Enzymatic synthesis of methyl-galactoaldehyde     

Wang Qun  Yu Guangli 《中国海洋大学学报(英文版)》2002,1(2):145-147

Methyl-galactosides were oxidized at room temperature by galactose oxidase in a one-step reaction and afforded methyl-galactoaldehyde in excellent yield and high purity. The resulting galactoaldehyde as a useful intermediate can be directly used in glycopeptide synthesis.  相似文献   

Lithium Abundances in the Atmospheres of SLR C-Giants WZ Cas and WX Cyg from Resonance and Subordinate Li I Lines     

Larisa A. Yakovina  Yakiv V. Pavlenko  Carlos Abia 《Astrophysics and Space Science》2003,288(3):279-286

Lithium abundances in the atmospheres of the super Li-rich C-giants WZ Cas and WX Cyg are derived by the spectral synthesis technique using the Li I resonance line at λ670.8 nm and three subordinate lines at λλ 812.6, 610.4 and 497.2 nm. The differences between the Li abundances derived from the λ670.8 nm line and the λλ 497.2, 812.6 nm lines do not exceed ±0.5 dex. The lithium line at λ610.4 nm provides typically lower abundances than the resonance line (by ≈ 1 dex). The mean LTE and NLTE Li abundances from three Li I lines (excluding λ610.4 nm) are 4.7, 4.9 for WZ Cas, and 4.6, 4.8 for WX Cyg, respectively. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Yields of Nucleosynthesis from massive and intermediate mass stars and constraints on their final evolution     

D. C. V. Mallik  Sushma V. Mallik 《Journal of Astrophysics and Astronomy》1985,6(3):113-130

Nucleosynthetic yields and production rates of helium and heavy elements are derived using new initial mass functions which take into account the recent revisions in O star counts and the stellar models of Maeder (1981a, b) which incorporate the effects of massloss on evolution. The current production rates are significantly higher than the earlier results due to Chiosi & Caimmi (1979) and Chiosi (1979), and a near-uniform birthrate operating over the history of the galactic disc explains the currently observed abundances. However, the yields are incompatibly high, and to obtain agreement it is necessary to assume that stars above a certain mass do not explode but proceed to total collapse. Further confirmation of this idea comes from the consideration of the specific yields and production rates of oxygen, carbon and iron and the constraints imposed by the observational enrichment history in the disc as discussed by Twarog & Wheeler (1982). Substantial amounts of⁴He and¹⁴C, amongst the primary synthesis species, are contributed by the intermediate mass stars in their wind phases. If substantial numbers of them exploded as Type I SN, their contribution to the yields of¹²C and⁵⁶Fe would be far in excess of the requirements of galactic nucleosynthesis. Either efficient massloss precludes such catastrophic ends for these stars, or the current stellar models are sufficiently in error to leave room for substantial revisions in the specific yields. The proposed upward revision of the¹²C (α,γ)¹⁶O rate may produce the necessary changes in stellar yields to provide a solution to this problem. Stars that produce most of the metals in the Galaxy are the same ones that contribute most to the observed supernova rate.  相似文献   

“Cretaceous black flysch” in the Pieniny Klippen Belt, West Carpathians: a case of geological misinterpretation     

Krzysztof Birkenmajer  Przemys&#x;aw Gedl  Ryszard Myczy&#x;ski  Jaros&#x;aw Tyszka 《Cretaceous Research》2008,29(3):535-549

This is a critical assessment of the paper by Oszczypko et al. (2004: Cretaceous Research 25, 89–113), in which they tried to prove a mid-Cretaceous age for the Szlachtowa (“black flysch”) and Opaleniec Formations, in the Pieniny Klippen Belt, West Carpathians, both of which had previously been shown to be of Jurassic age. We argue that the mid-Cretaceous age assignment is a misinterpretation, primarily resulting from their field samples having been collected from some Cretaceous lithostratigraphic units, tectonically associated with the Jurassic formations, and/or from tectonic contact-breccias involving Jurassic and Cretaceous strata. In addition, we suggest that they have overlooked a number of significant palaeontological papers, published since 1962, which record the presence of in situ ammonites, aptychi, belemnites, thin-shelled bivalves (Bositra), gryphaeids, foraminifera, and ostracod assemblages, all indicating a Jurassic (mainly Aalenian), and not a Cretaceous, age for the Szlachtowa Formation, and also the in situ Jurassic (Bajocian) ammonites and thin-shelled bivalves (Bositra), Bositra-microfacies, and age-diagnostic foraminiferal assemblages of the Opaleniec Formation.Our presentation here of recently published dinocyst data from well-preserved assemblages further supports the Jurassic ages for the Szlachtowa (“black flysch”) and Opaleniec Formations.  相似文献   

Development of two novel CYP-antibodies and their use in a PCB exposure experiment with Mytilus edulis     

H. Jonsson  K. Viken Sandnes  D. Schiedek  R. Schneider  B. E. Grsvik  A. Goksyr 《Marine environmental research》2004,58(2-5):655

