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91.
92.
The natural human female hormones oestrone and 17β-oestradiol have been implicated in the disruption of endocrine systems in some wildlife adjacent to sewage effluents. The sorption behaviour of these two compounds under estuarine conditions was studied by spiking either 2.55 μg of oestrone or 2.65 μg of 17β-oestradiol in kinetic experiments. In equilibrium experiments, 3 ng of oestrone or 3.2 ng of 17β-oestradiol was added in each of the centrifuge tubes. Sorption onto sediment particles was relatively slow, with sorption equilibrium being reached in about 70 and 170 h for oestrone and 17β-oestradiol, respectively. The effects of a variety of environmental parameters on sorption were studied including salinity, sediment concentration (SC), the presence of a third phase, particle size and, also, surfactant concentrations. Results show that although salinity did not induce any statistically significant effect on the sorption of 17β-oestradiol, it did statistically enhance the sorption of oestrone, and a salting constant of 0.3 l mol−1 was derived. The partition coefficient for both compounds decreased with increasing sediment concentration, a phenomenon that has been widely reported and attributed to the presence of colloids (which could enhance dissolved concentrations). In this paper, the true partition coefficients for sediment particles (Kptrue) and colloidal particles (Kctrue) have been calculated, and a Kptrue value of 141 and 102 ml g−1 was obtained for oestrone and 17β-oestradiol, respectively. In addition, Kctrue values for oestrone (222×102 ml g−1) and 17β-oestradiol (135×102 ml g−1) were two orders of magnitude higher than their respective Kptrue values, suggesting that the colloidal particles are significantly stronger sorbents for natural oestrogens than sediment particles. Particles of different sizes were found to have different partition coefficients due to the strong relationships between partition coefficients for the two compounds and particulate organic carbon (POC) contents and specific surface areas (SSAs). The presence of a surfactant was shown to reduce the partition coefficients for the two compounds, although its concentrations being used were higher than those normally found in the natural environment.  相似文献   
93.
崂山花岗岩地区含锶、偏硅酸矿泉水的形成机理   总被引:1,自引:0,他引:1  
报道了崂山花岗岩地区矿泉水的特征。指出其矿泉类型为含锶、偏硅酸型,并讨论了其形成机理。  相似文献   
94.
使用切向流超滤系统得到粒度较均匀的Fe(OH)3胶体,进而对Fe(OH)3胶体粒子与Cu2 的作用进行了研究,并将实验结果与南沙群岛海区表层水中铜与胶体物质结合状况的调查数据进行了比较分析,得到如下结果:(1)在海水介质中,铜在Fe(OH)3胶体上结合的百分率(pH>5)随pH的升高而下降,随着Fe(OH)3胶体浓度的减小而下降?(2)在天然海水介质中,使铜在Fe(OH)3胶体上结合的百分率在50%-70%的有机物浓度为1.0mg·L-1,有机物浓度的增大使铜与无机胶体结合的百分率有下降的趋势?  相似文献   
95.
96.
A model based on that of Kishi et al. (2001) has been extended to 15 compartments including silicon and carbon cycles. This model was applied to Station A7 off Hokkaido, Japan, in the Northwestern Pacific. The model successfully simulated the observations of: 1. a spring bloom of diatoms; 2. large seasonal variations of nitrate and silicate concentrations in the surface water; and 3. large inter-annual variations in chlorophyll-a. It also reproduced the observed features of the seasonal variations of carbon dioxide partial pressure (pCO2)—a peak in pCO2 in winter resulting from deep winter convection, a rapid decrease in pCO2 as a result of the spring bloom, and an almost constant pCO2 from summer through fall (when the effect of increasing temperature cancels the effect of biological production). A comparison of cases with and without silicate limitation shows that including silicate limitation in the model results in: 1. decreased production by diatoms during summer; and 2. a transition in the dominant phytoplankton species, from diatoms to other species that do not take up silicate. Both of these phenomena are observed at Station A7, and our results support the hypothesis that they are caused by silicate limitation of diatom growth. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
97.
