Application of allochthonous organic carbon and phosphorus forms in the interpretation of past environmental conditions   总被引：2，自引：0，他引：2  

Changwei Lü  Jiang He  Huimin Sun  Hongxi Xue  Ying Liang  Saruli Bai  Ying Sun  Lili Shen  Qingyun Fan 《Environmental Geology》2008,55(6):1279-1289

Organic matter in sediments, for instance, carbon, nitrogen and phosphorus, can be used to reconstruct the paleoecological and pollution history of lakes and their catchment basins. In this paper, the contents of allochthonous organic carbon (allochthonous OC) and autochthonous organic carbon (autochthonous OC) in sediment cores taken from Wuliangsuhai Lake and Daihai Lake in northern China are quantified by using a binary model, and phosphorus forms in the sediment cores from the two lakes are extracted by sequential extraction techniques. The results indicate that the palaeoenvironment and paleoclimate of Daihai Lake and its catchment basin in the recent 250 years can be well reconstructed based on the content of allochthonous OC. The climate was relatively humid and warm in the period of 1865–2005, while relatively dry and cold in the period of 1765–1865. The sedimentary information of allochthonous OC in the 22–42-cm portion of the sediment cores in Daihai Lake corresponds to the final cold fluctuation of the Little Ice Age that occurred since the Middle Holocene. The difference of phosphorus forms in the sediment cores between the two lakes indicates that phosphorus input to the lakes and the correlation between phosphorus forms and distribution and the changes of environment are influenced by the eutrophication mechanisms and environmental conditions of the two lakes.  相似文献   

Site characterization for CO<Subscript>2</Subscript> geologic storage and vice versa: the Frio brine pilot,Texas, USA as a case study     

Christine Doughty  Barry M. Freifeld  Robert C. Trautz 《Environmental Geology》2008,54(8):1635-1656

Careful site characterization is critical for successful geologic storage of carbon dioxide (CO₂) because of the many physical and chemical processes impacting CO₂ movement and containment under field conditions. Traditional site characterization techniques such as geological mapping, geophysical imaging, well logging, core analyses, and hydraulic well testing provide the basis for judging whether or not a site is suitable for CO₂ storage. However, only through the injection and monitoring of CO₂ itself can the coupling between buoyancy flow, geologic heterogeneity, and history-dependent multi-phase flow effects be observed and quantified. CO₂ injection and monitoring can therefore provide a valuable addition to the site-characterization process. Additionally, careful monitoring and verification of CO₂ plume development during the early stages of commercial operation should be performed to assess storage potential and demonstrate permanence. The Frio brine pilot, a research project located in Dayton, Texas (USA) is used as a case study to illustrate the concept of an iterative sequence in which traditional site characterization is used to prepare for CO₂ injection and then CO₂ injection itself is used to further site-characterization efforts, constrain geologic storage potential, and validate understanding of geochemical and hydrological processes. At the Frio brine pilot, in addition to traditional site-characterization techniques, CO₂ movement in the subsurface is monitored by sampling fluid at an observation well, running CO₂-saturation-sensitive well logs periodically in both injection and observation wells, imaging with crosswell seismic in the plane between the injection and observation wells, and obtaining vertical seismic profiles to monitor the CO₂ plume as it migrates beyond the immediate vicinity of the wells. Numerical modeling plays a central role in integrating geological, geophysical, and hydrological field observations.  相似文献   

川东北飞仙关组储层固体沥青地球化学特征及其气源指示意义   总被引：6，自引：1，他引：5  

王铜山  耿安松  孙永革  熊永强  刘德汉  李霞 《沉积学报》2008,26(2):340-348

运用有机岩石学、有机地球化学、催化加氢热解、GC—IRMS等方法和技术,深入研究了川东北飞仙关组储层固体沥青及可能烃源岩的地球化学特征。研究认为,飞仙关组储层固体沥青反射率高,双反射明显,为非均质结构储层焦沥青;在碳酸盐岩储层的各种孔隙中,呈脉状、球粒状、角片状或块状等他形充填,具有中间相结构和镶嵌状结构特征,反映其高温热变质成因;元素组成有S/C高、H/C低的特点,其固体碳同位素组成与长兴组烃源岩干酪根相似。储层固体沥青的可能烃源岩发育于还原—弱氧化咸水沉积环境,有机质来源于水生藻类;氯仿沥青“A”饱和烃甾萜类生物标志物对比表明,上二叠长兴组烃源岩是主要来源,飞仙关组、下志留统烃源岩亦有贡献;催化加氢产物饱和烃及其正构烷烃单体碳同位素组成显示,坡2井飞仙关组储层固体沥青与罐5井飞仙关组烃源岩具有明显的亲缘关系,这也可作为飞仙关组海槽相烃源岩对飞仙关组气藏有贡献的佐证。  相似文献   

