Fluid inclusions in granulites, granulitized eclogites and garnet clinopyroxenites from the Dabie–Sulu terranes, eastern China     

Bin Fu  Jacques L.R Touret  Yong-Fei Zheng  Bor-ming Jahn 《Lithos》2003,70(3-4):293-319

Minor granulites (believed to be pre-Triassic), surrounded by abundant amphibolite-facies orthogneiss, occur in the same region as the well-documented Triassic high- and ultrahigh-pressure (HP and UHP) eclogites in the Dabie–Sulu terranes, eastern China. Moreover, some eclogites and garnet clinopyroxenites have been metamorphosed at granulite- to amphibolite-facies conditions during exhumation. Granulitized HP eclogites/garnet clinopyroxenites at Huangweihe and Baizhangyan record estimated eclogite-facies metamorphic conditions of 775–805 °C and ≥15 kbar, followed by granulite- to amphibolite-facies overprint of ca. 750–800 °C and 6–11 kbar. The presence of (Na, Ca, Ba, Sr)-feldspars in garnet and omphacite corresponds to amphibolite-facies conditions. Metamorphic mineral assemblages and P–T estimates for felsic granulite at Huangtuling and mafic granulite at Huilanshan indicate peak conditions of 850 °C and 12 kbar for the granulite-facies metamorphism and 700 °C and 6 kbar for amphibolite-facies retrograde metamorphism. Cordierite–orthopyroxene and ferropargasite–plagioclase coronas and symplectites around garnet record a strong, rapid decompression, possibly contemporaneous with the uplift of neighbouring HP/UHP eclogites.

Carbonic fluid (CO₂-rich) inclusions are predominant in both HP granulites and granulitized HP/UHP eclogites/garnet clinopyroxenites. They have low densities, having been reset during decompression. Minor amounts of CH₄ and/or N₂ as well as carbonate are present. In the granulitized HP/UHP eclogites/garnet clinopyroxenites, early fluids are high-salinity brines with minor N₂, whereas low-salinity fluids formed during retrogression. Syn-granulite-facies carbonic fluid inclusions occur either in quartz rods in clinopyroxene (granulitized HP garnet clinopyxeronite) or in quartz blebs in garnet and quartz matrices (UHP eclogite). For HP granulites, a limited number of primary CO₂ and mixed H₂O–CO₂(liquid) inclusions have also been observed in undeformed quartz inclusions within garnet, orthopyroxene, and plagioclase which contain abundant, low-density CO₂±carbonate inclusions. It is suggested that the primary fluid in the HP granulites was high-density CO₂, mixed with a significant quantity of water. The water was consumed by retrograde metamorphic mineral reactions and may also have been responsible for metasomatic reactions (“giant myrmekites”) occurring at quartz–feldspar boundaries. Compared with the UHP eclogites in this region, the granulites were exhumed in the presence of massive, externally derived carbonic fluids and subsequently limited low-salinity aqueous fluids, probably derived from the surrounding gneisses.  相似文献   

Diagenetic history and porosity evolution of Upper Carboniferous sandstones from the Spring Valley #1 well, Maritimes Basin, Canada–implications for reservoir development     

