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Fariborz Goodarzi Hamed Sanei 《中国地球化学学报》2006,25(B08):47-48
Particles, less than PM10 in size, emitted from the stack of pulverized coal-fired power plants are of environmental concern since they can easily enter the human respiratory track. These fine particles are examined by Scanning Electron Microscope/Electron Dispersive Spectrometry (SEM/EDX). Plerospheres are found in fly ash and are particles containing smaller particles formed during combustion of coal. The large plerospheres 〉50 μm mostly are present in ESP fly ash, indicating that they are effectively capturing fine particles and reducing their stack emission. 相似文献
74.
Turchanina Oksana Satin Vladimir Derevyanko Aleksey 《中国地球化学学报》2006,25(B08):51-52
As is well known, a high content of sulphur in coals is an effect of the post-depositional history of coal seams and one of the most important criteria of its use as a fuel. Sulphur in coals can cause a serious environmental and technological problem during their utilization. This problem is very actual for the Donetsk Basin because 734 mined seams out of the total of 1009 (73%) are comprised of coals with sulphur content -2%. The chemical pre-treatment as a first stage in their processing is widely used in order to effectively obtain the thermal destruction products of coals (such as semi-coke, coke, adsorbents, etc.) and to simultaneously utilize coal wastes. Development in pre-treatment methods for high-sulphur, low-rank coals is especially desirable for reducing the sulphur contents of the solid products. The aim of the present work is to investigate the influence of coal pre-treatment on the yield and composition of thermal destruction products, and the sulphur distribution among different components of the coals of different genetic types by reductivity (low-reduced LRC and reduced RC coals). The thermal behavior of the coals was studied by means of the Fisher method (heated to 520℃, at a rate of 7℃/min). The composition of the semi-coking gas was investigated by means of a VTI gas analyzer. The coal samples were chemically treated directly before thermal destruction by the introduction of 1-% solutions of radical polymerization initiator AAD (acrylic acid dinitrile C8H12N4) and products of coal-tar distillation (absorber oil). Coal pre-treatment increases the semi-coke yield and its coking ability, and changes the liquid/gaseous product ratio. 相似文献
75.
Xinghui XIA 《中国地球化学学报》2006,25(B08):263-263
Photodegradation of chrysene, benzo (a) pyrene and benzo (g, h, i) perylene in natural water of the Yellow River was studied using simulation sunlight. The effects of particulates on the photodegradation were explored. Several results arose from this study. (1) The photodegradation of PAHs can be fitted with first-order kinetics when no particulate exists in water system, and the first-order constant increases with decreasing of initial concentration of PAHs. The photodegradation rates of the three PAHs are related to their molecule absorption spectrum. (2) The existence of loess exerts two kinds of effects on the photodegradation of PAHs, including the inner filter effects and the photosensitizing effects of humic substance in loess. These two contrary effects lead to the difference of net effects among different contents of loess. When the loess contents are 0.1 and 5.0 g/L, the existence of loess stimulates the photodegradation of chrysene, benzo (a) pyrene. When the loess content is 5.0 g/L, the existence of loess stimulates the photodegradation of benzo (g, h, i) perylene. In addition, the photodegradation of PAHs can be fitted with the second-order kinetics when there is loess in the water system. (3) The soluble humic substances in loess can accelerate the photodegradation of PAHs while the in soluble part cannot. (4) Since the soluble humic substances in the suspended solids of the river have been dissolved in water, 相似文献
76.
Sivaji Patra Congqiang LIU Siliang LI Fushun WANG Baoli WANG 《中国地球化学学报》2006,25(B08):269-270
Geochemical cycling has received wide attention due to the need to understand the pathways of pollutants through our present environment. In this regard the Yangtze River plays a significant role in putting those pollutants into the East China SeafWorld Oceans. The Yangtze River is of high sedimentation rate and water discharge. The watershed covers variable climate regions from temperate to subtropical and from semiarid to humid. Twenty three (23) sampling locations at the estuary have been selected for understanding the dynamic relationships. The elements (Cl^-, SO4^2-, Na^+, K^+, and Ca^2+) show conservative behavior during mixing of fresh water with saline water whereas Mg^2+, Mn^2+ show a non-conservative pattern . The relationships between Na^+/SO4^2- and Cl^-/SO4^2- molar ratios show a mixing of more than two water sources. 相似文献
77.
78.
分析了27个紫色土丘陵区土壤样品的机械组成,运用分形模型计算出土壤颗粒分形维数D(D=2.817—3.030),探讨了分形维数D与土壤粒度组成、土壤抗蚀性之间的关系,并分析了不同土地利用方式下土壤颗粒分形维数D与土壤有机质含量(O.M)、土壤容重(B.D)的相关关系。研究表明:土壤颗粒分形维数D能够很好的表征土壤质地,重点反映〈0.05mm的细颗粒物质,尤其是粘粒,其次是粉粒;与土壤有机质含量(O.M)、土壤容重(B.D)均达到极显著水平;其次分形维数D还能作为评价土壤水土流失和土壤生态恢复的指标。 相似文献
79.
从地上、地下有机物质生产对湿地碳输入的贡献,湿地土壤碳库以及土地利用变化对湿地土壤碳库和碳排放的影响,甲烷排放和可溶性有机碳输出以及影响因子,湿地生态系统碳循环动态模型4个方面对湿地生态系统碳循环国内外研究进展和研究成果进行综述、分析,提出了我国亚热带区域天然湿地碳循环研究的主要热点和方向:⑴沿海湿地碳库估算及土地利用转化对土壤碳库和温室气体排放的影响;⑵酸沉降对于我国东南沿海低纬度地区湿地甲烷排放的影响;⑶沿海湿地生态系统碳循环动态模型的应用与开发;⑷湿地系统可溶性有机碳的输出机理探讨. 相似文献
80.
大气CO2浓度升高对土壤中不同粒级碳的影响 总被引:4,自引:0,他引:4
不同粒级土壤中的碳有着不同的周转规律,在高CO2浓度条件下,它们含量的变化将在一定程度上反映土壤碳是累积还是减少,对明确土壤碳的变化趋势有重要意义.采用田间培养试验初步模拟研究在高CO2浓度条件下土壤不同粒级碳的分布.结果表明,加入秸秆培养1年,由于CO2浓度升高的原因导致在低氮(LN)、常规氮(NN)和高氮(HN)水平下土壤中碳分别增加0.01、1.10、1.22g/kg,表现为粒级〈53μm土壤颗粒中碳分别增加1.53、2.19、2.70g/kg.粒级〈53μmm土壤颗粒碳量的增加,主要是由于其重量分配百分数显著增加36.2%,碳浓度增加5.4%;粒级〉250μm和250~53μm土壤颗粒部分虽然其碳浓度分别增加20.8%和17.3%(P〈0.05),怛由于重量分配百分数分别显著降低22.8%和36.1%,结果碳量降低.试验表明高CO2浓度导致不同粒级土壤的分配及碳浓度的变化;高氮施肥水平下有增加土壤碳量特别是小粒级土壤碳量的趋势. 相似文献