Environmental Redox Changes of the Ancient Sea in the Yangtze Area during the Ordo-Silurian Transition     

YAN Detian  CHEN Daizhao  WANG Qingchen  WANG Jianguo  CHU Yang 《《地质学报》英文版》2008,82(3):679-689

Extensive organic-matter （OM） rich facies （black shales） occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections （Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province） straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon （TOC）, pyrite sulphur, and different species of Fe, including dithionite-extractable Fe （FED）, pyrite Fe （FeP）, HCl-extractable Fe （FeH）, and total Fe （FeT）, in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe （FeHR = FeD ＋ FeP） and FeT, and the FeP/（FeP ＋ FeH） ratio, known as the degree of pyritization （DOP）. In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios （0.20-0.77; avg. 0.45）, high DOP values （0.21-0.72; avg. 0.54）, and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios （0.10-0.35; avg. 0.21）, low DOP values （0.11- 0.40; avg. 0.28）, and SIC values are clustering on the normal marine value （SIC = 0.36）. The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios （0.32-0.49; avg. 0.41）, high DOP values （0.46-0.68; avg. 0.53） and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters  相似文献   

软弱夹层几何参数对试样力学行为影响颗粒元模拟研究   总被引：2，自引：0，他引：2  

张晓平  吴顺川  张兵  潘文 《工程地质学报》2008,16(4):539-545

基于离散元理论的颗粒元程序,采用颗粒接触连接模型和滑动模型,建立了含软弱夹层试样的颗粒元模型。通过数值模型实验,对不同软弱夹层几何参数试样进行加载模拟,探讨了不同夹层厚度及不同倾角条件下试样的破坏过程和破坏形式,并分析其对试样强度的影响。模拟结果表明,裂隙首先产生于软弱夹层处,随着荷载的增加,再逐渐扩展,呈现渐进性破坏特征;夹层越厚,倾角越大,试样沿软弱夹层呈现较强的滑动特征,如果夹层薄且缓,软弱夹层成为试样破坏的非控制因素;软弱夹层厚度和夹角对试样的峰值强度都有影响,随软弱夹层厚度和夹角的增大,试样的峰值强度降低。  相似文献   

洛钼集团三道庄矿让资源“颗粒归仓”     

张永强  ;秦玉辉 《河南地质》2008,(1):32-33

洛阳栾川钼业集团公司开采的三道庄钼钨矿区是栾川钼矿田三大矿区之一。矿体厚大集中,面积487万平方米,矿石储量5.8亿吨,其中钼金属储量67万吨,平均原矿品位0.115%,钨金属储量50万吨,平均品位0.117%。为埋藏浅、品位高、选别性能好的特大型钼钨矿床,是亚洲最大的钼矿区之一。洛钼人形象地把三道庄钼钨矿区称作洛钼集团的＂大粮仓＂。  相似文献   

胞外聚合物EPS组成及对污泥特性的影响研究     

赵军  徐高田  秦哲  官春芬 《地质勘探安全》2008,15(1):66-70

综述了进水基质、溶解氧（DO）、pH、污泥停留时间（SRT）和污泥负荷（Ns）对EPS组成的影响,分析了EPS对污泥的表面特性（污泥混合液疏水性、Zeta电位等）、生物絮凝沉降性、脱水性及吸附再生性能的影响,并通过控制适当的条件,改善EPS组成,形成良好的活性污泥,能使之更好的发挥作用。  相似文献   

Fe-Cu-Zn-Mo同位素示踪氧化还原过程     

黄思民  张贵宾 《岩石矿物学杂志》2024,43(2):469-494

非传统稳定同位素（Fe-Cu-Zn-Mo）理论与数据相结合提高了科研工作者对地质体系氧化还原过程的理解。本文对这一相对较新的领域进行了综述,包括与氧化还原过程相关的同位素分馏理论和实验约束、时空尺度下的氧逸度以及同位素示踪氧化还原过程。稳定同位素理论预测,Fe-Cu-Zn-Mo同位素应该对氧化还原状态的变化能够做出响应。结果表明,Fe同位素作为岩浆过程、表生过程、俯冲带流体性质"氧逸度计"应用前景广阔;Cu同位素在岩浆、热液、陆地系统可以很好地示踪氧化还原过程;Zn同位素由于络合过程分馏已经被用在许多不同环境中作为含硫/碳流体迁移的敏感示踪剂;Mo同位素作为古氧逸度计可有效重建古海洋-大气氧化还原状态。  相似文献   

