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101.
A 95-day field trial on the bioremediation of oil in beach sediment using Osmocote and chitosan was conducted on an inter-tidal foreshore in Singapore. Osmocote was the key factor in enhancing nutrient levels in sediments, the metabolic activity of the indigenous microbial biomass, and the biodegradation of aliphatics and polycyclic aromatic hydrocarbons (PAHs) with ring number of 2 and 3. In contrast, chitosan did not enhance these parameters in the presence of Osmocote. However, the addition of chitosan to Osmocote amended sediments significantly enhanced biodegradation of recalcitrant 4–6-ring PAHs. This is most likely due to the high oil adsorbancy capacity of chitosan, which enhances the bioavailability of high ring number PAHs to the microbial biomass. 相似文献
102.
Barbora Topinkova Kamil Nesetril Josef Datel Ondrej Nol Petr Hosl 《Hydrogeology Journal》2007,15(5):961-976
The geochemical processes, water–rock interactions and stable isotopes distribution (δ13C of DIC and δ18O and δ34S of \({\text{SO}}^{{{\text{2 - }}}}_{{\text{4}}} \)) were investigated in the gasoline-contaminated aquifer at the Hnevice site, 50 km northwest of Prague, Czech Republic. Diesel, gasoline and oil leaks originate from a large fuel storage area causing heavy contamination of the saturated and unsaturated zones in an area of about 0.7 km2. Groundwater investigations were conducted using five multilevel sampler wells with emphasis on redox parameters and degradation by-products and a solid-phase study focused on iron speciation and determination of principal and secondary minerals. Based on the study of groundwater and solid-phase geochemistry, four different geochemical zones were described. Zone I is thought to be background consisting of an aerobic aquifer and the absence of reduced species in significant concentrations. Zone II is situated in the plume core with methanogenic, sulphate and iron-reducing conditions accompanied by ankerite and kutnahorite precipitates and significant depletion of the oxidation capacity of the aquifer. Zone III is a mixing (corona) zone, situated at the fringe of the plume with high biodegradation rates and Fe(III)-precipitants. In zone IV, reoxidation of Fe(II) minerals (with e.g. the occurrence of psilomelane and cornelite) is typical. 相似文献
103.
This geochemical survey defines the typical features of representative oils from the major Colombian basins, and proposes a classification scheme useful for hydrocarbon exploration. This work is based on properties of whole oils such as API gravity, sulfur, vanadium and nickel concentrations, and gas chromatography fingerprints. The framework is completed by inclusion of biomarker parameters derived from GCMS and GCMSMS analysis.Oils from the basins of the Middle Magdalena Valley, Upper Magdalena Valley, Sinú - San Jacinto, Putumayo-Caguan, Lower Magdalena Valley and Catatumbo were assessed. Conclusions were drawn regarding possible sources of origin, oil families, degree of thermal evolution, biodegradation, mixing and refreshing, and inferences regarding exploration implications.The oils from the Middle Magdalena Valley and Upper Magdalena Valley (intermontane basins) and Putumayo (foreland basin), except those from the Caguan area, are oils with similar characteristics. In these three cases the oils are probably coming from source rocks intervals deposited in a marine Cretaceous platform, with variable carbonate/siliciclastic features. In these basins there are no oils derived from Tertiary source rocks.In Sinú-San Jacinto and Lower Magdalena Valley basins the main proportions of oils comes from very proximal environments, probably deltaic type, of Tertiary age with a minor proportion of oils coming from Cretaceous source rocks of marine anoxic environment (the only marine Cretaceous oils discovered so far in the Sinú-San Jacinto and Lower Magdalena Valley basins).The oils from Eastern Foothills of the Eastern Cordillera, look to be derived mainly from proximal Cretaceous source rocks with some mixing of oils derived from Tertiary strata. In the Catatumbo basin there are oils derived mainly from Cretaceous source rocks and some from Tertiary source rocks.Regarding the processes after entrapment, in all of the basins, the biodegradation effects were observed in varying degrees. These processes are dominant toward more quiescent regions, beyond the areas with more tectonic activity, far from the foothills of the Eastern Cordillera. Instead, close to the Eastern Cordillera are more common the paleobiodegradation processes due to reburial of younger molasses. The effects of mixing or refreshing are remarkable close to the Eastern Cordillera foothills in Llanos, Middle Magdalena Valley, and Upper Magdalena Valley basins. 相似文献