Carbonyl products of the gas phase reaction of ozone with 1,1-disubstituted alkenes     

Eric Grosjean  Daniel Grosjean 《Journal of Atmospheric Chemistry》1996,24(2):141-156

Carbonyl products have been identified and their formation yields measured in experiments involving the gas phase reaction of ozone with 1,1-disubstituted alkenes at ambient T and p=1 atm. of air. Sufficient cyclohexane was added to scavenge the hydroxyl radical in order to minimize OH-alkene and OH-carbonyl reactions. Formation yields (carbonyl formed/ozone reacted) of primary carbonyls were close to the value of 1.0 that is consistent with the mechanism: O₃+R₁R₂C=CH₂ (HCHO+R₁R₂COO)+(1–)(R₁COR₂+H₂COO) where formaldehyde and the ketone R₁ COR₂ are the primary carbonyls and R₁R₂COO and H₂COO are the corresponding biradicals. Measured values of were 0.58–0.82 and indicate modest preferential formation of formaldehyde and the disubstituted biradical as compared to the ketone and the biradical H₂COO. Carbonyls other than the primary carbonyls were identified. Their formation is discussed in terms of subsequent reactions of the disubstituted biradicals R₁R₂COO. Similarities and differences between disubstituted and monosubstituted biradicals are outlined.  相似文献   

“雅安天漏”研究 III：特征、物理量结构及其形成机制   总被引：9，自引：5，他引：4  

曾庆存  宇如聪  彭贵康 《大气科学》1994,18(6):649-659

本文的这一部分首先进一步分析了第二部分的预报结果,结果发现,在本文第二部分所建立的模式,不仅较好地预报出了24小时总降水量,而且也较好地预报出了“雅安天漏”的降水特征和降水中的物理结构。模式基本上抓住了形成雅安降水的主要影响因子。然后通过一系列精心设计的数值模拟试验得到了形成雅安降水的可能机制。  相似文献   

安徽董岭花岗岩类的构造特征及侵位机制   总被引：5，自引：1，他引：4       下载免费PDF全文

董树文  何大林 《地质科学》1993,28(1):10-20

安徽怀宁董岭花岗岩类底辟滑覆构造体系是长江中下游地域独特的构造形式。花岗岩底辟构造是在中生代华北地块与扬子地块碰撞背景下通过气球膨胀机制侵位至盖层内(燕山期),形成了围绕董岭几何中心的环状或半环状接触变质和韧性变形岩块。该花岗岩类其内部变形明显,岩相分带、分期清晰,围岩顶盖保存完好,围岩变质均匀,变形强烈,滑覆断层发育,糜棱岩典型等为特征,是一个罕见的盖层中花岗岩类底辟构造。后期在其北侧和东侧被月山—白子山冲断岩块所超覆。  相似文献   

基于网络药理学与分子对接技术探讨青蛇方外用治疗湿疹的作用机制          下载免费PDF全文

王家辉  王军文  彭湘宁 《应用海洋学学报》2024,40(2):189

目的：基于网络药理学与分子对接技术探讨青蛇方外用治疗湿疹的作用机制。方法：应用TCMSP和UniProt数据库平台查询青蛇方组方的有效活性成分及靶基因,与疾病靶基因取交集后构建蛋白质-蛋白质相互作用(PPI)网络;应用DAVID数据库,对潜在核心作用靶点基因进行基因本体（GO）功能、京都基因与基因组百科全书（KEGG）通路富集分析。利用分子对接原理论证青蛇方生物活性成分与核心靶点的分子结合能力。结果：筛选出青蛇方有效成分63种,作用靶点99个;主要有β-谷甾醇、2,4,7-三羟基-9,10-二氢菲、靛蓝素、豆甾醇、色氨酸等关键成分;转录因子AP-1（JUN）、肿瘤坏死因子（TNF）、原癌基因（RELA）、干扰素γ（IFNG）、转化生长因子-β1（TGF-β1）等核心基因。关键信号通路有癌症信号通路、恰加斯病通路、弓形体病通路、脂质和动脉粥样硬化通路等,分子对接结果显示活性成分与核心靶点基因结合能力较强。结论：青蛇方外用可以通过多种活性成分、多种通路有效抑制免疫炎症反应,促进免疫系统正常运行,从而达到治疗湿疹的目的。  相似文献   

On the spatial characteristic of the short term and imminent anomalies of underground water behaviors before strong earthquake     

杜学彬  刘耀炜  倪明康 《地震学报(英文版)》1997,10(4):523-533

Ｏｎｔｈｅｓｐａｔｉａｌｃｈａｒａｃｔｅｒｉｓｔｉｃｏｆｔｈｅｓｈｏｒｔ┐ｔｅｒｍａｎｄｉｍｍｉｎｅｎｔａｎｏｍａｌｉｅｓｏｆｕｎｄｅｒｇｒｏｕｎｄｗａｔｅｒｂｅｈａｖｉｏｒｓｂｅｆｏｒｅｓｔｒｏｎｇｅａｒｔｈｑｕａｋｅＸＵＥ－ＢＩＮＤＵ（杜学彬）...  相似文献   