东海温度锋的分布特征及其季节变异   总被引:8,自引:4,他引:8  
汤毓祥 《海洋与湖沼》1996,27(4):436-444
根据1934-1988年东海水文观测资料,重点分析东海温度锋的分布特征及其季节变异,并结合近期中日黑潮合作调查研究成果,初步探讨温度锋季节变异和水团演变的关系,所得主要结论是:(1)东海不仅常年存在浙闽沿岸锋,东海北部陆架锋和黑潮锋,而且、春、夏两季,在东海南部还出现一条东海中部出架锋。(2)江海温度锋季节变化的特点是:冬季,锋的宽度和强度皆是表层最强,夏季,表层温度锋仅出现在浙江近岸小范围海域。  相似文献   
98.
Anomalous change of the Antarctic sea ice and global sea level change   总被引:3,自引:0,他引:3  
AnomalouschangeoftheAntarcticseaiceandglobalsealevelchange¥XieSimei;ZouBing;WangYiandBaoChenglan(1.NationalMarineEnvironmentF...  相似文献   
99.
The Princeton Ocean Model with realistic bottom topography has been used to investigate the summer temperature decrease in the past 25 years in Fukuoka Bay. The vertical mixing of the model is expressed by a scheme that effectively includes the influences of interannual variations of tidal currents and wind. The results show that the historical temperature decrease in summer has been caused by tidal currents and wind weakening in the past 25 years in Fukuoka Bay. The weakening of tidal currents and wind gives rise to weakening of the vertical mixing, and to enhancement of the estuarine circulation in the bay. The enhancement of the estuarine circulation activates the inflow of open-ocean water toward Fukuoka Bay. Coastal water in summer has therefore tended to be colder and more saline in the past 25 years. This interannual variation in coastal waters is called “open-oceanization” in this study. On the basis of the numerical model, it is anticipated that the temperature will decrease by 0.2°C in the next 25 years in Fukuoka Bay if the tide and wind weaken persistently as in the present bay.  相似文献   
100.
The biology, population dynamics, and production of Talorchestia brito were studied at two sandy beaches located on the Atlantic (Portugal) and on the Mediterranean (Tunisia) coasts, respectively. The seasonal variation in abundance and the overall densities were similar in both populations. Reproduction occurred from February to September in the Atlantic, and from March to early November in the Mediterranean. The sex ratio was male biased in the Atlantic, and female biased in the Mediterranean. Based on data from the Atlantic population, both abundance and the proportion of reproductive females were positively correlated with temperature, while the proportion of juveniles in the population was positively correlated with temperature and sediment moisture. On average, individuals from the Atlantic were larger than the ones from the Mediterranean. Life span was estimated at six to nine months in the Atlantic, and five to eight months in the Mediterranean. Talorchestia brito was shown to be a semiannual species, with iteroparous females producing two broods per year, and exhibited a bivoltine life cycle. The minimum age required for males' and females' sexual differentiation and for female sexual maturation was shorter in the Mediterranean. Growth production (P) was estimated at 0.19 g m−2 y−1 ash free dry weight (AFDW; 4.3 kJ m−2 y−1) in the Atlantic population, and 0.217 g m−2 y−1 AFDW (4.9 kJ m−2 y−1) in the Mediterranean one. Elimination production (E) was estimated at 0.35 g m−2 y−1 AFDW (7.9 kJ m−2 y−1) in the Atlantic, and 0.28 g m−2 y−1 AFDW (6.3 kJ m−2 y−1) in the Mediterranean. The average annual biomass ( ) (standing stock) was estimated at 0.032 g m−2 in the Atlantic beach, and 0.029 g m−2 in the Mediterranean one, resulting, respectively, in ratios of 5.9 and 7.5 and ratios of 10.8 and 9.6. Like other talitrids, T. brito exhibited geographic variation in morphometrical characteristics, sex ratio, growth rates, life span, and reproduction period, with the Atlantic population presenting a slower life history.  相似文献   
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