Fe(Ⅱ)/针铁矿复合系统对水中橙黄G的吸附-还原脱色研究     

赵丹  肖丹玲  何广平  吴宏海 《岩石矿物学杂志》2015,34(1):97-102

系统研究了Fe(Ⅱ)/针铁矿复合系统对偶氮染料橙黄G(简称OG)的吸附-还原脱色机理,重点考察了反应条件p H值、Fe(Ⅱ)与OG摩尔比对OG还原脱色效果的影响。研究结果表明,矿物表面结合态Fe(Ⅱ)能够有效提高还原脱色反应速率;OG脱色反应非常符合准一级反应动力学方程,速率常数(k)随p H值的升高、亚铁离子吸附量的增加而显著增大;当OG初始浓度为50 mg/L、Fe(Ⅱ)与OG的摩尔比为27.0时,Fe(Ⅱ)/针铁矿复合系统对OG的去除脱色率在弱碱性条件下1 h内可达到100%。该系统对OG去除脱色的高效性是界面吸附与还原协同作用的结果。该研究可为有效应用Fe(Ⅱ)/针铁矿复合系统在缺氧环境中的污染修复提供理论指导。  相似文献   

Estimating the global potential of water harvesting from successful case studies     

《Global Environmental Change》2020

Water harvesting has been widely applied in different social-ecological contexts, proving to be a valuable approach to sustainable intensification of agriculture. Global estimates of the potential of water harvesting are generally based on purely biophysical assessments and mostly neglect the socioeconomic dimension of agriculture. This neglect becomes a critical factor for the feasibility and effectiveness of policy and funding efforts to mainstream this practice. This study uses archetype analysis to systematically identify social-ecological regions worldwide based on >160 successful cases of local water harvesting implementation. We delineate six archetypal regions which capture the specific social-ecological conditions of the case studies. The archetypes cover 19% of current global croplands with hotspots in large portions of East Africa and Southeast Asia. We estimate that the adoption of water harvesting in these cropland areas can increase crop production up to 60–100% in Uganda, Burundi, Tanzania and India. The results of this study can complement conventional biophysical analysis on the potential of these practices and guide policy development at global and regional scales. The methodological approach can be also replicated at finer scales to guide the improvement of rainfed agricultural.  相似文献   

九孔鲍养殖水体中产酶菌群的研究     

王志  蔡俊鹏  宋志萍  温其标 《广东海洋大学学报》2005,25(3):43-47

为了解九孔鲍养殖环境中细菌生理菌群的生态作用,对分离自养殖水体的33株菌株的产酶能力和种类进行了研究。结果表明,具有分泌胞外蛋白酶、脂肪酶和纤维素酶能力的菌株分别为39.4%、57.6%和30.3%;在这33株菌中,产至少一种胞外酶的菌株比例高达63.6%。API鉴定结果表明,在有能力分泌胞外蛋白酶、脂肪酶和纤维素酶的菌株中,弧菌菌群所占的比例分别为46%、42%和40%,而其中河流弧菌又占各弧菌菌群比例的83.3%、62.5%和100%。充分阐明弧菌,尤其是河流弧菌为优势菌,在鲍鱼养殖微生物态中起的重要作用。  相似文献   

Detecting subtle hydrochemical anomalies with multivariate statistics: an example from ‘homogeneous’ groundwaters in the Great Artesian Basin,Australia     

Bethany O'Shea  Jerzy Jankowski 《水文研究》2006,20(20):4317-4333

The major ion composition of Great Artesian Basin groundwater in the lower Namoi River valley is relatively homogeneous in chemical composition. Traditional graphical techniques have been combined with multivariate statistical methods to determine whether subtle differences in the chemical composition of these waters can be delineated. Hierarchical cluster analysis and principal components analysis were successful in delineating minor variations within the groundwaters of the study area that were not visually identified in the graphical techniques applied. Hydrochemical interpretation allowed geochemical processes to be identified in each statistically defined water type and illustrated how these groundwaters differ from one another. Three main geochemical processes were identified in the groundwaters: ion exchange, precipitation, and mixing between waters from different sources. Both statistical methods delineated an anomalous sample suspected of being influenced by magmatic CO₂ input. The use of statistical methods to complement traditional graphical techniques for waters appearing homogeneous is emphasized for all investigations of this type. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

闽东沿岸2004～2006年浮游植物生态特征研究     

丁页  林元烧  曹文清  杨圣云  李乃姜 《台湾海峡》2009,28(3):360-369

根据闽东海洋环境监测中心2004年-2006年阂东沿岸生态调查的资料，分析和研究了闽东沿岸浮游植物的生态特征．共鉴定出浮游植物的种类3个门39属共134种，其中硅藻门的种类占总种数的80％，为该调查海域主要门类．主要优势种是中肋骨条藻（Skeletonema costatum）、旋链角毛藻（Chaetoceros curvisetus）、尖刺拟菱形藻（Pseudo—nitzschia pungens）和丹麦细柱藻（Leptocylindrus danicus）等．浮游植物的丰度分布，呈现由调查海域东北侧向西南侧、由近岸向远岸减少的空间特征，夏季高、春季低的季节变化特点，并且有逐年减少的年际变化趋势．本调查海域浮游植物多样性指数较高，群落较稳定．  相似文献   

Kinetics of phosphate adsorption by iron oxyhydroxides in aqueous systems     

S.A. Crosby  G.E. Millward  E.I. Butler  D.R. Turner  M. Whitfield 《Estuarine, Coastal and Shelf Science》1984,19(2):257-270

