 S、Ph 同位素等系统地进行了研究,综合研究表明,本区该类型金矿成矿流体一般温度低、盐度低,来源主要为循环的大气水、矿石中黄铁矿的 S、Pb 同位素均为深源,暗示金的深部来源:矿体石英包裹体中 CO_2的δ~(13)C 为低于-10‰的有机碳,反映了本区年轻的富含有机质的沉积地层参与了金的成矿。此外,本文首次提出了富硫型阔尔真阔腊金矿床成矿流体中有侵入岩浆热液参与,深部有多金属成矿远景;贫硫型石英滩金矿没有侵入岩浆热液的参与,成矿仅与火山古热液活动有关,其成矿较单一。此外,阔尔真阔腊金矿中低温流体活动较强,金矿化也较强:石英滩金矿低温流体活动相对较弱,金矿化也较弱,也体现了该类型金矿床低温流体活动的越强烈,金矿化越强的规律。  相似文献   

成矿流体演化与成矿物理化学   总被引：7，自引：0，他引：7  

费红彩  肖荣阁 《矿物岩石地球化学通报》2002,21(2):139-144

成矿流体是富含挥发分 (CO2 、CH4等 )是具有较高含盐度的特殊地质流体。本文讨论了在流体演化过程中挥发分的来源 ,指出主要来自水岩作用、有机质分解及地幔去气和岩浆 ;碱金属及卤素同样具有多来源的性质 ,以海水、含盐系淋滤、建造水为主要来源 ,含盐系重熔可以形成富含碱金属的成矿流体。流体演化过程中氢氧同位素、硫同位素的分馏主要与温度、水岩比值或硫源丰度有关。一个重要的结论是 ,成矿流体的形成主要与地质作用有关 ,而流体来源是次要的。海底热水流体的地球化学特征以高δ3 4 S值、中稀土富集及正铕异常为特征。本文总结了热水流体成矿物理化学条件 ,指出水热流体物相点 :1) 10 80℃ ,7.5× 10 8Pa水溶液与硅酸岩熔浆分熔点 ;2 )水溶液的第二个临界点是气水溶液的超临界点 (374.15℃ ,2 .2 1× 10 7Pa) ;3)水溶液的沸点 (≥ 10 0℃ ,≥ 1× 10 5Pa) ;4)水溶液的冰点 (≤ 0℃ ,1× 10 5Pa) ;5 )H2 O CO2 体系的不混溶温度点 (2 6 6℃ ,2 .15×10 8Pa[1 3 ] 等是重要的成矿相变点。  相似文献   

柴北缘绿梁山地区辉长岩的锆石U-Pb年龄及意义   总被引：11，自引：0，他引：11  

袁桂邦  王惠初  李惠民  郝国杰  辛后田  张宝华  王青海  田琪 《华北地质》2002,25(1):36-40

柴达木盆地北缘绿梁山地区的辉长岩侵入到古生代滩间山群及超基性岩中 ,地球化学、微量元素、稀土元素显示出源幔特征。选自其中的锆石明显具岩浆型锆石特点 ,4个单颗粒锆石U -Pb同位素年龄均为谐和年龄 ,2 0 6 Pb 2 38U表面年龄统计权重平均值为 (496 .3± 6 .2 )Ma ,代表了该岩体的结晶年龄 ,从而间接地否定了本区滩间山群的时代为晚奥陶世 -志留纪的认识。辉长岩与滩间山群是柴北缘活动大陆边缘火山岛弧的组成部分。此类岩体同位素地质年龄的确定对柴北缘榴辉岩、滩间山群时代及大地构造性质的重新认识具有重要意义  相似文献   

Stable isotopic signature of a palaeoaquifer, Mississippian Alamogordo Member limestones, Sacramento Mountains, New Mexico, USA   总被引：1，自引：0，他引：1  

YongqiangWu  Henry S. Chafetz 《Sedimentology》2002,49(2):227-235

Nine stratigraphic sections, each ≈5 m thick, were sampled from the Alamogordo Member limestones of the Lake Valley Formation, Sacramento Mountains, New Mexico, USA. Four stratigraphic sections consist entirely of lime mudstone and wackestone, whereas the other five sections have a prominent layer of crinoidal packstone about 1 m thick at their base. Stable isotopic analyses reveal that the lime muds in the sections with basal packstone layers show a downward decrease in δ¹⁸O and constant δ¹³C values, whereas those in the sections solely composed of lime mudstone and wackestone have, in general, relatively uniform δ¹⁸O and δ¹³C values. The diagenesis of the Alamogordo Member limestones was previously believed to have been governed by the downward percolation of meteoric water from a regional pre-Pennsylvanian exposure surface ≈100 m above this unit. However, the uniform δ¹³C and downward decrease in δ¹⁸O values in the lime muds in the sections with basal packstones indicate that the meteoric water ascended within the Alamogordo Member, rather than descended from the overlying exposure surface. This indicates that the basal packstones were probably a conduit for meteoric water. This is further supported indirectly by the relatively uniform δ¹⁸O and δ¹³C values of the lime mud in the sections without basal packstones. The implications are that the oxygen isotopic gradients may be used to identify palaeoaquifers, flow directions within these aquifers and that meteoric diagenesis below an exposure surface could be governed by flow through a palaeoaquifer.  相似文献   