G. Chi  P. S. Giles  M. A. Williamson  D. Lavoie  R. Bertrand 《Journal of Geochemical Exploration》2003,80(2-3):171-191

Eighty-two core samples were collected from the Spring Valley #1 well which penetrates the Upper Carboniferous strata in the Late Devonian–Early Permian Maritimes Basin. The strata consist of alternating sandstones and mudstones deposited in a continental environment. The objective of this study is to characterize the relationship of sandstone porosity with depth, and to investigate the diagenetic processes related to the porosity evolution. Porosity values estimated from point counting range from 0% to 27.8%, but are mostly between 5% and 20%. Except samples that are significantly cemented by calcite, porosity values clearly decrease with depth. Two phases of calcite cement were distinguished based on Cathodoluminescence, with the early phase being largely dissolved and preserved as minor relicts in the later phase. Feldspar dissolution was extensive and contributed significantly to the development of secondary porosity. Quartz cementation was widespread and increased with depth. Fluid inclusions recorded in calcite and quartz cements indicate that interstitial fluids in the upper part of the stratigraphic column were dominated by waters with salinity lower than that of seawater, the middle part was first dominated by low-salinity waters, then invaded by brines, and the lower part was dominated by brines. Homogenization temperatures of fluid inclusions generally increase with depth and suggest a paleogeothermal gradient of 25 °C/km, which is broadly consistent with that indicated by vitrinite reflectance data. An erosion of 1.1–2.4 (mean 1.75) km of strata is inferred to have taken place above the stratigraphic column. δ¹⁸O values of calcite cements (mainly from the late phase) decrease with depth, implying increasing temperatures of formation, as also suggested by fluid-inclusion data. δ¹³C values of calcite cements range from −13.4‰ to −5.7‰, suggesting that organic matter was an important carbon source for calcite cements. A comparison of the porosity data with a theoretical compaction curve indicates that the upper and middle parts of the stratigraphic column show higher-than-normal porosity values, which are related to significant calcite and feldspar dissolution. Meteoric incursion and carboxylic acids generated from organic maturation were probably responsible for the abundant dissolution events.  相似文献   

1966年以来华北地区一系列七级大震破裂过程的数值模拟   总被引：9，自引：5，他引：9       下载免费PDF全文

陈祖安  白武明  林邦慧  王新华  许国凯  张瑞清  黄为清 《地球物理学报》2003,46(3):373-381

用非连续变形分析方法(DDA+FEM)数值模拟，在华北地区各地块相互制约的块体系统环境中，地块边界断层上发生1966年邢台地震、 1969年渤海地震、 1975年海城地震、 1976年唐山地震等不同类型破裂模式大震的破裂过程. 数值模拟结果给出每个大震释放的主应力场，最大剪应力变化等值线图，地震前后位移变化矢量图，发震断层滑移随时间变化以及走滑错距和应力降等震源参数. 这些结果与地震的震源机制，用地震波资料研究得到的震源参数,宏观等震线,地表观测的水平位移矢量图基本一致. 其中1969年渤海地震正交破裂模式的结果与宏观等震线及小震分布图像更接近. 1976年唐山地震复杂震源模式与该震早期余震分布图像更相符. 表明用DDA+FEM方法进行数值模拟研究，能较好地模拟地震破裂过程.  相似文献   

中国大陆科学钻探主孔0～2000米流体剖面及流体地球化学研究   总被引：13，自引：6，他引：13  

罗立强孙青  詹秀春 《岩石学报》2004,20(1):185-191

地下深部流体的来源与演化的研究已成为国际地球化学领域的探索前沿和研究热点之一，中国大陆科学钻探(CCSD)为开展深部流体地球化学研究提供了珍贵的样品，构建了探索地下流体的研究平台。中给出了中国大陆科学钻探(CCSD)主孔He、Ar、N2、O2、H2、CH4、CO2流体地球化学剖面。CCSD主孔CH4浓度的变化与H2浓度的升降没有显相关性；CO2浓度的变化与钻井条件下的氧含量无显相关性；CO2浓度与CH4浓度的关系有三种情况：CO2浓度与CH4浓度不相关、CO2浓度与CH4浓度负相关、或CO2浓度与CH4浓度正相关；氦浓度的增加与CO2和CH4浓度的上升呈现一定的正相关。大气中N2、O2、Ar浓度太高，掩盖了井中N2、O2、Ar气体组分浓度变化，通常情况下N2、O2、Ar浓度变化难以作为深源气体的判据。CCSD流体与KTB流体中氧．氮关系基本一致，氧、氮线性相关(r=0.97)，表明这两种气体主要来源于大气。KTB中的CH4与乙烷、N2表现出非常强的线性关系，而在CCSD流体中CH4与乙烷、N2之间不存在线性相关性。两个地区间的流体成因、围岩相互作用机理等方面可能有所不同。在CCSD主孔中，目前已发现存在大量的CO2，及少量CO、CH4、C2H6、C3H8、C4H10和He、N2等气体。已确定300～2000米主孔出现多处来自于地下的气体异常，包括甲烷和C2～C4等烃类气体，一氧化碳与二氧化碳，稀有气体氦。根据流体各组分间相关性研究，可以判定异常中氧主要来源于大气，N2、Ar和CO2有一部分源于大气，一部分来源于地下。在流体显异常时，甲烷等烃类气体、氦、一氧化碳和绝大部分CO2来源于地下。出现显地下流体异常处，在岩石中存在裂隙、晶洞、破裂面、断层；它们作为流体迁移通道或存储空间，可能是流体存在的必要条件。某些CO2和He气异常与碳酸盐和铀矿石等围岩密切相关。  相似文献   