The rate of uptake of phosphate onto synthetic Fe(III)- and Fe(II)-derived oxyhydroxides has been studied using reaction conditions similar to those encountered in natural waters. Kinetic analyses were carried out on the adsorption profiles and both first-order and second-order conditional rate constants were obtained. The temperature dependence of some of the rate constants was investigated and corresponding apparent activation energies calculated. Similar experiments and analyses were undertaken using Fe from natural sources and in general the conditional rate constants obtained in seawater were in agreement with the synthetic ones. The results of this study are of value when comparing the time scales of adsorption processes in natural waters with the time scales of mixing and advection.  相似文献   

Chlorinated hydrocarbons in the seawater and surface sediments of Blanca Bay,Argentina     

JoséLuis Sericano  Adan E. Pucci 《Estuarine, Coastal and Shelf Science》1984,19(1):27-51

In order to characterize our study area and to provide reference values to be used in the future to measure the changes produced by an increase in contamination, the concentrations of chlorinated hydrocarbons have been investigated in fifty-one samples of seawater, taken at four different depths: air-sea interface, surface, one metre and bottom waters, and in twenty-three samples of surface sediments from Blanca Bay, Argentina. Of eleven organochlorine compounds we were looking for (α BHC, lindane, heptachlor, δ BHC. aldrin, heptachlor epoxide, dieldrin, o-p′DDD, p-p′DDD, o-p′DDT and p-p′DDT), seven could be detected in seawater and three in surface sediments with the following mean concentrations: α-BHC=48·2 ng l^?1; lindane=54·2 ng l^?1; heptachlor=45·0 ng l^?1; δ BHC=12·5 ng l^?1; aldrin=61·8 ng l^?1 and ΣDDT=67·0 ng l^?1; and δ BHC=3·2 ng g^?1; lindane=4·2 ng g^?1 and heptachlor=1·0 ng g^?1 for seawater, regarding the surface waters, and sediment samples, respectively.Concentration factors among the different water layers were also studied to see if there was any correlation between chlorinated hydrocarbon contents and the water depths from which the samples were taken. As a mean value, the air-sea interface water contains 18 times more of these compounds than that of the water near the bottom. A comparison of the values corresponding to seawater and surface sediments from our study area with those levels measured in samples from other geographic locations is also presented.With the purpose to detect a relationship between chlorinated hydrocarbon concentrations and the contents of particulate matter (PM) on the one hand, and particulate organic material (POM) on the other hand, four groups of samples containing different amounts of PM and POM, respectively were formed. From a comparison of the results obtained, lindane, heptachlor and δ BHC showed a tendency to lower concentrations in those samples containing little PM whereas α BHC and aldrin remained without important changes. No significant correlation was found between organochlorine levels and contents of POM.  相似文献   

The hydrogeothermal basin of Sofia graben (Bulgaria)     

K.?D.?ShterevEmail author 《Environmental Geology》2004,46(5):651-660

Abstract In the Mesozoic basement and Neogene filling of Sofia tectonic graben a non-homogenous system of thermal water reservoirs connected to a united hydrogeothermal basin occurred. The basin contains and reproduces five types of low mineralized thermal waters and four types of mineralized thermal waters with exotic composition. The water temperatures are 30–80(90) ^°C. The total potential of the basin is assessed at 500 l/s thermal waters and 48 MWt thermal power. The utilization of thermal waters in the area of the Bulgarian capital has its roots and traditions in antiquity, and a promising future. The new town plan of Sofia provides construction of 35 centers for developing a versatile and prosperous hydrothermal business.  相似文献   

Trace elements in medium-temperature (40–80 °C) thermal waters from the Mura basin (North-Eastern Slovenia)     

Peter?KraljEmail author 《Environmental Geology》2004,46(5):622-629

Medium-temperature thermal waters in the Mura basin occur in hydrogeological systems different in age, burial depth, temperature, porosity and permeability, and the presence of free carbon dioxide which penetrates through the fractures from pre-Tertiary basement. The waters commonly belong to sodium-bicarbonate hydrogeochemical facies, but may have significantly different amounts of total dissolved solids, including trace elements. Thermal waters occurring in low-permeable, well-compacted and moderately fractured Tertiary sediments older than Upper Pliocene are the richest in trace elements, although their abundance may be very variable from one aquifer to another. The ratios of major alkaline and alkaline earth elements (Na, K, Ca) and trace elements (Li, Rb, Cs, Ba, Sr) commonly show relative enrichment in highly mineralised waters with respect to the waters with lower mineralisation. Rare earth elements (REEs) and Y show only minor fractionation in the highly mineralised waters, whereas in the waters with lower mineralisation strong fractionation of heavy rare earth elements (HREEs) over light rare earth elements (LREEs) occurs, along with a pronounced positive europium anomaly. Positive Th/U ratios are commonly observed, although both actinide elements occur in the range of some hundredths of ppb to some ppb. Trace elements were particularly useful in the study of well cycling in two hydraulically interconnected geothermal wells in the town of Murska Sobota, which produce a mixture of low- and high-mineralised waters.  相似文献   

测量船的摇动对AIRSEA SystemⅡ的干扰分析     

于富强 《北京测绘》2012,(6):11-13

根据海洋重力测量的实际情况,结合AIRSEA SystemⅡ的结构特点,对仪器在测量中受到测量船摇动的影响进行分析,认为影响仪器观测精度的干扰因素有三类:垂直加速度、横摇与纵摇、交叉耦合效应。并对这三种干扰因素进行分析,给出了减弱干扰影响的措施,这些措施能使海洋重力测量外业获取更高的观测精度。  相似文献