云南临沧地区帮卖盆地含铀煤中锗矿的研究   总被引：8，自引：0，他引：8  

张淑苓  王淑英  尹金双 《铀矿地质》1987,(5)

帮卖盆地是一个不对称山间向斜盆地,其基底为海西·燕山期(γ~3_4-γ~2_5)花岗岩体。盖层为新第三纪的含煤碎屑岩。锗矿体大部分存在于N_1~2煤层中。含铀煤主要为变质程度低的褐煤,属于半暗-半亮煤、暗亮煤及亮暗煤。锗在煤中的存在形式:1.主要为腐植酸锗络合物及锗的有机化合物;2.一部分呈吸附状态;3.极少数呈类质同象。  相似文献   

Location and quantitative analysis of OH in coesite     

M. Koch-Müller  Y. Fei  E. Hauri  Z. Liu 《Physics and Chemistry of Minerals》2001,28(10):693-705

 The incorporation of hydrogen (deuterium) into the coesite structure was investigated at pressures from 3.1 to 7.5 GPa and temperatures of 700, 800, and 1100 °C. Hydrogen could only be incorporated into the coesite structure at pressures greater 5.0 GPa and 1100 °C . No correlation between the concentration of trace elements such as Al and B and the hydrogen content was observed based on ion probe analysis (1335 ± 16 H ppm and 17 ± 1 Al ppm at 7.5 GPa, 1100 °C). The FTIR spectra show three relatively intense bands at 3575, 3516, and 3459 cm⁻¹ (ν₁ to ν₃, respectively) and two very weak bands at 3296 and 3210 cm⁻¹ (ν₄ and ν₅, respectively). The band at 3516 cm⁻¹ is strongly asymmetric and can be resolved into two bands, 3528 (ν_2a) and 3508 (ν_2b) cm⁻¹, with nearly identical areas. Polarized infrared absorption spectra of coesite single-crystal slabs, cut parallel to (0 1 0) and (1 0 0), were collected to locate the OH dipoles in the structure and to calibrate the IR spectroscopy for quantitative analysis of OH in coesite (ɛ _{i ,tot}=190 000 ± 30 000 l mol⁻¹ _H2O cm⁻²). The polarized spectra revealed a strong pleochroism of the OH bands. High-pressure FTIR spectra at pressures up to 8 GPa were performed in a diamond-anvil cell to gain further insight into incorporation mechanism of OH in coesite. The peak positions of the ν₁, ν₂, and ν₃ bands decrease linearly with pressure. The mode Grüneisen parameters for ν₁, ν₂, and ν₃ are −0.074, −0.144 and −0.398, respectively. There is a linear increase of the pressure derivatives with band position which follows the trend proposed by Hofmeister et al. (1999). The full widths at half maximum (FWHM) of the ν₁, ν₂, and ν₃ bands increase from 35, 21, and 28 cm⁻¹ in the spectra at ambient conditions to 71, 68, and 105 in the 8 GPa spectra, respectively. On the basis of these results, a model for the incorporation of hydrogen in coesite was developed: the OH defects are introduced into the structure by the substitution Si^4+(Si2)+4O²⁻= ^[4]□^(Si2) + 4OH⁻, which gives rise to four vibrations, ν₁, ν_2a, ν_2b, and ν₃. Because the OH(D)-bearing samples do contain traces of Al and B, the bands ν₄ and ν₅ may be coupled to Al and/or B substitution. Received: 19 December 2000 / Accepted: 23 April 2001  相似文献   

线翼截断方式对大气辐射计算的影响   总被引：2，自引：0，他引：2  

张华  石广玉  刘毅 《气象学报》2007,65(6):968-975

在大气辐射传输计算方法中,有3种基本方法,即,逐线积分方法,k-分布方法和带模式方法。其中,逐线积分方法是最精确的计算大气透过率的方法,本文根据透过率计算方式的不同,将逐线积分方法分为追线积分法和追点积分法。由于逐线积分计算需要耗费大量的计算时间,在大气遥感和大气探测业务中使用时,必须减少计算成本,提高计算速度。本文在追线积分法的基础上,给出了简化的逐线积分的基本方法,在保证同样计算精度的同时,大大提高了计算速度。对在精确的和简化的逐线积分下,不同线翼截断方式(CUTOFF)对吸收系数、大气透过率和冷却率的影响进行了更详细的探讨。通过数值试验发现,对谱线线翼的截断方式是影响辐射计算精度和计算速度的重要因子。在不同压力下,用CUTOFF=2计算的吸收系数误差最大;对CUTOFF=1,在大多数取样点上误差都小于2%;对CUTOFF=3或4,对绝大多数取样点上计算的吸收系数误差都在5%以内,但所用的计算时间却明显减少。大气低层的透过率对不同的计算方法和不同的线翼截断方式不敏感;对大气高层,无论是对精确的还是简化的逐线积分方法,当CUTOFF=2时的透过率结果与其他线翼截断方式的结果差别较大。通过比较,本文给出线翼截断的优选方案。  相似文献   

General absorbing boundary conditions for dynamic analysis of fluid-saturated porous media     

T. Akiyoshi  X. Sun  K. Fuchida 《Soil Dynamics and Earthquake Engineering》1998,17(6):397-406

General absorbing boundary conditions based on Biot's two-phase mixture theory and paraxial approximation is presented for the dynamic analysis of fluid-saturated porous media with isotropic, transverse isotropic, and anisotropic properties. For the last two cases, the equivalent Lame's constants, under conditions of uniqueness, are introduced to facilitate the analytical solutions. The numerical results show that the proposed absorbing boundary can greatly suppress spuriously reflected waves and efficiently model the far field of the system with sufficient accuracy.  相似文献   

