Dissolved silica concentrations and reactions in pore waters from continental slope sediments offshore from Cape Hatteras, North Carolina, USA     

Joan D. Willey  Arthur J. Spivack 《Marine Chemistry》1997,56(3-4)

The pore water concentrations of dissolved silica in sediment cores from the continental slope offshore from Cape Hatteras, North Carolina, varied from 150 to almost 700 μ,M with depth in the top 40 cm of sediment. Sediment cores from 630 to 2010 m depth had very similar profiles of dissolved silica in their pore waters, even though these cores came from regions greatly different in slope, topography, sedimentation rate, and abundance of benthic macrofauna. Cores from 474 to 525 m were more variable, both with respect to pore water dissolved silica profiles, and with respect to sediment texture. Experiments indicate that both the rate of dissolution of silica and the saturation concentration decrease as sediment depth below the sediment-seawater interface increases. These data are consistent with depletion of a reactive silica phase in surface sediment, which may be radiolarian tests, or the alteration of biogenic silica to a less reactive form over time. Experimental results suggest that the pore water dissolved silica concentration in sediments below the top few centimeters may be higher than the sediments could now achieve. The flux of dissolved silica out of these sediments is estimated to be 15 μmoles cm⁻² yr⁻¹.  相似文献   

Nature and origin of the Vani manganese deposit, Milos, Greece: an overview     

A. Liakopoulos  G. P. Glasby  C. T. Papavassiliou  J. Boulegue 《Ore Geology Reviews》2001,18(3-4)

The Vani manganese deposit is located in the rugged NW sector of Milos Island. It occurs within the Vani volcano-sedimentary basin, which is underlain by dacitic domes and flows of Upper Pliocene age (3.5–2.0 Ma). The end of the emplacement of the dacites was marked by the collapse of the magma chamber, which resulted in a huge pyroclastic episode and the deposition of a thick layer of pyroclastic material within a shallow submarine basin. This pyroclastic material subsequently compacted to form the volcaniclastic sandstone, which became the host for the manganese ore beds which were about 4 m thick in the two sections studied. Hydrothermal fluids penetrated these sandstone horizons via fractures and fissures to produce the manganese deposit. The permeable nature of the sandstone facilitated the retention of the hydrothermal fluids within these layers. This permitted the fluids to cool slowly and deposit the manganese oxides almost quantitatively. Formation of the hydrothermal manganese deposit took place fairly rapidly over a period of several tens of thousands of years at most. Strong tectonic activity resulted in rapid uplift of the area which elevated the deposit above sea level.Two generations of manganese oxides have been identified within this deposit; the first generation consists of pyrolusite and ramsdellite; the second generation of oxides of the isostructural series cryptomelane–hollandite–coronadite plus hydrohetaerolite characterized by high contents of K, Ba, Pb and Zn, respectively. This sequence is the result of a two-stage process of formation of the manganese-oxide minerals in which a second high-salinity hydrothermal fluid enriched in Ba, Pb and Zn as a result of the dissolution of sulphide minerals remineralized the original manganese-oxide assemblage. It is this two-stage process of formation, which was mainly responsible for the unique characteristics of this deposit. Although formed in a submarine setting, the deposit shows marked differences in mineralogy and composition from known submarine hydrothermal manganese deposits and is most analogous to the epithermal vein deposits of the southwestern United States.  相似文献   

Rural Local Economic Development and Land Restitution in South Africa: The Case of Schmidtsdrift,Northern Cape     

D.E. Philander  C.M. Rogerson 《Singapore journal of tropical geography》2001,22(1):74-89

Local Economic Development is (LED) an activity of increasing importance in the developing world as globalisation produces new roles for local governments. As compared to a growing number of urban initiatives for LED, rural LED initiatives are relatively undeveloped. In this paper, the focus is upon South Africa, where the post‐apartheid government has sought to encourage both urban and rural LED initiatives. Programmes of land reform and restitution in South Africa result in the resettlement or return to the land of communities formerly dispossessed under apartheid. A critical element of planning for successful resettlement is the implementation of LED programmes. Schmidtsdrift in Northern Cape is examined as an example of participatory LED in a developing rural context. Rural LED in South Africa is distinguished by its focus upon poverty alleviation in the context of addressing the legacies of apartheid.  相似文献   

