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101.
本工作使用一次培养法初步研究了Cr(VI)对菱形硅藻和隐藻的毒性,实验结果表明,当Cr(VI)浓度大于16ppb时,则对其生长率产生抑制作用,其72小时EC_(50)值分别为260ppb和230ppb.根据活性点位模式计算了Cr(VI)与藻体的结合常数,约为2×10~5藻体中Cr含量与培养液中Cr浓度有关,两者近似指数关系,根据藻体中Cr含量和溶液中Cr的浓度,估计每个硅藻细胞与Cr最大结合容量约为5×10~(-17)mol/cell.  相似文献   
102.
本文阐述了生物海洋学的内容及其研究状况。根据我国沿海特点,建议我国今后对生物海洋学研究的重点是:1.对不同水域初级生产力的研究。2.对沿海小型底栖生物在海洋生态系统能流和物质循环中的作用研究。3.河口,有代表性海域可溶性有机物(DOM)、颗粒有机物(POM)的来源、数量分布、化学组成,以及在海洋食物链的作用和鱼虾产卵场变动关系的研究。4.沿海养殖环境生原要素循环、环境容量及病害发生的环境研究。5.海洋生物对重要有机污染物和海藻毒素的吸收、富集、代谢、在食物链传递,以及生态影响和生态监测研究。6.沿海植物性碎屑向近海输运,及其在食物链中的作用研究。7.浮游生物的群集、支配群集因素,以及和渔业关系的研究。8.选择代表性海域开展物质通量的研究。  相似文献   
103.
The accumulation of nine heavy metals in fine-grained sediments from the mangrove fringed coast of French Guiana is evaluated. The dynamic features of the South American tropical coastline, from the Amazon to the Orinoco Rivers, result in mangrove sediments being alternately submitted to phases of erosion and net sedimentation a few tens of years long. This process influences the distribution of the heavy metals associated with these frequently re-mobilized deposits. Sedimentary cores and mangrove plant samples were collected, at different seasons, in various swamps characterized by different properties (content of sedimentary organic matter, distance from sea water and fresh water). The ranges of measured concentrations expressed in μmol g 1 were the following: Cu (0.06 to 0.61), Co (0.12 to 0.68), Pb (0.08 to 0.18), Ni (0.32 to 0.76), Cr (0.61 to 1.40), Zn (1.25 to 5.94), Mn (4.36 to 45.4) and Fe (441 to 1128). No differences were found between sediments from mangroves developing upstream and downstream of urban areas, i.e. Cayenne and Kourou. This suggests that the content of mangrove sediments in heavy metals along the coastline of French Guiana is essentially the result of the continuous alternation of accumulation and transport phases occurring upstream after departing from the Amazon watershed. The sources of this heavy metals content are thus difficult to identify. However it is well known that the alluvium produced by the natural erosion of the Amazonian soils is naturally enriched in mercury. Also, the run-off from gold mining activities is known to contribute to mercury pollution. Ranges in total Hg were between 0.15 and 2.57 nmol g 1, with mean values close to 0.41 nmol g 1, and were clearly correlated with total organic carbon except for some outstanding high values, which may be a result of rapid geochemical changes. Heavy metal concentrations showed variations with depth. The redox conditions and the decay processes affecting the organic matter control the cycling of iron and manganese, which in turn control the concentrations and associations of heavy metals. These preliminary results suggest that the variations in heavy metal content with depth or between mangrove areas result largely from diagenetic processes rather than changes in metal input resulting from local human activities.  相似文献   
104.
Rates of transformation, recycling and burial of nitrogen and their temporal and spatial variability were investigated in deep-sea sediments of the Porcupine Abyssal Plain (PAP), NE Atlantic during eight cruises from 1996 to 2000. Benthic fluxes of ammonium (NH4) and nitrate (NO3) were measured in situ using a benthic lander. Fluxes of dissolved organic nitrogen (DON) and denitrification rates were calculated from pore water profiles of DON and NO3, respectively. Burial of nitrogen was calculated from down core profiles of nitrogen in the solid phase together with 14C-based sediment accumulation rates and dry bulk density. Average NH4 and NO3-effluxes were 7.4 ± 19 μmol m−2 d−1 (n = 7) and 52 ± 30 μmol m−2 d−1 (n = 14), respectively, during the period 1996–2000. During the same period, the DON-flux was 11 ± 5.6 μmol m−2 d−1 (n = 5) and the denitrification rate was 5.1 ± 3.0 μmol m−2 d−1 (n = 22). Temporal and spatial variations were only found in the benthic NO3 fluxes. The average burial rate was 4.6 ± 0.9 μmol m−2 d−1. On average over the sampling period, the recycling efficiency of the PON input to the sediment was 94% and the burial efficiency hence 6%. The DON flux constituted 14% of the nitrogen recycled, and it was of similar magnitude as the sum of burial and denitrification. By assuming the PAP is representative of all deep-sea areas, rates of denitrification, burial and DON efflux were extrapolated to the total area of the deep-sea floor (>2000 m) and integrated values of denitrification and burial of 8 ± 5 and 7 ± 1 Tg N year−1, respectively, were obtained. This value of total deep-sea sediment denitrification corresponds to 3–12% of the global ocean benthic denitrification. Burial in deep-sea sediments makes up at least 25% of the global ocean nitrogen burial. The integrated DON flux from the deep-sea floor is comparable in magnitude to a reported global riverine input of DON suggesting that deep-sea sediments constitute an important source of DON to the world ocean.  相似文献   
105.