A simple two-band semi-analytical model for retrieval of specific absorption coefficients in coastal waters     

《ISPRS Journal of Photogrammetry and Remote Sensing》2014

A non-linear iterative method is used to replace the traditional spectral slope technique in initializing the total absorption decomposition model. Based on comparison of absorption coefficient by QAA and two-band semi-analytical model (TSAA) models with field measurements collected from the West Florida Shelf waters and Bohai Sea, it is shown that both models are effective in estimating absorption coefficients from the West Florida Shelf waters, but the TSAA model is superior to the QAA model. Use of the TSAA model in estimating absorption coefficient in the West Florida Shelf and Bohai Sea decreases the uncertainty of estimation by 1.3–74.7% from the QAA model. The TSAA model’s sensitivity to the input parameters was evaluated by varying one parameter and keeping the others fixed at their default values. Our results indicate that the TSAA model has quite a strong noise tolerance to addressing the field data of the total absorption coefficient.  相似文献   

萃取分离—石墨炉原子吸收光谱法测定铅锌矿中的铟     

赵星  张代云  刘锐 《云南地质》2014,33(3):417-420

样品经硝酸、氢氟酸分解除硅,加热硫酸冒烟除尽硝酸、氢氟酸,利用铟与氢溴酸能生成稳定的络合物并被乙酸丁酯萃取的性质,将铟与其它干扰离子分离并富集.使用MOLAARM6（Thermo Electron Corporation）石墨炉原子吸收分光光度计,以钒为机体改进剂,测定铅锌矿中的铟.方法检出限为LD=0.012ug/ml.实验结果令人满意.  相似文献   

田口方法用于地质样品中痕量超痕量金三种分析方法的对比     

陈爱平  孙自军  李振 《岩矿测试》2014,33(1):51-56

目前测定地质样品痕量、超痕量金常用的三种方法是活性炭吸附富集-发射光谱法、泡塑吸附富集-石墨炉原子吸收光谱法、活性炭吸附富集-电感耦合等离子体质谱法,这三种方法的检出限在0.1~0.3ng/g之间,由于矿石矿物的组成非常复杂,因此在有效富集和分离的基础上,采用合适的分析手段,能够对地质样品提供满意的分析结果。为保证试样要求的灵敏度和准确性,分析方法的选择需求应根据具体试样情况和实验室条件而定。根据田口玄一博士在测量工程学中提出的信噪比(S/N)能测量系统抗干扰能力,评价测量系统的稳健性和可靠性这一观点,本文利用田口测量质量控制理论,评价地质样品中痕量、超痕量金常用的上述三种分析测试方法,对这三种分析方法三个金标准物质的测试数据进行分类处理,计算S/N值和相对标准不确定度,通过比较三者的S/N值和相对标准不确定度值,确定更为可靠的测试体系。分析结果表明,对于地质样品中痕量金(含量大于1 ng/g)的测试,三种分析方法均能够满足要求;对于超痕量金(含量小于1 ng/g)的测试,活性炭吸附富集-电感耦合等离子体质谱法是较好的测试方案。  相似文献   

Molecular Hydrogen in high redshift Damped Lyman-α systems     

Patrick Petitjean 《Astrophysics and Space Science》2002,281(1-2):467-470

I describe briefly the status of an ongoing mini-survey for molecular hydrogen in high-redshift Damped Lyman-α systems using UVES at the VLT. H₂ is detected in about 30% of the cases. When H2 is not detected the molecular fraction f = 2N(H₂)/(2N(H₂)+N(HI) is smaller than 10^-5. Therefore, most of the DLA systems arise in warm (T > 3000 K) and diffuse neutral gas embedded in a strong UV flux. The very recent detection of HD molecules in a Damped Lyman-α system at z _abs = 2.337 demonstrates the possibility to discuss the high redshift chemistry. This revised version was published online in September 2006 with corrections to the Cover Date.  相似文献   

RAPID ESTIMATION OF THE NUMBER OF COELUTING COMPONENTS IN LIQUID CHROMATOGRAPHY BY FACTOR ANALYSIS     

CHENGBOSHEN  THOMASJ.VICKERS  CHARLESK.MANN 《地理学报(英文版)》1991,(5)

Evaluation of the results of factor analysis of sets of spectroscopically detected chromatograms is carriedout by examining the shapes of the abstract factors.This is done either by visual inspection or by analysisof the power density spectra produced from them.Owing to constraints imposed by the column functionand the spectroscopic instrument function,the information content of the chromatograms necessarilyoccurs at low spatial frequencies.As a consequence,it appears as relatively broad features in the abstractchromatograms and as a peak in the low-frequency region of the corresponding power density plot.Onthe basis of examination of the power density distribution,a well-defined distinction is made betweenprimary and secondary abstract factors.The major uncertainty encountered in determining the numberof chemical components appears to arise from effects of contaminants in reagents.  相似文献   

用卫星高光谱数据提取德兴铜矿区植被污染信息   总被引：24，自引：7，他引：17  

刘圣伟  甘甫平  王润生 《国土资源遥感》2004,15(1):6-10,31

在深入分析研究德兴铜矿矿区植被光谱特征的基础上,利用美国EO-1卫星Hyperion高光谱数据,通过反演表征植物生理状态的光谱特征参数(红边位置和最大吸收深度)变异,提取与污染相关的信息,获取了矿山植被污染生态效应概况,为矿山污染的诊断和监测提供新技术和知识支撑。  相似文献