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31.
Irina N. Plotnikova 《International Journal of Earth Sciences》2008,97(5):1131-1142
The study area is the South Tatarstan Arch located in the Volgo-Ural Region, which is an enigmatic crustal segment occupying
one third of the East European Platform. Monitoring studies have shown that fluid discharge processes are still active and
time-dependent. This paper presents an integrated review of the geological, geophysical, hydrochemical and geochemical studies
of the crystalline basement of Tatarstan. These studies are based on the stratigraphic and compositional schemes within the
crystalline basement, the drilling of deep wells, the geodynamic activity of the fractured zones of the crystalline basement
and the presence of fluids therein. Furthermore, the changes in the chemical composition of the basement waters are taken
into account. 相似文献
32.
We study the aspect of unstable behavior (like strain localization bands) in elastic solids as a consequence of micro-fracturing.
A two-scale approach of computational homogenization is considered. The macroscopic behavior is investigated by finite element
computations on a unit cell. At the micro-level, we consider a granular structure with elastic grains. The inter-granular
boundaries are modeled with cohesive laws, friction and unilateral contact. We show that decohesion between grains gives rise
to macro-instabilities, indicated by the loss of ellipticity, typical for deformation localization bands. The relation between
the microscopic softening on inter-granular boundaries and the onset of macro-instabilities is studied through numerical examples.
The influence of the cohesive law and friction parameters is analyzed. For periodic distributions of granular structures,
we prove the loss of periodicity by failure and the corresponding size dependence effect in the homogenized response. We present
numerical examples of bifurcation of solutions for granular cell structures and of particular solutions specific to elementary
volumes with periodic cell distribution. Size dependence appears in the unstable regime and is strongly influenced by cohesion
and friction parameters. 相似文献
33.
The scope of the present paper is to provide analytic solutions to the problem of the attitude evolution of a symmetric gyrostat about a fixed point in a central Newtonian force field when the potential function isV
(2).We assume that the center of mass and the gyrostatic moment are on the axis of symmetry and that the initial conditions are the following: (t
0)=0, (t
0)=0, (t
0)=(t
0)=0, 1(t
0)=0, 2(t
0)=0 and 3(t
0)=
3
0
.The problem is integrated when the third component of the total angular momentum is different from zero (B
1 0). There now appear equilibrium solutions that did not exist in the caseB
1=0, which can be determined in function of the value ofl
3
r
(the third component of the gyrostatic momentum).The possible types of solutions (elliptic, trigonometric, stationary) depend upon the nature of the roots of the functiong(u). The solutions for Euler angles are given in terms of functions of the timet. If we cancel the third component of the gyrostatic momentum (l
3
r
=0), the obtained solutions are valid for rigid bodies. 相似文献
34.
Fluid sources for the La Guitarra epithermal deposit (Temascaltepec district, Mexico): Volatile and helium isotope analyses in fluid inclusions 总被引:1,自引:0,他引:1
Antoni Camprubí Beverly A. Chomiak Ruth E. Villanueva-Estrada David I. Norman Martin Stute 《Chemical Geology》2006,231(3):252-284
The La Guitarra deposit (Temascaltepec district, South-Central Mexico), belongs to the low/intermediate sulfidation epithermal type, has a polymetallic character although it is currently being mined for Ag and Au. The mineralization shows a polyphasic character and formed through several stages and sub-stages (named I, IIA, IIB, IIC, IID, and III). The previous structural, mineralogical, fluid inclusion and stable isotope studies were used to constrain the selection of samples for volatile and helium isotope analyses portrayed in this study. The N2/Ar overall range obtained from analytical runs on fluid inclusion volatiles, by means of Quadrupole Mass Spectrometry (QMS), is 0 to 2526, and it ranges 0 to 2526 for stage I, 0 to 1264 for stage IIA, 0 to 1369 for stage IIB, 11 to 2401 for stage IIC, 19 to 324 for stage IID, and 0 to 2526 for stage III. These values, combined with the CO2/CH4 ratios, and N2-He-Ar and N2-CH4-Ar relationships, suggest