内蒙古赤峰地区安家营子金矿成矿流体研究   总被引：6，自引：1，他引：6  

李永刚翟明国  苗来成薛良伟  朱嘉伟关鸿 《岩石学报》2004,20(4):961-968

该金矿床产于晚燕山期安家营子二长花岗岩岩体内,受NNE向断裂带控制。矿化类型属蚀变岩型。矿物包裹体研冤表明,成矿流体为CO2-H2O-NaCl-KCl体系,来自安家营子花岗岩浆期后热液,其氢氧同位素组成分别为δD=-80.0~-96.5‰,δ18OH2O=4.5~5.7‰。主成矿期四个成矿阶段包裹体的均一温度和盐度分别为Ⅰ=340~360℃:Ⅱ=315~330℃,3.80~6.20 wt％／NaCl,CO2密度0.2~0.3 g／cm3;Ⅲ=245~285℃,3.5~4.5 wt％NaCl:Ⅳ=150~170℃,<2.0wt％NaCl。成矿流体盐度和CO2密度均较低。包裹体气相成分中(CH4 CO)／CO2<0.1,成矿环境为弱还原条件;液相成分中K Na 总量较高,K >Na 有利于碱质交代成矿作用。根据CO2包裹体获得资料计算,成矿压力为500~750×105Pa,成矿深度为2.0~2.5 km。流体控矿因素有水-岩反应、CO2与H2O-NaCl溶液不混溶和硫浓度降低等。其中以水-岩反应为主,它贯穿成矿全过程,控制原始成矿流体由碱性向弱碱性-弱酸性变化,使流体发生交代成矿作用。  相似文献   

沉积盆地中的流体包裹体：理论基础、图解与分析方法     

JeanDUBESSY 《岩石学报》2004,20(6):1301-1318

本文主要介绍如何利用流体包裹体来获得合理的数据。首先对H2O-体系进行总结，着重介绍利用显微测温法和其他新的分析技术来确定流体的组成，并举例说明流体混合在流体包裹体研究中的应用。介绍了H2O-(气)-盐体系特别是CO2-CH4体系的图解，探讨了在低温下由于笼舍物的形成H2O-(气)-盐体系的复杂相变。重点介绍显微激光拉曼光谱仪在含甲烷水溶液流体中的应用，并根据相图详细讨论了如何确定流体的不混溶。  相似文献   

Genetic significance of fluid inclusions in the CSA Cu–Pb–Zn deposit, Cobar, Australia     

