SKB (Svensk Kärnbränslehantering AB) is responsible for all handling, transport and storage of the nuclear wastes outside the Swedish nuclear power stations. According to Swedish law, SKB is responsible for an R&D-programme needed to take care of the radwastes. The programme comprises, among others, a general supportive geo-scientific R&D and the Äspö Hard Rock Laboratory (HRL) for more in-situ specific tasks.
Sweden is geologically located in the Fennoscandian shield which is dominated by gneisses and granitoids of Precambrian age. The Swedish reference repository concept thus considers an excavated vault at ca. 500 m depth in crystalline rocks. In this concept (KBS-3), copper canisters with high level waste will be emplaced in deposition holes from a system of tunnels. Blocks of highly compacted swelling bentonite clay are placed in the holes leaving ample space for the canisters. At the final closure of the repository, the galleries are backfilled with a mixture of sand and bentonite. This repository design aims to make the disposal system as redundant as possible. Although the KBS-3 concept is the reference concept, alternative concepts and/or repository lay-outs are also studied. The main alternative, currently under development at SKB, is disposal in boreholes with depths of 4–5 km. The geoscientific research will to a great extent be guided by the demands posed by the performance and safety assessments, as well as the constuctability issues. Some main functions of the geological barrier are fundamental for the long-term safety of a repository. These are: bedrock mechanical stability, a chemically stable environment as well as a slow and stable groundwater flux. The main time-table for the final disposal of long-lived radioactive waste in Sweden foresees the final selection of the disposal system and site during the beginning of next decade. 相似文献
On April 1, 1936, an M6(3/4) earthquake occurred on the Fangcheng-lingshan Fault. This event is the biggest historical earthquake on the coastal seismic zone, South China ever. But so far, no any findings about the surface rupture of this event have been reported. This paper is the first to find several intact surface rupture zones associated with the 1936 Lingshan seismic event, in the areas of Gaotang, Jiaogengping etc. on the northeast segment of the Fangcheng-Lingshan Fault. According to the field work, the surface rupture stretches to 10km and distributes along NE direction in front of Luoyang Mountain, represented by earthquake scarp, extensional fracture, dextrally faulted gully and river system etc. The characteristics of surface ruptures and faulted landforms indicate that the surface rupture is of normal-dextral strike slip faulting. The trenching on this fault exposed that at least three seismic events have been recorded, including two historical earthquake events and the latest one is the 1936 Lingshan M6(3/4) earthquake. These surface rupture zones are the key to the detection of seismogenic structure and the re-estimate of magnitude of this event. The new finding of these surface rupture zones would be particularly significant for the detection of the seismogenic structure of Lingshan M6(3/4) earthquake. 相似文献
To assess the performances of state-of-the-art global climate models on simulating the Arctic clouds and surface radiation balance, the 2001–2014 Arctic Basin surface radiation budget, clouds, and the cloud radiative effects(CREs) in 22 coupled model intercomparison project 6(CMIP6) models are evaluated against satellite observations. For the results from CMIP6 multi-model mean, cloud fraction(CF) peaks in autumn and is lowest in winter and spring, consistent with that from three satellite observation products(Cloud Sat-CALIPSO, CERESMODIS, and APP-x). Simulated CF also shows consistent spatial patterns with those in observations. However,almost all models overestimate the CF amount throughout the year when compared to CERES-MODIS and APP-x.On average, clouds warm the surface of the Arctic Basin mainly via the longwave(LW) radiation cloud warming effect in winter. Simulated surface energy loss of LW is less than that in CERES-EBAF observation, while the net surface shortwave(SW) flux is underestimated. The biases may result from the stronger cloud LW warming effect and SW cooling effect from the overestimated CF by the models. These two biases compensate each other,yielding similar net surface radiation flux between model output(3.0 W/m~2) and CERES-EBAF observation(6.1 W/m~2). During 2001–2014, significant increasing trend of spring CF is found in the multi-model mean,consistent with previous studies based on surface and satellite observations. Although most of the 22 CMIP6 models show common seasonal cycles of CF and liquid water path/ice water path(LWP/IWP), large inter-model spreads exist in the amounts of CF and LWP/IWP throughout the year, indicating the influences of different cloud parameterization schemes used in different models. Cloud Feedback Model Intercomparison Project(CFMIP)observation simulator package(COSP) is a great tool to accurately assess the performance of climate models on simulating clouds. More intuitive and credible evaluation results can be obtained based on the COSP model output. In the future, with the release of more COSP output of CMIP6 models, it is expected that those inter-model spreads and the model-observation biases can be substantially reduced. Longer term active satellite observations are also necessary to evaluate models' cloud simulations and to further explore the role of clouds in the rapid Arctic climate changes. 相似文献
