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S. Alan Stern Jason C. Cook Jean -Yves Chaufray Paul D. Feldman G. Randall Gladstone Kurt D. Retherford 《Icarus》2013
We report on the detection of H2 as seen in our analysis of twilight observations of the lunar atmosphere observed by the LAMP instrument aboard NASA’s Lunar Reconnaissance Orbiter. Using a large amount of data collected on the lunar atmosphere between September 2009 and March 2013, we have detected and identified, the presence of H2 in the native lunar atmosphere, for the first time. We derive a surface density for H2 of 1.2 ± 0.4 × 103 cm−3 at 120 K. This is about 10 times smaller than originally predicted, and several times smaller than previous upper limits from the Apollo era data. 相似文献
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利用 Gresens( 1967)质量平衡方程及 Brimhall等 ( 1987)提出的元素不活动组份ΔX- fv 图解 ,对复杂热液成矿体系的元素不活动组份进行了深入探讨。指出了复杂体系内部各个子体系间元素不活动组份及体积变化上的差异。并结合库布苏金矿中矿带元素不活动组份进行了研究。同时对一些矿床地质现象的形成及成矿物质来源从元素地球化学角度进行了解释和判断。 相似文献
55.
We report new estimates of abundances of rarely analyzed elements (As, B, Be, Bi, Cd, Ge, In, Mo, Sb, Sn, Te, Tl, W) in the upper continental crust based on precise ICP-MS analyses of well-characterized upper crustal samples (shales, pelites, loess, graywackes, granitoids and their composites) from Australia, China, Europe, New Zealand and North American. Obtaining a better understanding of the upper crustal abundance and associated uncertainties of these elements is important in placing better constraints on bulk crust composition and, from that, whole Earth models of element cycling and crust generation. We also present revised abundance estimates of some more commonly analyzed trace elements (Li, Cr, Ni, and Tm) that vary by > 20% compared to previous estimates. The new estimates are mainly based on significant (r2 > 0.6) inter-element correlations observed in clastic sediments and sedimentary rocks, which yield upper continental crust elemental ratios that are used in conjunction with well-determined abundances for certain key elements to place constraints on the concentrations of the rarely analyzed elements. Using the well-established upper crustal abundances of La (31 ppm), Th (10.5 ppm), Al2O3 (15.40%), K2O (2.80%) and Fe2O3 (5.92%), these ratios lead to revised upper crustal abundances of B = 47 ppm, Bi = 0.23 ppm, Cr = 73 ppm, Li = 41 ppm, Ni = 34 ppm, Sb = 0.075, Te = 0.027 ppm, Tl = 0.53 ppm and W = 1.4 ppm. No significant correlations exist between Mo and Cd and other elements in the clastic sediments and sedimentary rocks, probably due to their enrichment in organic carbon. We thus calculate abundances of these elements by assuming the upper continental crust consists of 65% granitoid rocks plus 35% clastic sedimentary rocks. The validity of this approach is supported by the similarity of SiO2, Al2O3, La and Th abundances calculated in this way with their upper crustal abundances given in Rudnick and Gao [Rudnick, R., Gao, S., 2003. Composition of the continental crust. In: Rudnick, R.L. (Ed.), The Crust. In: Holland, H.D., Turekian, K.K. (Eds.), Treatise on Geochemistry, vol. 3. Elsevier–Pergamon, Oxford, pp. 1–64.]. The upper crustal abundances thus obtained are Mo = 0.6 ppm and Cd = 0.06 ppm. Our data also suggest a 20% increase of the Tm, Yb and Lu abundances reported in Rudnick and Gao [Rudnick, R., Gao, S., 2003. Composition of the continental crust. In: Rudnick, R.L. (Ed.), The Crust. In: Holland, H.D., Turekian, K.K. (Eds.), Treatise on Geochemistry, vol. 3. Elsevier–Pergamon, Oxford, pp. 1–64.]. 相似文献
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V. Vuitton P. Lavvas M. Galand G.R. Lewis A.J. Coates J.-E. Wahlund 《Planetary and Space Science》2009,57(13):1558-662
The Electron Spectrometer (ELS), one of the sensors making up the Cassini Plasma Spectrometer (CAPS) revealed the existence of numerous negative ions in Titan's upper atmosphere. The observations at closest approach (∼1000 km) show evidence for negatively charged ions up to ∼10,000 amu/q, as well as two distinct peaks at 22±4 and 44±8 amu/q, and maybe a third one at 82±14 amu/q. We present the first ionospheric model of Titan including negative ion chemistry. We find that dissociative electron attachment to neutral molecules (mostly HCN) initiates the formation of negative ions. The negative charge is then transferred to more acidic molecules such as HC3N, HC5N or C4H2. Loss occurs through associative detachment with radicals (H and CH3). We attribute the three low mass peaks observed by ELS to CN−, C3N−/C4H− and C5N−. These species are the first intermediates in the formation of the even larger negative ions observed by ELS, which are most likely the precursors to the aerosols observed at lower altitudes. 相似文献
