冻融作用对地气系统能量交换的影响分析   总被引：7，自引：12，他引：7  

李述训  南卓铜  赵林 《冰川冻土》2002,24(5):506-511

通过对温度波在地层内传播过程问题的分析研究, 讨论土在冻结和融化过程对地气系统能量交换的影响, 并以亚粘土为例应用近似方法计算了在冻结和融化过程地气系统能量交换和地温变化特征, 同时将相同条件下发生冻融作用与不发生冻融作用情况地气系统热交换量进行了比较. 结果表明, 冻融作用使地气系统热交换加强, 同时吸热和放热的过程也发生了改变.  相似文献   

质量传输和同位素交换:流动几何学和交换机制     

刘伟 《地学前缘》2002,9(4):423-428

耦合的质量传输和动力学限制的同位素交换模型综合考虑了平流、扩散、热液弥散 ,以及岩石与水之间的不平衡同位素交换等项因素。把耦合模型应用于 2个构造环境下的古热液系统 ,进而解释稳定同位素数据。对于造成环绕浅成侵入岩体分布的18O亏损环带的流体的流动几何学 ,以及浅部正断层流体流动的几何学 ,耦合模型提供了不同于单一同位素交换模型的解释。耦合模型也提供了关于同位素相对交换速率和同位素交换机制的信息。结果表明 ,断层带的动态重结晶促进了表面反应 ,进而便利了同位素交换 ;在化学不反应性和未变形的矿物中 ,同位素交换可能受制于固态条件下的扩散。  相似文献   

单道扫描电感耦合等离子体发射光谱法测定地质样品中的微量稀土元素     

郭振华  张立英  杜百娟 《化工矿产地质》2003,25(1):57-60

采用Na_2O_2熔融矿样,水提取,加三乙醇胺、EGTA做掩蔽剂。经氢型阳离子交换树脂交换分离富集稀土元素,由于选择了合适的仪器条件及测定波长,有效地消除了电感耦合等离子体发射光谱法(ICP-AES)测定过程中的基体干扰和光谱干扰。应用于地质样品中的稀土元素分析,获得了满意的准确度、精密度及检出限。  相似文献   

超声提取-气相色谱法测定覆盖区土壤中的六六六和滴滴涕   总被引：4，自引：2，他引：4  

李军 《岩矿测试》2003,22(4):248-253

将超声波提取技术引入到覆盖区土壤样品六六六、滴滴涕组分的预处理中，建立了超声提取，磺化法净化，气相色谱测定的分析方法。对被测组分在超声波提取中的稳定性进行了试验，对超声提取时间、提取温度、提取溶剂用量以及磺化净化过程可能导致组分损失的各种相关条件逐个试验筛选，采用样品加标回收法对六六六、滴滴涕的8种组分进行了两种浓度的精密度和准确度试验，RSD值均小于10％，平均回收率92．5％-103．9％。方法对各种异构体的六六六、滴滴涕的最低检测浓度为0．30-3．89ng／g。  相似文献   

Determination of Halogens (F, Cl, Br, I), Sulfur and Water in Seventeen Geological Reference Materials   总被引：5，自引：0，他引：5  

Agnès Michel  Benoît Villemant 《Geostandards and Geoanalytical Research》2003,27(2):163-171

Fluorine, chlorine, bromine, iodine and sulfur were determined in seventeen geological reference materials after extraction by pyrohydrolysis. Fluorine, Cl and S (as sulfate ions) were determined in the extraction solution by ion chromatography with detection limits of around 0.2 mg l⁻¹. Bromine and I were measured by ICP-MS with detection limits of 1 μg l⁻¹ for Br and 0.1 μg l⁻¹ for I. For rock samples, using normal extraction conditions (500 mg of sample and 100 ml of final solution) detection limits were 40 mg kg⁻¹ for F and Cl, 15 mg kg⁻¹ for S, 0.2 mg kg⁻¹ for Br and 0.02 mg kg⁻¹ for I. These detection limits may be improved by increasing the amount of sample and hence the concentration of the final solution. Water was also determined using an extraction technique based on H₂O degassing, reduction on zinc at 1000 °C and H₂ manometry. Our results for fluorine, chlorine, sulfur and water are in good agreement with literature data. Very few reference materials have recommended values for bromine and especially for iodine. Among the analysed samples, three are new reference materials: BHVO-2, BCR-2 and AGV-2.  相似文献   