A continuous and mechanistic representation of calcite reaction-controlled kinetics in dilute solutions at 25°C and 1 atm total pressure     

Takeshi Arakaki  Alfonso Mucci 《Aquatic Geochemistry》1995,1(1):105-130

  相似文献   

洛安江干渠老菁湾滑坡分析     

周华志 《工程地质学报》1995,3(1):86-91

洛安江水库灌溉工程是贵州黔北万亩以上骨干工程之一,中华人民共和国成立初期建成。１９９１年＂７．５Ｆ＂洪灾,连续大暴雨,河水暴涨,倒灌暗河,产生高静、动水压力作用。岸坡岩体受不利结构面组合,发生顺层岩质滑坡,破坏干渠,严重影响灌溉。本文根据滑坡破坏情况,对滑坡产生的地质环境、滑坡特征、滑坡形成机理（滑坡形式和破坏机理,各种稳定性分析与评价）,以及产生滑坡原因进行了初步分析。  相似文献   

Hamiltonian perturbation theory on a manifold     

Francesco Fassò 《Celestial Mechanics and Dynamical Astronomy》1995,62(1):43-69

This paper deals with Hamiltonian perturbation theory for systems which, like Euler-Poinsot (the rigid body with a fixed point and no torques), are degenerate and do not possess a global system of action-angle coordinates. It turns out that the usual methods of perturbation theory, which are essentially local being based on the construction of normal forms within the domain of a local coordinate system, are not immediately usable to study perturbations of these systems, since degeneracy makes impossible to control that the system does not fall into a singularity of the coordinates. To overcome this difficulty, we develop a global formulation of Hamiltonian perturbation theory, in which the normal forms are globally defined on the phase space manifold. The key for this study lies in the geometry of the fibration by the invariant tori of an integrable degenerate Hamiltonian system, which is described by some generalizations of the Liouville-Arnol'd theorem and is reviewed in the paper. As an application, we provide a global formulation of Nekhoroshev's theorem on the stability for exponentially long times.  相似文献   

A combined study of macroseismic data and focal mechanisms applied to the West-Bohemian earthquake,Czechoslovakia     

J. Zahradník  M. Antonini  G. Grünthal  J. Janský  D. Procházková  E. Schmedes  A. Špičak  J. Zedník 《Pure and Applied Geophysics》1990,133(1):53-71

The main shock of the West-Bohemian earthquake swarm, Czechoslovakia, (magnitudem=4.5, depthh=10 km) exhibits an irregular areal distribution of macroseismic intensities 6° to 7° MSK-64. Four lobes of the 6° isoseismal are found and the maximum observed intensity is located at a distance of 8 km from the instrumentally determined epicentre. This distribution can be explained by the energy flux of the directS wave generated by a circular source, the hypocentral location and focal mechanism of which are taken from independent instrumental studies. The theoretical intensity, which is assumed to be logarithmically proportional to the integrated squared ground-motion velocity (i.e.,I=const+log v ² (t)dt), fits the observed intensity with an overall root-mean-square error less than 0.5°. It is important that the present intensity data can also be equally well explained by the isotropic source. The fit was attained by means of a horizontally layered model though large fault zones and an extended sedimentary basin suggest a significant lateral heterogeneity of the epicentral region. The results encourage a broader application of the simple modelling technique used.  相似文献   

Seasonal variation of atmospheric dimethylsulfide at Amsterdam Island in the southern Indian Ocean     

B. C. Nguyen  N. Mihalopoulos  S. Belviso 《Journal of Atmospheric Chemistry》1990,11(1-2):123-141

Daily measurements of atmospheric concentrations of dimethylsulfide (DMS) were carried out for two years in a marine site at remote area: the Amsterdam Island (37°50S–77°31E) located in the southern Indian Ocean. DMS concentrations were also measured in seawater. A seasonal variation is observed for both DMS in the atmosphere and in the sea-surface. The monthly averages of DMS concentrations in the surface coastal seawater and in the atmosphere ranged, respectively, from 0.3 to 2.0 nmol l^-1 and from 1.4 to 11.3 nmol m^-3 (34 to 274 pptv), with the highest values in summer. The monthly variation of sea-to-air flux of DMS from the southern Indian Ocean ranges from 0.7 to 4.4 mol m^-2 d^-1. A factor of 2.3 is observed between summer and winter with mean DMS fluxes of 3.0 and 1.3 mol m^-2 d^-1, respectively.  相似文献