Edge wave and non-trapped modes of the 25 april 1992 Cape Mendocino tsunami     

F. I. González  K. Satake  E. F. Boss  H. O. Mofjeld 《Pure and Applied Geophysics》1995,144(3-4):409-426

The 25 April 1992 Cape Mendocino earthquake generated a tsunami characterized by both coastal trapped edge wave and non-trapped tsunami modes that propagated north and south along the U.S. West Coast. Both observed and synthetic time series at Crescent City and North Spit are consistent with the zero-order edge wave mode solution for a semi-infinite sloping beach depth profile. Wave amplitudes at Crescent City were about twice that observed at North Spit, in spite of the fact that the source region was three times farther from Crescent City than North Spit. The largest observed amplitude was due to an edge wave which arrived almost three hours after the initial onset of the tsunami; since such waves are highly localized nearshore, this suggests that the enhanced responsiveness at Crescent City is at least partly due to local dynamic processes. Furthermore, the substantially delayed arrival of this wave, which was generated at the southern end of the Cascadia Subduction Zone, has significant implications for hazard mitigation efforts along the entire U.S. West Coast. Specifically, this study demonstrates that slow-moving but very energetic edge wave modes could be generated by future large tsunamigenic earthquakes in the CSZ, and that these might arrive unexpectedly at coastal communities several hours after the initial tsunami waves have subsided.  相似文献   

Subtidal variability of transverse flow off a cape     

Arnoldo?Valle–LevinsonEmail author  Mary Catherine?Brown 《Ocean Dynamics》2003,53(3):166-175

Time series of velocity profiles at two Chesapeake Bay entrance sites were used to characterize the subtidal variability of transverse flows off a cape. A shallow sampling site was located near Cape Henry over 6 m of water and separated from a deep site, 20 m deep, by a distance of 4 km. The velocity profiles showed that wind-induced subtidal variations in general masked curvature effects (centrifugal accelerations) that may produce secondary circulation associated with tidal flow around a cape. Such secondary circulation, consisting of flow away from the cape at surface and toward the cape at depth, was observed only during periods of weak winds. Most of the time, transverse flows were unidirectional throughout the water column and moved in opposite directions at the two sites examined. This caused convergence of transverse flow between the two sites under the influence of northerly winds and divergence of transverse flow with southwesterly winds. In addition to unidirectional and curvature-induced secondary flows, other modes of subtidal variability consisted of (1) two-layered responses with surface flow toward the cape, and (2) three-layered responses. These two- and three-layered structures were observed more frequently at the deep site, where greater stratification is expected, than at the shallow site.Responsible Editor: Iris Grabemann  相似文献   

The annual cycle of peroxides and ozone in marine air at Cape Grim, Tasmania     

G. P. Ayers  S. A. Penkett  R. W. Gillett  B. Bandy  I. E. Galbally  C. P. Meyer  C. M. Elsworth  S. T. Bentley  B. W. Forgan 《Journal of Atmospheric Chemistry》1996,23(3):221-252

The concentration of gas-phase peroxides has been measured almost continuously at the Cape Grim baseline station (41° S) over a period of 393 days (7702 h of on-line measurements) between February 1991 and March 1992. In unpolluted marine air a distinct seasonal cycle in concentration was evident, from a monthly mean value of>1.4 ppbv in summer (December) to <0.2 ppbv in winter (July). In the summer months a distinct diurnal cycle in peroxides was also observed in clean marine air, with a daytime build-up in concentration and decay overnight. Both the seasonal and diurnal cycles of peroxides concentration were anticorrelated with ozone concentration, and were largely explicable using a simple photochemical box model of the marine boundary layer in which the central processes were daytime photolytic destruction of ozone, transfer of reactive oxygen into the peroxides under the low-NO_x ambient conditions that favour self-reaction between peroxy radicals, and continuous heterogeneous removal of peroxides at the ocean surface. Additional factors affecting peroxides concentrations at intermediate timescales (days to a week) were a dependence on air mass origin, with air masses arriving at Cape Grim from higher latitudes having lower peroxides concentrations, a dependence on local wind speed, with higher peroxides concentrations at lower wind speeds, and a systematic decrease in peroxides concentration during periods of rainfall. Possible physical mechanisms for these synoptic scale dependencies are discussed.  相似文献   