环电流区中性原子观测特性模拟研究   总被引：2，自引：1，他引：2       下载免费PDF全文

沈超  刘振兴 《地球物理学报》2003,46(1):1-1

为了给双星计划中性原子(ENA)探测仪的研制提供可靠 的理论依据，并为未来中性原子探测数据的分析及研究做好准备，针对双星轨道初步模拟计 算了双星ENA探测仪对磁暴时中性原子的观测特性. 建立了磁暴主相期间环电流离子分布的 一 个近似理论模式，并模拟计算了极轨卫星在极区上空、赤道面以及其他位置上对不同强度磁 暴主相期间环电流区ENA空间角分布及能谱的观测结果. 研究表明，存在环电流区方向和南 北极区环电流粒子沉降带两个中性原子强度极大区域；磁暴越强烈，注入区高度越低，环电 流区观测到的ENA通量越高；处于有利位置的ENA探测器可分辨注入区内边界或注入前沿；EN A探测器能够分辨环电流带离子分布的不均匀性；由于离子交换截面的差异，H，O，He 3种E NA的能谱分布不同；在10～80keV能谱范围内通量较强，易于观测；环电流区H，O两种ENA 通 量较强，有利于观测；而环电流区He ENA通量很弱，不易于观测. 模拟计算研究表明，双星 极轨卫星能够对环电流区ENA进行有效探测；低纬轨道上的ENA探测器也能够对环电流区ENA 进行一些观测；ENA探测器的研制应重视低、中能量范围ENA的探测.  相似文献   

Atmospheric Methyl Iodide at Cape Grim, Tasmania, from AGAGE Observations     

D. S. Cohan  G. A. Sturrock  A. P. Biazar  P. J. Fraser 《Journal of Atmospheric Chemistry》2003,44(2):131-150

Atmospheric mixing ratios of methyl iodide (CH₃I) and other methyl halides have been measured at Cape Grim, Tasmania (41°S, 145°E), since early 1998 as part of the Advanced Global Atmospheric Gases Experiment (AGAGE). This paper analyses about 1700 ambient air CH₃I measurements from the 14-month period (March 1998–April 1999). Mixing ratios peaked during the summer, despite faster photolytic loss, suggesting local oceanic emissions were about 2.2–3.6 times stronger in summer than in winter. Back trajectories show that CH₃I levels are strongly dependent on air mass origin, with highest mixing ratios in air from the Tasman Sea/Bass Strait region and lowest levels in air originating from the Southern Ocean at higher latitudes. CH₃I mixing ratios were not well correlated with other methyl halides in unpolluted marine air. The large variations with season and air mass origin suggest that high frequency, continuous data from key locations will make a significant contribution to the understanding of sources and sinks of this important short-lived atmospheric species.  相似文献   

A STUDY ON TYPHOON MOVEMENT PART Ⅲ:EFFECT OF THE HORIZONTAL MOMENTUM EXCHANGE BETWEEN TYPHOONS AND ENVIRONMENT     

贺海晏  董惠菁 《热带气象学报(英文版)》1997,3(1):1-10

Two semi-asymmetric flow patterns of typhoons are chosen to qualitatively determine the effect of exchange of horizontal momentum between inflow and outflow layers and the environment on the motion of typhoons. The results show that only the asymmetric flow component (residual after azimuthal mean flow has been removed) could cause a net momentum input into or output from a typhoon and therefore contribute to the changes in speed and direction of the typhoon movement. A typhoon with major inflow and/or outflow channels on its right (left) side would tend to accelerate and turn left (decelerate and turn right); On the other hand, a typhoon with major inflow and/or outflow channels in the rear (front) semicircle would tend to accelerate and turn right (decelerate and turn left).  相似文献   

矿物流体包裹体中的羧酸     

曾贻善  刘家齐 《矿物岩石地球化学通报》1997,(1)

矿物流体包裹体中的羧酸曾贻善刘家齐（北京大学地质系，北京１００８７１）（地矿部宜昌地质矿产研究所，宜昌４４３００３）关键词矿物包裹体浸取液羧酸离子色谱分析分子中含有羧基官能团（—ＣＯＯＨ）的物质称为羧酸。Ｆｅｉｎ［１］和Ｓｈｏｃｋ［２］曾概述羧酸在自...  相似文献   

The respiratory environment of the Namib Desert Golden Mole     

Roger S. Seymour  Mary K. Seely 《Journal of Arid Environments》1996,32(4):453-461

We measured the partial pressure of oxygen (PO₂) in the interstitial gas surrounding the sand-swimming Namib moleEremitalpa granti namibensis. At a sand temperature of 26 °C, which produced a nearly maximal rate of oxygen consumption, thePO₂near the noses of the animals averaged only 0·9 kPa (6·7 Torr) below the level in the free atmosphere. High oxygen availability was a result of the notably low metabolic rate in the 20 g mammals and the dry, porous and metabolically inactive nature of dune sand. A mathematical model indicated that normal mammals weighing 200 g or more could comfortably exist completely encased in dune sand. We concluded that the moles' small size and low metabolic rate are not adaptations to hypoxia or hypercapnia underground but are probably related to low food availability and the energetic cost of foraging in their desert environment.  相似文献