下辽河地区砂土液化形成的震害地质问题   总被引：2，自引：0，他引：2       下载免费PDF全文

朱海之  王立功  高清武  王登弟 《地震地质》1979,1(2):67

海城地震引起下辽河平原大面积砂土液化,液化震害有喷水冒砂、陷落砂坑、地滑移等等。液化区是全新世海退之地,震害严重区地表粘性土层薄,承压水头高;震害轻微区地表粘性土层厚,承压水头低。喷砂颗粒的单粒结构表明液化砂层具有松散的特点,砂颗粒的滚圆度在液化难易上不起主要作用  相似文献   

岩石破裂与氡含量变化关系的实验研究   总被引：1，自引：0，他引：1  

罗光伟 《地球物理学报》1977,20(4):277-282

为探索氡含量的变化能否视作地震前兆,作者进行了岩石破裂与氡含量变化关系的模拟实验。实验结果表明,可以认为岩石破裂是引起地震之前氡含量异常的原因之一。文末,根据实验结果对在地震区某些实际观测中的问题进行了初步讨论。  相似文献   

唐山地震时不同烈度区液化砂土的特征及其液化判别   总被引：2，自引：0，他引：2       下载免费PDF全文

王克鲁  盛学斌  蔡灵铎  胡碧茹  刘慧敏 《地震地质》1982,4(2):59

本文根据唐山地区的东、中、西三条剖面上的地震喷砂的物质成分和理化性质等分析,探讨了不同烈度区液化砂土的颗粒成分、化学成分、物理性质及砂颗粒形态等变化规律,并根据这些规律,编制出以物质成分和性质为基础的、具有多种因素的砂土液化判别图。该图可供砂土液化预测、砂土液化研究者参考  相似文献   

Plerospheres and their role in reduction of emitted fine fly ash particles     

Fariborz Goodarzi Hamed Sanei 《中国地球化学学报》2006,25(B08):47-48

Particles, less than PM10 in size, emitted from the stack of pulverized coal-fired power plants are of environmental concern since they can easily enter the human respiratory track. These fine particles are examined by Scanning Electron Microscope/Electron Dispersive Spectrometry （SEM/EDX）. Plerospheres are found in fly ash and are particles containing smaller particles formed during combustion of coal. The large plerospheres 〉50 μm mostly are present in ESP fly ash, indicating that they are effectively capturing fine particles and reducing their stack emission.  相似文献   

Catalytic ozonation of phenol in water with natural brucite and magnesia     

Kun HE Yuming DONG Lin YIN Aiming ZHANG Zhen LI 《中国地球化学学报》2006,25(B08):101-101

Catalytic ozonation has attracted much attention in treatment of wastewater for its mild conditions. Phenol and its ramifications are common components in a wide variety of wastewaters including those from coal conversion processes, coking plants, petroleum refineries and several chemical industries. In this paper, natural brucite and magnesia have been successfully used in catalytic ozonation of phenol. And the mechanisms of catalysis were also investigated. From Figs. 1 and 2, it can be found that both brucite and magnesia have remarkable catalysis on degradation of phenol and removal of Chemical Oxygen Demand （COD）. The pH of solutions on the process of ozonation alone, catalytic ozonation with brucites and with magnesia were 6.35-2.76, 10.18-8.52 and 10.58-10.83, respectively. It can be concluded that alkali environment plays a critical role for catalytic ozonation of phenol. We also found that the alkaline minerals reacted on the surface with oxalic acid and other low molecular-weight acids which are intermediate products in ozonation, but those intermediate products could be mineralized into carbon dioxide completely with enough ozonation time.  相似文献