In an attempt to learn more about the cytochrome P450 (CYP) system of mussels, we used protein databases and alignment software to extract highly conserved CYP sequences. From these alignments synthetic peptides were produced and used for rabbit immunisation, which yielded polyclonal antibodies against the CYP families 2 and 4. The antibodies were evaluated with Western Blot and ELISA assays, using digestive gland microsomal samples from the mussel Mytilus edulis. Western Blots revealed immunoreactions for both antibodies. The anti-CYP2 sequence rendered one major immunopositive protein of ≈49 kDa size, and weak signals for proteins of ≈41 and 56 kDa size. The anti-CYP4 sequence rendered two major bands of ≈56 and 59 kDa size, and also a weak immunoreaction with a protein of ≈43 kDa size. ELISA rendered only weak signals even with a 1:50 dilution of IgG-purified serum. A 10-day exposure to Aroclor 1254 did not appear to affect any of the immunopositive proteins, while total PCBs in soft bodies increased from 14–40 ng/g DW in controls to 373–638 ng/g DW in exposed mussels.  相似文献   

合浦珠母贝26S蛋白酶体S4,S7亚基基因片段的分离与分析     

姜铁民  张勇  黄洁  谢莉萍  吴移谋  张荣庆 《海洋科学》2003,27(4):28-34

26S蛋白酶体是真核生物中一种具有ATP依赖性的蛋白酶复合体,主要通过泛肽途径选择性降解细胞内与代谢调控、细胞周期有关的功能蛋白及异常蛋白,参与多种细胞活动的调控过程。26S蛋白酶体由具有催化活性的20S亚复合体和一个具有调节作用的19S亚复合体组成,其中19S亚复合体中的ATP酶亚基是调节26S蛋白酶体活性的重要组件。本通过简并引物PCR手段,从软体动物合浦珠母贝(Pinctada fucata)中扩增到参与构成19S亚复合体的S4和S7(MSS1)两个亚基的基因片段。这两个基因片段所编码的ATP酶组件包含有Gx4GKT,DEID,SAT和H／QRxGRxxR等26S蛋白酶体ATP酶亚基的共同功能基序。这是首次在软体动物中报道26S蛋白酶体的ATP酶亚基基因序列,为研究软体动物中26S蛋白酶体的结构与功能奠定了分子基础。  相似文献   

Subunit composition and chromophore content of R-phycocyanin and allophycocyanin from Porphyra haitanensis     

Gao Hongfeng  Cao Wen  Ji Minghou 《海洋学报(英文版)》1994,13(2):253-259

ＳｕｂｕｎｉｔｃｏｍｐｏｓｉｔｉｏｎａｎｄｃｈｒｏｍｏｐｈｏｒｅｃｏｎｔｅｎｔｏｆＲ－ｐｈｙｃｏｃｙａｎｉｎａｎｄａｌｌｏｐｈｙｃｏｃｙａｎｉｎｆｒｏｍＰｏｒｐｈｙｒａｈａｉｔａｎｅｎｓｉｓ￥ＧａｏＨｏｎｇｆｅｎｇ；ＣａｏＷｅｎｄａａｎｄＪｉＭｉｎｇ...  相似文献   

Methodical series tests for fuller ship hull forms     

B. Della Loggia  L. Doria 《Ocean Engineering》1980,7(6):659-706

In recent years many fuller ship hull forms have been designed and constructed in various shipbuilding countries, but the data available for the development of the fuller forms are inadequate from the point of view of preliminary ship design. In this paper the authors describe how they have systematically tested vessel forms of block coefficients ranging from 0.80 to 0.90. The analysis and presentation of the test results have been made in such a manner that designers can produce hull forms like those of tankers and other bulk carriers quickly and reliably.  相似文献   

I(L)值完全诱导空间     

方进明  岳跃利  刘刚 《中国海洋大学学报(自然科学版)》2001,31(6):960-964

作者引入 I(L)值完全下半连续映射 ,研究其性质。利用 I(L)值完全下半连续映射定义I(L)值完全诱导空间 ,给出 I(L)值完全诱导空间的拓扑基的表达形式 ,证得两个 I(L)值完全诱导空间的映射是连续映射的充分必要条件 ,并建立了乘积空间的 I(L)值完全诱导空间与 I(L)值完全诱导空间的乘积空间的联系  相似文献   

肝素酶Ⅰ对合成的肝素五糖的酶解作用及对其抗Xa因子活性的影响     

于广利  管华诗  Jawed Fareed 《中国海洋大学学报(自然科学版)》2001,31(4):529-535

研究肝素酶Ⅰ(来源于Flavobacterumheparinase，EC4.2.2.7)对人工合成的且含有与抗凝血酶Ⅲ特定结合位点的肝素五糖(SHP)的酶解作用，并对酶解作用的动力学进行研究。利用强阴离子高效液相色谱(SAX-HPLC)对酶解混合物进行分离，利用质谱(ESIMS)和核磁共振波谱(1H-NMR)技术对得到的二糖和三糖的结构进行确证。研究结果表明，这种被作为肝素反向试剂的肝素酶Ⅰ可水解人工所合成的肝素五糖，从而使之丧失抗Xa因子活性。  相似文献