the occurrence of fluids from magmatic, crustal, and shallow meteoric sources in the forming epithermal vein deposit. The helium isotope analyses, obtained by means of Noble Gas Mass Spectrometry, display R/Ra average values between 0.5 and 2, pointing to the occurrence of mantle-derived helium that was relatively diluted or “contaminated” by crustal helium. These volatile analyses, when correlated with the stable isotope data from previous works and He isotope data, show the same distribution of data concerning sources for mineralizing fluids, especially those corresponding to magmatic and crustal sources. Thus, the overall geochemical data from mineralizing fluids are revealed as intrinsically consistent when compared to each other.The three main sources for mineralizing fluids (magmatic, and both deep and shallow meteoric fluids) are accountable at any scale, from stages of mineralization down to specific mineral associations. The volatile and helium isotope data obtained in this paper suggest that the precious metal-bearing mineral associations formed after hydrothermal pulses of predominantly oxidized magmatic fluids, and thus it is likely that precious metals were carried by fluids with such origin. Minerals from base-metal sulfide associations record both crustal and magmatic sources for mineralizing fluids, thus suggesting that base metals could be derived from deep leaching of crustal rocks. At the La Guitarra epithermal deposit there is no evidence for an evolution of mineralizing fluids towards any dominant source. Rather than that, volatile analyses in fluid inclusions suggest that this deposit formed as a pulsing hydrothermal system where each pulse or set of pulses accounts for different compositions of mineralizing fluids.The positive correlation between the relative content of magmatic fluids (high N2/Ar ratios) and H2S suggests that the necessary sulfur to carry mostly gold as bisulfide complexes came essentially from magmatic sources. Chlorine necessary to carry silver and base metals was found to be abundant in inclusion fluids and although there is no evidence about its source, it is plausible that it may come from magmatic sources as well. 相似文献
35.
Hong-Rui Fan Fang-Fang Hu Kui-Feng Yang Kai-Yi Wang 《Journal of Geochemical Exploration》2006,89(1-3):104
The giant Bayan Obo REE–Nb–Fe deposit consists of replacement bodies hosted in dolomite marble made up of magnetite, REE fluorocarbonates, fluorite, aegirine, amphibole, calcite and barite. Two or three phase CO2-rich, three phase hypersaline liquid–vapor–solid, and two phase liquid-rich inclusions have been recognized in mineralized fluorite and quartz samples. Microthermometry measurements indicate that the carbonic phase in CO2-rich inclusions is nearly pure CO2. Fluids involving in REE–Nb–Fe mineralization at Bayan Obo might be mainly of H2O–CO2–NaCl–(F–REE) system. Coexistences of brine inclusions and CO2-rich inclusions with similar homogenization temperatures give evidence that immiscibility happened during REE mineralization. An unmixing of an original H2O–CO2–NaCl fluid probably derived from carbonatitic magma. The presence of REE-carbonates as an abundant solid in fluid inclusions shows that the original ore-forming fluids are very rich in REE, and therefore, have the potential to produce economic REE ores at Bayan Obo. 相似文献
36.
Postcollisional flow of aqueous fluid within ultrahigh-pressure eclogite in the Dabie orogen 总被引:1,自引:0,他引:1
Tian-Shan Gao Song-Shan Wang Bing Gong Yuan-Bao Wu Yong-Fei Zheng 《Journal of Geochemical Exploration》2006,89(1-3):115
A combined study of chronometric dating and oxygen isotope analysis for minerals from vein and host eclogite as well as regional country-rock gneiss in the Dabie orogen provides a direct constraint on timing of fluid flow in this orogen formed by continental collision. Oxygen isotope ratios of vein minerals are significantly lower than those of the host eclogite, but comparable with those of the regional gneiss. This suggests the veining fluid came from the regional gneiss (i.e. exhumed slab itself) rather than the host eclogite. While zircon U–Pb and phengite Ar–Ar dating yields ages of 214 to 222 Ma for the eclogite and gneiss, the vein gives a quartz–muscovite Rb–Sr isochron age of 181 Ma and a muscovite K–Ar age of 179 Ma. Thus the veining postdates the Triassic ultrahigh pressure metamorphic event, witnessing postcollisional fluid flow after the orogenic cycle of continental collision. 相似文献
37.