Sorption coefficients measured for PAHs on dissolved humic substances by SPME and FQT were found to be inevitably different and method‐dependent – SPME provides activity‐based and FQT concentration‐based sorption coefficients. Poly(acrylic acid) esters as well‐defined model polymers were used in sorption experiments, leading to the conclusion that short aliphatic chains are more effective in binding PAHs than aromatic moieties. FQT was inappropriate to measure sorption coefficients for the interaction of pyrene with poly(acrylic acid) esters but the experiments revealed a characteristic shift in the fluorescence spectrum. Using pyrene as a probe for the molecular environment in the sorbed state, the observed spectral shift indicated a highly hydrophobic microenvironment. The empirical relationships between lg KDOC and lg KOW were generalized on the basis of a modified Flory‐Huggins concept. Introducing only one sorbent‐specific parameter, the solubility parameter δDOM, the calculation of sorption coefficients became possible for a wide range of HOCs using fundamental data readily available from the literature. Long‐term experiments showed that reactive PAHs (such as acenaphthylene and 9‐methylanthracene) are able to react with HAs under strictly abiotic and anoxic conditions, whereas less reactive PAHs (such as naphthalene and dihydroanthracene) do not form bound residues. The HA reveals two functions in the interaction, behaving as a reaction partner and as a protecting ligand. 相似文献
The New EC Framework Water Directive: Assessment of the Chemical and Ecological Status of Surface Waters The main objective of the draft EC Framework Water Directive is the good quality of all surface waters. The directive provides for an assessment of the chemical status of surface waters (EU‐wide valid environmental quality standards for approximately 30 priority substances) and a five‐stage ecological classification of waters, comprising the stages high, good, moderate, poor, and bad. The starting point for the assessment are the reference conditions, which are defined as corresponding to high water quality and characterising a water status with no significant anthropogenic impact. The reference sites in the various water body types are to be selected using hydromorphological and physico‐chemical parameters and subsequently characterised by means of biological parameters. For surface waters, three groups of characteristics are provided for, namely: 1. with priority the biology – in the case of surface waters – with the four elements phytoplankton, macrophytes/phytobenthos, benthic invertebrate fauna, and fish fauna; 2. supporting the hydromorphology, e.g. flowing waters with the three elements hydrological regime, river continuity, and morphological conditions and 3. supporting the physico‐chemical conditions with the three elements general conditions, specific synthetic pollutants, and specific non synthetic pollutants (other than the priority substances of the chemical status). 相似文献
Selected samples of dissolved organic matter (DOM) isolated by ultrafiltration (UDOM) have been analyzed by thermochemolysis in the presence of tetramethylammonium hydroxide (TMAH). This technique cleaves ester and ether bonds of bio‐ and geological macromolecules and releases monomer subunits and methylates them in situ as their methyl ethers and methyl esters. Compared with conventional pyrolysis, TMAH thermochemolysis avoids decarboxylation of preexisting carboxylic moieties and produces aromatic acids as their methyl esters. Various phenolic derivatives, which might originate from incorporated lignin‐derived structures, from the highly aliphatic and resistant biopolymer cutan and also from proteinaceous materials, were identified among the products produced from UDOM upon thermochemolysis. The presence of lignin derivatives in UDOM indicates input of organic matter derived from terrestrial sources. Various aromatic acids, perhaps representing the final steps in the oxidation of the side‐chain during microbial oxidation of lignin, were released upon TMAH thermochemolysis, suggesting they are structural constituents of the UDOM. Different ratios of lignin‐derived materials, commonly determined using the CuO oxidation method, such as the Δ value, indicative of the amount of lignin present, the acid/aldehyde ratio (Ad/Al)G, indicative of the extent of oxidative degradation of the lignin component, and the syringyl/guaiacyl (S/G) and p‐hydroxyphenyl/guaiacyl (P/G) ratios, indicative of the contribution for the different types of lignin, were determined. 相似文献