In this study, hydrogeologic and hydrochemical information from the Mersin-Erdemli groundwater system were integrated and
used to determine the main factors and mechanisms controlling the chemistry of groundwaters in the area and anthropogenic
factors presently affecting them. The PHREEQC geochemical modeling demonstrated that relatively few phases are required to
derive water chemistry in the area. In a broad sense, the reactions responsible for the hydrochemical evolution in the area
fall into four categories: (1) silicate weathering reactions; (2) dissolution of salts; (3) precipitation of calcite, amorphous
silica and kaolinite; (4) ion exchange. As determined by multivariate statistical analysis, anthropogenic factors show seasonality
in the area where most contaminated waters related to fertilizer and fungicide applications that occur during early summer
season. 相似文献
Garnets in continentally derived high-pressure (HP) rocks ofthe Sesia Zone (Western Alps) exhibit three different chemicalzonation patterns, depending on sample locality. Comparisonof observed garnet zonation patterns with thermodynamicallymodelled patterns shows that the different patterns are causedby differences in the water content of the subducted protolithsduring prograde metamorphism. Zonation patterns of garnets inwater-saturated host rocks show typical prograde chemical zonationswith steadily increasing pyrope content and increasing XMg,together with bell-shaped spessartine patterns. In contrast,garnets in water-undersaturated rocks have more complex zonationpatterns with a characteristic decrease in pyrope and XMg betweencore and inner rim. In some cases, garnets show an abrupt compositionalchange in core-to-rim profiles, possibly due to water-undersaturationprior to HP metamorphism. Garnets from both water-saturatedand water-undersaturated rocks show signs of intervening growthinterruptions and core resorption. This growth interruptionresults from bulk-rock depletion caused by fractional garnetcrystallization. The water content during burial influences significantly thephysical properties of the subducted rocks. Due to enhancedgarnet crystallization, water-undersaturated rocks, i.e. thoselacking a free fluid phase, become denser than their water-saturatedequivalents, facilitating the subduction of continental material.Although water-bearing phases such as phengite and epidote arestable up to eclogite-facies conditions in these rocks, dehydrationreactions during subduction are lacking in water-undersaturatedrocks up to the transition to the eclogite facies, due to thethermodynamic stability of such hydrous phases at high PTconditions. Our calculations show that garnet zonation patternsstrongly depend on the mineral parageneses stable during garnetgrowth and that certain co-genetic mineral assemblages causedistinct garnet zonation patterns. This observation enablesinterpretation of complex garnet growth zonation patterns interms of garnet-forming reactions and water content during HPmetamorphism, as well determination of detailed PT paths. KEY WORDS: dehydration; high-pressure metamorphism; Sesia Zone; subduction; thermodynamic modelling相似文献
In order to apply Monin–Obukhov similarity theory to estimatethe profiles of mean quantities and surface fluxes from bulk meteorological parameters, the assumptions of homogeneityand stationarity must be valid. Unfortunately, in coastal zones as well as many other regions of interest, theseassumptions are often violated. In this paper, an extension to the theory is presented that considers systematically varyingstate variables. Along-wind variations of windspeed, atmospheric stratification, and roughness are examined with respectto their relative importance to momentum flux divergence, and the drag coefficient is shown to be systematicallylower in coastal zones. For profiles of scalars, an analysis of the set of quasi-homogeneous terms is only speculated,and the relative importance for the terms will strongly depend on which scalar is of interest. 相似文献
The circulation and transport of freshwater generated by an idealized buoyant source is studied using a three-dimensional primitive equation model. Freshwater enters the continental shelf, turns anticyclonically and moves downstream in the direction of Kelvin wave propagation. In the region close to the source, the flow reaches an equilibrium in the bottom boundary layer so that freshwater does not spread offshore any further. This offshore equilibrium distance increases as we move downstream until the freshwater is able to feel the presence of the shelfbreak. A shelfbreak front forms and the shelfbreak prevents any further offshore spreading of freshwater in the bottom boundary layer.Two complimentary mechanisms are responsible for the slow cross-shelf migration of freshwater and subsequent trapping of shelfbreak fronts: bottom stress and topographic changes. The shelfbreak creates an active, dynamic process preventing leakage from the continental shelf region to the slope region. However, the dynamical process that traps the front to the shelfbreak is still unclear.The location of the shelfbreak front depends on four dimensionless parameters: scaled inlet volume transport, scaled breadth, scaled “diffusivity” and scaled shelf width. We develop empirical relations for predicting the location of the frontal bottom intersection, given these parameters. 相似文献
The Late Cretaceous–Cenozoic evolution of the eastern North Sea region is investigated by 3D thermo-mechanical modelling. The model quantifies the integrated effects on basin evolution of large-scale lithospheric processes, rheology, strength heterogeneities, tectonics, eustasy, sedimentation and erosion.
The evolution of the area is influenced by a number of factors: (1) thermal subsidence centred in the central North Sea providing accommodation space for thick sediment deposits; (2) 250-m eustatic fall from the Late Cretaceous to present, which causes exhumation of the North Sea Basin margins; (3) varying sediment supply; (4) isostatic adjustments following erosion and sedimentation; (5) Late Cretaceous–early Cenozoic Alpine compressional phases causing tectonic inversion of the Sorgenfrei–Tornquist Zone (STZ) and other weak zones.
The stress field and the lateral variations in lithospheric strength control lithospheric deformation under compression. The lithosphere is relatively weak in areas where Moho is deep and the upper mantle warm and weak. In these areas the lithosphere is thickened during compression producing surface uplift and erosion (e.g., at the Ringkøbing–Fyn High and in the southern part of Sweden). Observed late Cretaceous–early Cenozoic shallow water depths at the Ringkøbing–Fyn High as well as Cenozoic surface uplift in southern Sweden (the South Swedish Dome (SSD)) are explained by this mechanism.
The STZ is a prominent crustal structural weakness zone. Under compression, this zone is inverted and its surface uplifted and eroded. Contemporaneously, marginal depositional troughs develop. Post-compressional relaxation causes a regional uplift of this zone.
The model predicts sediment distributions and paleo-water depths in accordance with observations. Sediment truncation and exhumation at the North Sea Basin margins are explained by fall in global sea level, isostatic adjustments to exhumation, and uplift of the inverted STZ. This underlines the importance of the mechanisms dealt with in this paper for the evolution of intra-cratonic sedimentary basins. 相似文献
The differentiation of units in the Sierra de Almagro has been a source of controversy. There were defined the Almagride and Ballabona–Cucharón complexes, the former considered by several authors as part of a Subbetic metamorphosed and outcropping in a tectonic window. In this study, the units of Ballabona, Almagro and Cucharón are integrated into a single one, that of Tres Pacos, because they correspond to different parts of the same stratigraphic series. This unit is tectonically over the Nevado–Filabride Complex. The existence of the Almagride and Ballabona–Cucharón complexes is discarded and their units form part of the Alpujarride Complex. To cite this article: C. Sanz de Galdeano, F.J. Garc??a Tortosa, C. R. Geoscience 334 (2002) 355–362.相似文献