J.D. Martín-Martín J. Tritlla E. Cardellach D. Gmez-Gras 《Journal of Geochemical Exploration》2006,89(1-3):267
Fluid inclusions and clay mineralogy of the Permo-Triassic rocks from the Espina and Espadà Ranges (SE Iberian Chain, Spain) have been investigated to establish their relationship with hydrothermal fluid circulation during the Alpine Orogeny. Primary fluid inclusions in quartz-filled tension gashes in Permo-Triassic sandstones reveal maximum temperatures around 230 °C and very constant salinities of 8.5% wt. eq. NaCl. Secondary fluid inclusions found in quartz from the Santonian Ba–Cu–Hg deposits show similar compositional and thermodynamic characteristics, denoting an Alpine recrystallization. Clay mineral composition of Permo-Triassic mudrocks is characterized by pyrophyillite, indicating low-grade metamorphic conditions. Field observations and experimental data suggest that the crystallization of quartz in tension gashes, the formation of secondary fluid inclusions and the development of the metamorphism are contemporaneous and related to fluid circulation during the Alpine compression. Fluid flow took place along the Hercynian fault system that was reactivated during the Mesozoic rift stage and inverted during the Alpine deformation. 相似文献
38.
R.E. Villanueva R.M. Prol-Ledesma M.A. Torres-Vera C. Canet M.A. Armienta C.E.J. de Ronde 《Journal of Geochemical Exploration》2006,89(1-3):414
A primary aim for sampling of submarine hydrothermal vents is to minimize inclusion of ambient seawater. Here, we compare the results of three different sampling methods (air displacement, two-valve bottle, and syringes) for shallow submarine systems. Mixing of hydrothermal fluid with seawater is unavoidable; however, calculations based on linear mixing models allow estimation of the hydrothermal fluid end-member composition. The results show that sampling with a two-valve bottle and syringes are the best options because they allow collection of samples with a large proportion of hydrothermal fluid. Additionally, we compare the results of in situ and laboratory analyses of the fluid samples, and demonstrate that determination of chemical composition in situ is the best option for some components, as re-equilibration affects some component concentrations (i.e. bicarbonate). Conversely, silica determination in situ usually underestimates the concentration in the fluid, as it does not account for polymeric silica. Other components can be measured either in the field or in the laboratory. 相似文献
39.
Darren F. Mark John Parnell Simon P. Kelley Sarah C. Sherlock 《Journal of Geochemical Exploration》2006,89(1-3):259
Integration of fluid inclusion analysis with high spatial resolution Ar–Ar dating of K-feldspar cements has been used to resolve and reconstruct palaeo-fluid flow. Fluid inclusion analysis allows discrimination of distinct cement phases, thereby identifying discrete episodes of fluid flow. Ar–Ar dating of the same cements via high spatial resolution laserprobe establishes absolute age constraints on the framework previously constructed. Integration of these two datasets yields temperature–composition–time data. 相似文献
40.
Neal T. Skipper Peter A. Lock James O. Titiloye Jan Swenson Zakaria A. Mirza W. Spencer Howells Felix Fernandez-Alonso 《Chemical Geology》2006,230(3-4):182-196
The interlayer pores of swelling 2:1 clays provide an ideal 2-dimensional environment in which to study confined fluids. In this paper we discuss our understanding of the structure and dynamics of interlayer fluid species in expanded clays, based primarily on the outcome of recent molecular modelling and neutron scattering studies. Counterion solvation is compared with that measured in bulk solutions, and at a local level the cation-oxygen coordination is found to be remarkably similar in these two environments. However, for the monovalent ions the contribution to the first coordination shell from the clay surfaces increases with counterion radius. This gives rise to inner-sphere (surface) complexes in the case of potassium and caesium. In this context, the location of the negative clay surface charge (i.e. arising from octahedral or tetrahedral substitution) is also found to be of major importance. Divalent cations, such as calcium, eagerly solvate to form outer-sphere complexes. These complexes are able to pin adjacent clay layers together, and thereby prevent colloidal swelling. Confined water molecules form hydrogen bonds to each other and to the clays' surfaces. In this way their local environment relaxes to close to the bulk water structure within two molecular layers of the clay surface. Finally, we discuss the way in which the simple organic molecules methane, methanol and ethylene glycol behave in the interlayer region of hydrated clays. Quasi-elastic neutron scattering of isotopically labelled interlayer CH3OD and (CH2OD)2 in deuterated clay allows us to measure the diffusion of the CH3- and CH2-groups in both clay and liquid environments. We find that in both the one-layer methanol solvates and the two-layer glycol solvates the diffusion of the most mobile organic molecules is close to that in the bulk solution. 相似文献