Regional Sources of Methyl Chloride, Chloroform and Dichloromethane Identified from AGAGE Observations at Cape Grim, Tasmania, 1998–2000     

M. L. Cox  G. A. Sturrock  P. J. Fraser  S. T. Siems  P. B. Krummel  S. O'Doherty 《Journal of Atmospheric Chemistry》2003,45(1):79-99

There are large uncertainties in identifying and quantifying the natural and anthropogenic sources of chloromethanes – methyl chloride (CH₃Cl), chloroform (CHCl₃) and dichloromethane (CH₂Cl₂), which are responsible for about 15% of the total chlorine in the stratosphere. We report two years of in situ observations of these species from the AGAGE (Advanced Global Atmospheric Gas Experiment) program at Cape Grim, Tasmania (41° S, 145° E). The average background levels of CH₃Cl, CHCl₃ and CH₂Cl₂ during 1998–2000 were 551± 8, 6.3± 0.2 and 8.9± 0.2 ppt (dry air mole fractions expressed in parts per 10¹²) respectively, with a two-year average amplitude of the seasonal cycles in background air of 25, 1.1 and 1.5 ppt respectively. The CH₃Cl and CHCl₃ records at Cape Grim show clear episodes of elevated mixing ratios up to 1300 ppt and 55 ppt respectively, which are highly correlated, suggesting common source(s). Trajectory analyses show that the sources of CH₃Cl and CHCl₃ that are responsible for these elevated observations are located in coastal-terrestrial and/or coastal-seawater regions in Tasmania and the south-eastern Australian mainland. Elevated levels of CH₂Cl₂ (up to 70 ppt above background) are associated mainly with emissions from the Melbourne/Port Phillip region, a large urban/industrial complex (population 3.5 million) 300 km north of Cape Grim.Now at the Centre for Atmospheric ChemistryNow at School of Environmental Sciences  相似文献   

Coastal geomorphic chronosequences across broad spatiotemporal scales. Metrical observations from the Cape Verde hotspot     

Nicolás Ferrer-Valero  Luis Hernández-Calvento 《地球表面变化过程与地形》2020,45(3):511-525

The study of the coastal landscapes of hotspot oceanic islands through comprehensive structural metrics and ecological estimators represents an opportunity to explore geomorphological transformations and broad spatiotemporal scale features of coastal evolution. As part of this approach, a new metrical comparative analysis is presented in this study, comprising four islands in different evolutionary stages. They belong to the Cape Verde archipelago, which forms a double insular chain in which an east–west gradient in age and evolution is particularly evident across the southern chain. A space-for-time (SFT) substitution approach is applied to the coasts of (1) Fogo, in the shield stage; (2) Santiago, in the early post-erosional stage; (3) São Vicente, in the advanced post-erosional stage; and (4) Boa Vista, in the last erosional stage. From the obtained spatial distributions and frequencies of landforms, the coastal landscapes of these islands are compared in relation to their (i) geomorphic composition, using similarity indices (Whittaker, β_w, Sorensen, C_s) and nestedness estimators (NOFD, WNODF), (ii) geomorphic abundance, using morpho-assembling densities (D_gm), and (iii) geomorphic diversity, using six alpha-diversity indices (Richness, S, Menhinick, D_MN, Simpson, D, Shannon, H', Berger-Parker, d, and Brillouin, HB). An advanced geomorphological taxonomy is implemented for areas with limited open-access data, including a set of planform features captured through scale-frequency decomposition. Photographic, cartographic and fieldwork data are used for landform identification at 1200 random sampling points, empirically determined by a bootstrap method. The results show a chronological ordering of the compared variables and a possible co-evolution towards an increase in organizational geomorphic complexity of coastal systems at broad space-timescales. The method proposed in this study can contribute, from a metrical perspective, to finding new long-term evolutionary features and constitutes an advance in the development of an integrated model of coastal evolution in oceanic islands. © 2019 John Wiley & Sons, Ltd.  相似文献   