南、北方坛紫菜多糖结构特征的比较研究   总被引:5,自引:1,他引:5  
对南方产(1987年3月采)和移植北方养殖(1988年11月采)的两种坛紫菜的热水和冷水提取多糖进行了层析分级,用~(13)C-NMR和IR光谱研究了各级分的化学结构特征,结果表明,南北方坛紫菜多糖分别主要由用 1.0mol/L和0.5mol/L NaCl从DEAE—Sephadex A_(50)层析柱洗脱下的带电荷的琼胶糖分子组成;~(13)C-NMR谱图表明坛紫菜主要由琼胶糖结构及其生物前体(硫酸基结合在L-半乳糖的第6位碳上)构成,且甲基化琼胶糖在南方坛紫菜中的含量明显比北移坛紫菜高,这是坛紫菜由南方移植北方后的明显差异。  相似文献   
106.
P, Fe, Mn, and S species were analyzed in water samples from the sediment-water interface collected at four seasonally different times during the course of a year at two sampling sites in the southern basin of Lake Lugano (Lago di Lugano). The results reveal the strong influence of the biogeochemical processes in the sediment on the chemical composition of the lake water above. Consumption of oxygen and nitrate under oxic to microoxic conditions in the water column as well as sequential release of reduced manganese and iron under anoxic conditions was observed as a direct or indirect consequence of microbially mediated degradation of organic matter. The seasonal pattern observed for the release and the retainment of dissolved reduced iron and manganese correlates well with the one for dissolved phosphate. Iron, manganese and phosphorus cycling are coupled tightly in these sediments. Both sediment types act as sinks for hydrogen sulfide and sulfate. An inner-sedimentary sulfur cycle is proposed to couple iron, manganese and phosphorus cycling with the degradation of organic matter. Nutrient cycling at the sediment-water interface might thus be driven by a microbially regulated electron pumping mechanism. The results contribute to a better understanding of the role of sediment processes in the lake's internal phosphorus cycle and its seasonal dynamics.  相似文献   
107.
沿海地区氯盐侵蚀会对混凝土结构造成严重的耐久性问题,混凝土设计使用寿命难以保障。对于新建工程,若在自由水含量较高混凝土养护期进行电迁阻锈处理,则有利于电迁移性阻锈剂在钢筋周围聚集以达到更佳的阻锈效果。为此,针对两种电迁移性阻锈剂对处于氯盐侵蚀环境中的混凝土适用性展开研究,并测试了干湿循环前后混凝土内钢筋电化学参数、氯离子扩散特征及钢筋周围电迁移性阻锈剂含量研究两种电迁移性阻锈剂对混凝土耐久性保障的作用。结果表明,试验中养护期介入电迁阻锈后试件阻锈效果良好,经过干湿循环后钢筋腐蚀电位正向高于-162.6 m V,同时,钢筋附近出现明显的阻锈剂聚集现象,能保持钢筋的钝化状态。  相似文献   
108.
This study examined the nitrogen cycling associated with agricultural production and environmental load in central Hokkaido. The nitrogen (N) budget analysis model offers a new set of tools for evaluating N cycling in agro-ecosystems. The cycling index (CI) is a useful tool for estimating optimal N flows in farmlands. The fertilization index (FI) is a useful indicator for characterizing the N flows related to farms. Using these parameters, we analyzed all farm systems to estimate the optimal N cycling for minimizing N pollution in groundwater and maximizing agricultural production in mountain regions of Japan. The results showed that the critical N application rate (chemical fertilizer + manure) was 143.3 kg N ha^-1 y^-1. The critical inter-system input (chemical fertilizer N, imported food and feed N, and natural supplied N) was 169.2 kg N ha^-1y^-1.  相似文献   
109.
Here we present Holocene organic carbon, nitrogen, sulphur, carbon isotope ratio and macrofossil data from a small freshwater lake near Sisimiut in south‐west Greenland. The lake was formed c. 11 cal ka BP following retreat of the ice sheet margin and is located above the marine limit in this area. The elemental and isotope data suggest a complex deglaciation history of interactions between the lake and its catchment, reflecting glacial retreat and post‐glacial hydrological flushing probably due to periodic melting of local remnant glacial ice and firn areas between 11 and 8.5 cal ka BP. After 8.5 cal ka BP, soil development and associated vegetation processes began to exert a greater control on terrestrial–aquatic carbon cycling. By 5.5 cal ka BP, in the early Neoglacial cooling, the sediment record indicates a change in catchment–lake interactions with consistent δ13C while C/N exhibits greater variability. The period after 5.5 cal ka BP is also characterized by higher organic C accumulation in the lake. These changes (total organic carbon, C/N, δ13C) are most likely the result of increasing contribution (and burial) of terrestrial organic matter as a result of enhanced soil instability, as indicated by an increase in Cenococcum remains, but also Sphagnum and Empetrum. The impact of glacial retreat and relatively subdued mid‐ to late Holocene climate variation at the coast is in marked contrast to the greater environmental variability seen in inland lakes closer to the present‐day ice sheet margin. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
110.
Ships are a dominant vector for biological invasions through ballast water discharge (BWD) and hull fouling. Here, we provide a first comprehensive analysis of shipping in Alaska, summarizing (a) the number, type and origin of vessel arrivals to Alaska for 2003 and 2004, (b) the spatial and temporal variation in vessel traffic, and (c) the available data on ballast water discharge in order to prioritize locations for tracking biological invasions. Most arrivals were passenger vessels, followed by ferries and fishing vessels, all of which carried little ballast water. Regional and seasonal patterns in arrivals and BWD were unevenly distributed among vessel types. The majority of vessels reporting BWD were from foreign ports, and most of this ballast was untreated. The largest volumes of ballast were from tankers at Valdez and Kenai Peninsula ports. Although Alaska has few documented invasions, opportunities for ship-mediated transfer now appear high and warrant further scrutiny.  相似文献   
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