Kinetic Modeling the Formation of Low-mature Gases and Analysis of the Possibility to Be Accumulated     

SHUAI Yanhu  WANG Hui  ZHANG Shuichang  SU Aiguo 《《地质学报》英文版》2008,82(3):537-542

At present, shallow gases have received much attention due to low cost in exploration and production. Low-mature gases, as one significant origin to shallow gas, turns to be an important research topic. The present understanding of low-mature gases is confined within some geological cases, and few laboratory studies have been reported. Therefore, the potential and characters of low- mature gases are not clear up to now. Here, two premature samples （one coal and the other shale） were pyrolyzed in a gold confined system. The gaseous components including hydrocarbon gases and non-hydrocarbon gases were analyzed. Based on kinetic modeling, the formation of low-mature gases was modeled. The results showed that during low mature stage, about 178 mL/gTOC gas was generated from the shale and 100 mL/gTOC from the coal. Two third to three fourth of the generated gases are non-hydrocarbon gases such as H2S and CO2. The total yields of C1-5 for the two samples are almost the same, 30-40 mL/gTOC, but individual gaseous hydrocarbon is different. The shale has much lower C1 but higher C2-5, whereas the coal has higher C1 but lower C2-5. Hydrocarbon gases formed during low-mature stage are very wet. The stable carbon isotope ratios of methane range from -40‰ to -50‰ （PDB）, in good consistence with empiric criterion for low-mature gases summed up by the previous researchers. The generation characters suggest that the low-mature gases could be accumulated to form an economic gas reservoir, but most of them occur only as associated gases.  相似文献   

A Study of the Migration and Accumulation Efficiency and the Genesis of Hydrocarbon Natural Gas in the Xujiaweizi Fault Depression   总被引：1，自引：1，他引：0  

LI Jijun  LU Shuangfang  XUE Haitao  HUO Qiuli  XU Qingxia 《《地质学报》英文版》2008,82(3):629-635

In order to investigate the migration and accumulation efficiency of hydrocarbon natural gas in the Xujiaweizi fault depression, and to provide new evidence for the classification of its genesis, a source rock pyrolysis experiment in a closed system was designed and carried out. Based on this, kinetic models for describing gas generation from organic matter and carbon isotope fractionation during this process were established, calibrated and then extrapolated to geologic conditions by combining the thermal history data of the Xushen-1 Well. The results indicate that the coal measures in the Xujiaweizi fault depression are typical ＂high-efficiency gas sources＂, the natural gas generated from them has a high migration and accumulation efficiency, and consequently a large-scale natural gas accumulation occurred in the area. The highly/over matured coal measures in the Xujiaweizi fault depression generate coaliferous gas with a high δ^13C1 value （〉 -20‰） at the late stage, making the carbon isotope composition of organic alkane gases abnormally heavy. In addition, the mixing and dissipation through the caprock of natural gas can result in the negative carbon isotope sequence （δ^13C1 〉δ^13C2 〉δ^13C3 〉δ^13C4） of organic alkane gases, and the dissipation can also lead to the abnormally heavy carbon isotope composition of organic alkane gases. As for the discovery of inorganic nonhydrocarbon gas reservoirs, it can only serve as an accessorial evidence rather than a direct evidence that the hydrocarbon gas is inorganic. As a result, it needs stronger evidence to classify the hydrocarbon natural gas in the Xujiaweizi fault depression as inorganic gas.  相似文献   

二氧化碳注入煤层多用途研究   总被引：1，自引：0，他引：1  

陈润  秦勇  申建  王国玲  刘国伟 《煤田地质与勘探》2008,36(6)