Isotopic constraints on growth conditions of multiphase calcite–pyrite–barite concretions in Carboniferous mudstones     

R. Raiswell  S. H. Bottrell  S. P. Dean  J. D. Marshall†  A. Carr‡  & D. Hatfield 《Sedimentology》2002,49(2):237-254

Carbonate concretions in the Lower Carboniferous Caton Shale Formation contain diagenetic pyrite, calcite and barite in the concretion matrix or in different generations of septarian fissures. Pyrite was formed by sulphate reduction throughout the sediment before concretionary growth, then continued to form mainly in the concretion centres. The septarian calcites show a continuous isotopic trend from δ¹³C=?28·7‰ PDB and δ¹⁸O=?1·6‰ PDB through to δ¹³C=?6·9‰ PDB and δ¹⁸O=?14·6‰ PDB. This trend arises from (1) a carbonate source initially from sulphate reduction, to which was added increasing contributions of methanogenic carbonate; and (2) burial/temperature effects or the addition of isotopically light oxygen from meteoric water. The concretionary matrix carbonates must have at least partially predated the earliest septarian cements, and thus used the same carbonate sources. Consequently, their isotopic composition (δ¹³C=?12·0 to ?10·1‰ PDB and δ¹⁸O=?5·7 to ?5·6‰ PDB) can only result from mixing a carbonate cement derived from sulphate reduction with cements containing increasing proportions of carbonate from methanogenesis and, directly or indirectly, also from skeletal carbonate. Concretionary growth was therefore pervasive, with cements being added progressively throughout the concretion body during growth. The concretions contain barite in the concretion matrix and in septarian fissures. Barite in the earlier matrix phase has an isotopic composition (δ³⁴S=+24·8‰ CDT and δ¹⁸O=+16·4‰ SMOW), indicating formation from near‐surface, sulphate‐depleted porewaters. Barites in the later septarian phase have unusual isotopic compositions (δ³⁴S=+6 to +11‰ CDT and δ¹⁸O=+8 to +11‰ SMOW), which require the late addition of isotopically light sulphate to the porewaters, either from anoxic sulphide oxidation (using ferric iron) or from sulphate dissolved in meteoric water. Carbon isotope and biomarker data indicate that oil trapped within septarian fissures was derived from the maturation of kerogen in the enclosing sediments.  相似文献   

Continental crust and lithospheric mantle interaction beneath North China: isotopic evidence from granulite xenoliths in Hannuoba, Sino-Korean craton   总被引：40，自引：0，他引：40  

Xinhua Zhou  Min Sun  Guohui Zhang  Shaohai Chen 《Lithos》2002,62(3-4):111-124

Mafic granulite and pyroxenite xenoliths from Cenozoic alkaline basalts at Hannuoba, Hebei Province, North China have been selected for a systematic geochemical and Sr–Nd–Pb isotopic study, which provides a unique opportunity to explore nature of the lower crust and the interaction between the continental crust and lithospheric mantle beneath an Archean craton. The major, compatible and incompatible elements and radiogenic isotopes of these xenoliths suggest great chemical heterogeneity of the lower crust beneath the Hannuoba region. Petrological and geochemical evidences indicate a clear cumulate origin, and most likely, they are related to basaltic underplating in different geological episodes. However, the Sr–Nd–Pb isotopic compositions of the xenoliths reveal a profound enriched source signature (EM I) with some influence of EM II, which implies that some portion of pre-existing, old metasomatized subcontinental lithospheric mantle could have played an important role in their genesis. It is suggested that the interaction between continental crust and subcontinental mantle as manifested by basaltic underplating would be closely related to regional tectonic episodes and geodynamic processes in the deep part of subcontinental lithospheric mantle.  相似文献   

内蒙古宝音图岩群变质基性火山岩锆石U-Pb年龄及意义     

张玉清  苏宏伟 《华北地质》2002,(Z1)

内蒙古达茂旗宝音图岩群是在达茂旗、查干呼绍地区 1:5万区调和白云鄂博幅 1:2 5万区调过程中从过去的巴特敖包群和白云鄂博群未分岩组解体出来的中级变质岩系。通过对宝音图岩群中阳起钠长片岩、二云片岩 (原岩均为基性火山岩 )进行单颗粒锆石U -Pb法年龄测定 ,获得了两条不一致线上交点年龄 (2 486± 42 )Ma、(2 496± 2 6 )Ma ,代表了宝音图岩群基性火山岩及宝音图岩群的形成时代 ;在不一致线之外不同成因的锆石的2 0 7Pb/ 2 0 6Pb表面年龄 (2 2 2 7± 15 )Ma ,寓示着 2 2 0 0Ma左右发生了一次区域性变质热事件 ;下交点年龄 (319±486 )Ma和 (40 6± 46 )Ma ,代表了 2 5 0～ 480Ma时期该区大面积岩浆侵位及宝音图岩群后期变形变质改造的时期 ,两个年龄样的获得为研究古元古代古陆的裂解及白云鄂博海槽的形成提供了直接依据。  相似文献   