The age and growth of hottentot seabream Pachymetopon blochii before and after the South African linefish state of emergency in 2000     

MW Farthing  AC Winkler  K Anderson  S Kerwath  C Wilke  WM Potts 《African Journal of Marine Science》2018,40(2):187-196

The hottentot seabream Pachymetopon blochii is a small-sized (maximum 2.67 kg) sparid endemic to southern Africa. It is an important target in South Africa's Western Cape traditional linefishery, particularly in the absence of more valuable pelagic species (such as Thyrsites atun and Seriola lalandi). In 2000, South Africa's linefishery was declared to be in a state of emergency, and commercial fishing effort was consequently reduced by 70%. A subsequent increase in stock biomass and intraspecific competition, coupled with environmental changes, were hypothesised to have thereafter altered the growth rate of hottentot, from 2000 to 2010. This study aimed to revise outdated age–growth models for the hottentot by using modern techniques (sectioned otoliths), and to compare age–growth relationships before and after the declared linefish state of emergency. The maximum age observed was 19 years, with no difference in the growth rate between sexes (p = 0.39–0.43) or time-periods (p = 0.96). Although the growth rate did not change, there is evidence that the age structure of the stock changed between time-periods as a result of changes in fishing pressure between 2000 and 2010. The enhanced recent growth model for hottentot, described as L_t = 418.063 (1 – e^{?0.104(t – [?4.709])}) (pooled sexes; n = 206), indicates a considerably slower growth rate for this species than was proposed previously using whole otoliths and has major implications for effective stock management.  相似文献   

Distribution, origin and transport process of boulders deposited by the 2004 Indian Ocean tsunami at Pakarang Cape, Thailand     

Kazuhisa Goto  Suchana A. Chavanich 《Sedimentary Geology》2007,202(4):821-837

The tsunami of 2004 in the Indian Ocean transported thousands of meters-long boulders shoreward at Pakarang Cape, Thailand. We investigated size, position and long axis orientation of 467 boulders at the cape. Most of boulders found at the cape are well rounded, ellipsoid in shape, without sharp broken edges. They were fragments of reef rocks and their sizes were estimated to be < 14m³ (22.7t). The distribution pattern and orientation of long axis of boulders reflect the inundation pattern and behavior of the tsunami waves. It was found that there is no clear evidence indicating monotonous fine/coarse shoreward trends of these boulders along each transect line. On the other hand, the large boulders were deposited repeatedly along the three arcuate lines at the intertidal zone with a spacing of approximately 136m interval. This distribution pattern may suggest that long-lasting oscillatory flows might have repositioned the boulders and separated the big ones from small. No boulders were found on land, indicating that the hydraulic force of the tsunami wave rapidly dissipated on reaching the land due to the higher bottom friction and the presence of a steep slope. We further conducted numerical calculation of tsunami inundation at Pakarang Cape. According to the calculation, the sea receded and the major part of the tidal bench (area with boulders at present) was exposed above the sea surface before the arrival of the first tsunami wave. The first tsunami wave arrived at the cape from west to east at approximately 130min after the tsunami generation, and then inundated inlands. Our calculation shows that tsunami wave was focused around the offshore by a small cove at the reef edge and spread afterwards in a fan-like shape on the tidal bench. The critical wave velocities necessary to move the largest and average-size boulders by sliding can be estimated to be approximately 3.2 and 2.0m/s, respectively. The numerical result indicates that the maximum current velocity of the first tsunami wave was estimated to be from 8 to 15m/s between the reef edge and approximately 500m further offshore. This range is large enough for moving even the largest boulder shoreward. These suggest that the tsunami waves that were directed eastward, struck the reef rocks and coral colonies, originally located on the shallow sea bottom near the reef edge, and detached and transported the boulders shoreward.  相似文献