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The reflectance of Saturn’s moon Enceladus has been measured at far ultraviolet (FUV) wavelengths (115-190 nm) by Cassini’s Ultraviolet Imaging Spectrograph (UVIS). At visible and near infrared (VNIR) wavelengths Enceladus’ reflectance spectrum is very bright, consistent with a surface composed primarily of H2O ice. At FUV wavelengths, however, Enceladus is surprisingly dark - darker than would be expected for pure water ice. Previous analyses have focused on the VNIR spectrum, comparing it to pure water ice (Cruikshank, D.P., Owen, T.C., Dalle Ore, C., Geballe, T.R., Roush, T.L., de Bergh, C., Sandford, S.A., Poulet, F., Benedix, G.K., Emery, J.P. [2005] Icarus, 175, 268-283) or pure water ice plus a small amount of NH3 (Emery, J.P., Burr, D.M., Cruikshank, D.P., Brown, R.H., Dalton, J.B. [2005] Astron. Astrophys., 435, 353-362) or NH3 hydrate (Verbiscer, A.J., Peterson, D.E., Skrutskie, M.F., Cushing, M., Helfenstein, P., Nelson, M.J., Smith, J.D., Wilson, J.C. [2006] Icarus, 182, 211-223). We compare Enceladus’ FUV spectrum to existing laboratory measurements of the reflectance spectra of candidate species, and to spectral models. We find that the low FUV reflectance of Enceladus can be explained by the presence of a small amount of NH3 and a small amount of a tholin in addition to H2O ice on the surface. The presence of these three species (H2O, NH3, and a tholin) appears to satisfy not only the low FUV reflectance and spectral shape, but also the middle-ultraviolet to visible wavelength brightness and spectral shape. We expect that ammonia in the Enceladus plume is transported across the surface to provide a global coating. 相似文献
60.
This work is dedicated to the application to 67P/Churyumov-Gerasimenko of a new quasi-3D approach for non-spherically shaped comet nuclei with the aim to interpret the current activity of the comet in terms of initial characteristics and to predict shape and internal stratification evolution of the nucleus. The model is applied to differently shaped nuclei taking into account the characteristics of Comet 67P/Churyumov-Gerasimenko deduced from observations. We focus our attention on the combined effects that shapes and obliquity have on the comet surface and sub-surface evolution. We discuss the results in terms of activity, local dust mantle formation and disruption, erosion of the surface and internal stratigraphy.The results show that differently shaped nuclei can have different internal structures leading to different activity patterns and behaviors. Our calculations have shown that local variations in the dust and gas fluxes can be induced by the nucleus shape. The distribution of “active” areas on Comet 67P/Churyumov-Gerasimenko is different because of different shapes, reflecting the illumination conditions on the surface. These shapes can influence the structure of the inner coma, but the coma far away from the nucleus is only marginally affected by the nucleus shape. However, different comet behaviors can arise from differently shaped comet nuclei, especially in terms of local activity, surface and sub-surface characteristics and properties. The water flux local distribution is the most influenced by the shape as it is directly linked to the illumination. Irregular shapes have large shadowing effects that can result in activity patterns on the comet surface.The effects of different pole directions are discussed to see the relations with the nucleus activity and internal structure. It is shown that the orientation of the rotation axis plays a strong role on the surface evolution of 67P/Churyumov-Gerasimenko, determining seasonal effects on the fluxes. The activity of the comet changes greatly with the nucleus obliquity leading to pre-post-perihelion differences in the activity and seasonal effects. The effects of the dust deposition and crust formation on the cometary activity have also been simulated and are discussed with respect to 67P/Churyumov-Gerasimenko observations. The dust mantling is also strongly obliquity dependent, with different surface distributions of the dust-covered regions according to the different comet pole orientations. Finally, we show that our model can reproduce the fluxes behavior near perihelion in terms of amplitude and asymmetry, and we estimate 20% of the illuminated surface to be active. 相似文献