为了减轻环境污染,提高煤层气产率,增加能源储备,根据煤层气地质学和生物气的基本理论,提出二氧化碳(CO2)注入煤层多种用途这一新观点。研究结果显示:煤对CO2具有很强的吸附能力,可将煤层作为CO2的储集层;煤具有优先吸附CO2而滞后吸附甲烷(CH4)的特性,向煤层注入CO2可大大提高煤层气的采收率;产甲烷菌具有利用CO2生成CH4的能力,新生成的CH4成为能源储备的有益补充。可见,CO2注入煤层不仅可有效减少温室气体的排放,强化煤层甲烷产出,而且为新能源生物CH4的生成提供了基质。  相似文献   

夜间灯光数据的区域能源消费碳排放空间化     

顾羊羊  乔旭宁  樊良新  关中美  冯德显  高亚红 《测绘科学》2017,42(2)

针对传统统计数据无法准确、客观地测量区域能源消费碳排放量并展现地理分布差异的问题,该文提出利用DMSP/OLS卫星数据稳定夜间灯光数据和能源消费数据,模拟区域碳排放空间分布,揭示区域碳排放分布特征和规律。以河南省为研究区的分析结果表明:1995—2012年河南省能源消费碳排放总量逐年增加,郑州、洛阳和新乡市的能源消费碳排放量年均增长较快,三门峡、济源市的碳排放量增长较慢;2012年各地区能源消费碳排放强度高于1995年,18年间地均碳排放强度均呈现出明显的地域分布差异规律,主要集中在郑州、洛阳和安阳市区域内。基于夜间灯光数据模拟区域能源消费碳排放具有一定的可行性,该数据能比较可靠地反映区域能源消费碳排放的时空动态变化规律。  相似文献   

利用普鲁士蓝/活性炭复合材料回收提钾后的盐湖卤水中铯          下载免费PDF全文

谢非  于业笑  屈小荣  王石军  晋冠平 《盐湖研究》2017,25(3):32-38

以亚铁氰化钾为单源前驱体,以活性炭为载体,采用超声辅助均匀沉淀法,制备了普鲁士蓝/活性炭复合材料(PB/AC)。通过场发射扫描电子显微镜、X-射线衍射、X-射线光电子能谱和傅立叶变换红外光谱技术,对PB/AC的形貌、结构和组成进行了表征。结果表明:立方体结构的PB微晶均匀地分布在活性炭表面。研究考察了PB/AC对水溶液中铯离子(Cs~+)的吸附和脱附性能。在pH=7、45℃和180 min条件下,PB/AC对Cs~+的最大吸附量为49.17 mg/g;在pH=2、45℃和240 min条件下,Cs~+的脱附率可达88.5%。  相似文献   

碳纤维布用于砖砌体抗震加固的试验研究   总被引：49，自引：1，他引：49  

赵彤  张晨军  谢剑  李浩菊 《地震工程与工程振动》2001,21(2):89-95

通过4片碳纤维布加固砖砌体在周期反复荷载作用下受力性能的试验，研究了粘贴碳纤维布来增强砖砌体抗震能力这种加固方法的有效性。本文研究了碳纤维布加固砖砌体的受力特性，分析了碳纤维布的用量以及贴布方式等因素对砖砌体抗震加固效果的影响。在此基础上，本文提出了碳纤维布加固砖砌体抗剪承载力的简化计算方法，可以满足实际工程设计的要求。  相似文献   

A SIMULATION OF CO_2 UPTAKE IN A THREE DIMENSIONAL OCEAN CARBON CYCLE MODEL     

金心  石广玉 《Acta Meteorologica Sinica》2001,(1)

A three-dimensional ocean carbon cycle model which is a general circulation model coupledwith simple biogeochemical processes is used to simulate CO_2 uptake by the ocean.The OGCMused is a modified version of the Geophysical Fluid Dynamics Laboratory modular ocean model(MOM2).The ocean chemistry and a simple ocean biota model are included.Principal variablesare total CO_2,alkalinity and phosphate.The vertical profile of POC flux observed by sedimenttraps is adopted,the rain ratio,a ratio of production rate of calcite against that of POC,and thebio-production efficiency should be 0.06 and 2 per year,separately.The uptake of anthropogenicCO_2 by the ocean is studied.Calculated oceanic uptake of anthropogenic CO_2 during the 1980s is2.05×10~(15)g(Pg)per year.The regional distributions of global oceanic CO_2 are discussed.  相似文献