Celestite formation, bacterial sulphate reduction and carbonate cementation of Eocene reefs and basinal sediments (Igualada, NE Spain)   总被引：5，自引：0，他引：5  

Conxita Taberner  James D. Marshall†  James P. Hendry‡  Catherine Pierre§  & M. F. Thirlwall¶ 《Sedimentology》2002,49(1):171-190

Petrographic and geochemical studies of an Upper Eocene reef and associated basinal sediments from the mixed carbonate–siliciclastic fill of the south‐eastern Pyrenean foreland basin near Igualada (NE Spain) provide new insights into the evolution of subsurface hydrology during the restriction of a marine basin. The reef deposits are located on delta‐lobe sandstones and prodelta marls, which are overlain by hypersaline carbonates and Upper Eocene evaporites. Authigenic celestite (SrSO₄) is an important component in the observed diagenetic sequences. Celestite is a significant palaeohydrological indicator because its low solubility constrains transportation of Sr²⁺ and SO₄^2? in the same diagenetic fluid. Stable isotopic analyses of carbonates in the reef indicate that meteoric recharge was responsible for aragonite stabilization and calcite cementation. Sulphur and oxygen isotope geochemistry of the celestite demonstrates that it formed from residual sulphate after bacterial sulphate reduction, but also requires that there was a prior episode of sulphate recycling. Meteoric water reaching the reef and basinal areas was most probably charged with SO₄^2? from the dissolution of younger Upper Eocene marine evaporites. This sulphate, combined with organic matter present in the sediments, fuelled bacterial sulphate reduction in the meteoric palaeoaquifer. Strontium for celestite precipitation was partly derived in situ from dissolution of aragonite corals in the reef and basinal counterparts. However, ⁸⁷Sr/⁸⁶Sr data also suggest that Sr²⁺ was partly derived from dissolution of overlying evaporites. Mixing of these two fluids promoted celestite formation. The carbonate stable isotopic data suggest that the local meteoric water was enriched in ¹⁸O compared with that responsible for stabilization of other reefs along the basin margin. Furthermore, meteoric recharge at Igualada post‐dated evaporite deposition in the basin, whereas other parts of the same reef complex were stabilized before evaporite formation. This discrepancy resulted from the spatial distribution of continental siliciclastic units that acted as groundwater conduits.  相似文献   

Variabilité isotopique des précipitations sahéliennes à différentes échelles de temps à Niamey (Niger) entre 1992 et 1999 : implication climatiqueIsotopic variability of Sahelian rainfall at different time steps in Niamey (Niger, 1992–1999): climatic implications     

Jean-Denis Taupin  Gaëlle Gaultier  Guillaume Favreau  Christian Leduc  Christelle Marlin 《Comptes Rendus Geoscience》2002,334(1):43-50

The isotopic content of rainfall was measured in Niamey (Niger) over a period of eight years (1992–1999). Seasonal distribution of rainy events depends on the monsoon movement over the region. At the beginning and at the end of the rainy season, low rainfall, high temperatures and low relative humidity favour isotopic enrichment. In the middle of the rainy season, heavy rainfall, low temperatures and relative humidity close to saturation lead to isotopically depleted contents because of the mass effect; moreover, in the case of low rainfall, marked vertical convective development favours high altitude condensation. How far the Intertropical Front moves north, determines the quality of the rainy season and influences the isotopic contents. Thus the isotopic contents of rainfall are good climatic indicators. To cite this article: J.-D. Taupin et al., C. R. Geoscience 334 (2002) 43–50  相似文献   

Production of selected cosmogenic radionuclides by muons: 2. Capture of negative muons   总被引：1，自引：0，他引：1  

B. Heisinger  D. Lal  A. J. T. Jull  P. Kubik  S. Ivy-Ochs  K. Knie  E. Nolte   《Earth and Planetary Science Letters》2002,200(3-4):357-369

We have determined the production yields for radionuclides in Al₂O₃, SiO₂, S, Ar, K₂SO₄, CaCO₃, Fe, Ni and Cu targets, which were irradiated with slow negative muons at the Paul Scherrer Institute in Villigen (Switzerland). The fluences of the stopped negative muons were determined by measuring the muonic X-rays. The concentrations of the long-lived and short-lived radionuclides were measured with accelerator mass spectrometry (AMS) and γ-spectroscopy, respectively. Special emphasis was put on the radionuclides ¹⁰Be, ¹⁴C and ²⁶Al produced in quartz targets, ²⁶Al in Al₂O₃ and S targets, ³⁶Cl in K₂SO₄ and CaCO₃ targets, and ⁵³Mn in Fe₂O₃ targets. These targets were selected because they are also the naturally occurring target minerals for cosmic ray interactions in typical rocks. We also present results of calculations for depth-dependent production rates of radionuclides produced after cosmic ray μ⁻ capture, as well as cosmic ray-induced production rates of geologically relevant radionuclides produced by the nucleonic component, by μ⁻ capture, by fast muons and by neutron capture.  相似文献