Alan D. Giles  Brian Marshall   《Ore Geology Reviews》2004,24(3-4):241

CSA mine exploits a ‘Cobar-type’ Cu–Pb–Zn±Au±Ag deposit within a cleaved and metamorphosed portion of the Cobar Supergroup, central New South Wales. The deposit comprises systems of ‘lenses’ that encompass veins, disseminations and semi-massive to massive Cu–Pb–Zn ores. The systems and contained lenses truncate bedding, are approximately coplanar with regional cleavage and similarly oriented shear zones and plunge parallel to the elongation lineation. Systems have extreme vertical continuity (>1000 m), short strike length (400 m) and narrow width (100 m), exhibit vertical and lateral ore-type variation and have alteration haloes. Models of ore formation include classical hydrothermalism, structurally controlled remobilisation and polymodal concepts; syntectonic emplacement now holds sway.Fluid inclusions were examined from quartz±sulphide veins adjacent to now-extracted ore, from coexisting quartz–sulphide within ore, and from vughs in barren quartz veins. Lack of early primary inclusions precluded direct determination of fluids associated with D₂–D₃ ore and vein emplacement. Similarly, decrepitation (by near-isobaric heating) of the two oldest secondary populations precluded direct determination of fluid phases immediately following D₂–D₃ ore and vein emplacement. Post-decrepitation outflow (late D₃ to early post-D₃) is recorded by monophase CH₄ inclusions. Entrained outflow of deeply circulated meteoric fluid modified the CH₄ system; modification is recorded by H₂O+CH₄ and H₂O+(trace CH₄) secondary populations and by an H₂O+(trace CH₄) primary population. The contractional tectonics (D₂–D₃) of ore emplacement was superseded by relaxational tectonics (D_4P) that facilitated meteoric water penetration and return flow.Under D₂ prograde metamorphism, entrapment temperatures (Tt) and pressures (Pt) for pre-decrepitation secondary inclusions are estimated as Tt300–330 °C and Pt1.5–2 kbar≈Plith (the lithostatic pressure). Decrepitation accompanied peak metamorphism (T350–380 °C) in mid- to late-D₃, while in late-D₃ to early post-D₃, essentially monophase CH₄ secondary inclusions were entrapped at Tt350 °C and Pt=1.5–2 kbar≈Plith. Subsequently, abundant CH₄ and entrained meteoric water were entrapped as H₂O+CH₄ secondaries under slowly decreasing temperature (Tt330–350 °C) and constant pressure (Pt1.5–2 kbar). Finally, with increasingly dominant meteoric outflow, H₂O+(trace CH₄) populations record decreasing temperatures (Tt>300 to <350 down to 275–300 °C) at pressures of Phydrostatic<Pt (1 kbar) <Plith (1.5 kbar).The populations of inclusions provide insight into fluid types, flow regimes and P–T conditions during parts of the deposit's evolution. They indirectly support the role of basin-derived CH₄ fluids in ore formation, but provide no insight into a basement-sourced ore-forming fluid. They fully support post-ore involvement of meteoric water. The poorly constrained entrapment history is believed to span 10 Ma from 395 to 385 Ma.  相似文献   

Structural controls on gold mineralisation and the nature of related fluids of the Paiol gold deposit, Almas Greenstone Belt, Brazil     

Mrcio Anselmo Duarte Ferrari  Asit Choudhuri 《Ore Geology Reviews》2004,24(3-4):173

Chemical analyses suggest that the metavolcanic rocks of the Almas Greenstone Belt (AGB), Tocantins State, Brazil have a continental affinity, possibly related to a continental rift environment. They were metamorphosed to amphibolite facies during a regional tectono-metamorphic event (D_n), retrogressed to greenschist facies assemblages and then hydrothermally altered within dextral strike–slip shear zones (D_n+1). Fracture sets related to D_n+2 intersect S_n+1.The Paiol Gold Mine is one of several mineralised zones within metabasic and meta-intermediate rocks of the AGB. It exploits shoots of sulphide–Au–quartz mineralisation that occupy dilational zones approximately perpendicular to an elongation lineation (L_n+1) within mylonitic foliation S_n+1 (S_n+1=S within the S–C fabric). The dilational zones probably formed due to dextral displacement on sinistrally en echelon C surfaces. Minor amounts of gold may have been introduced or remobilised during D_n+2.Coexisting primary and pseudosecondary fluid inclusions in mineralised quartz veins from ore shoots comprise a high-salinity three-phase type (Type II) and a lower salinity two-phase type (Type I). Homogenisation temperatures for Type II inclusions range from 200 to 410 °C and Type I from 90 to 320 °C. The inclusions and their temperature ranges are believed to reflect heat exchange and some mixing between the two fluid types under relatively constant ambient temperatures, but variable (though broadly declining) fluid temperatures. This took place late in D_n+1 in conjunction with greenschist facies retrogression and localised hydrothermally induced metasomatism.  相似文献   

Conditions of pocket formation in the Oktyabrskaya tourmaline-rich gem pegmatite (the Malkhan field, Central Transbaikalia, Russia)     

Igor S. Peretyazhko  Victor Ye. Zagorsky  Sergey Z. Smirnov  Mikhail Y. Mikhailov 《Chemical Geology》2004,210(1-4):91-111

Coexisting melt (MI), fluid-melt (FMI) and fluid (FI) inclusions in quartz from the Oktaybrskaya pegmatite, central Transbaikalia, have been studied and the thermodynamic modeling of PVTX-properties of aqueous orthoboric-acid fluids has been carried out to define the conditions of pocket formation. At room temperature, FMI in early pocket quartz and in quartz from the coarse-grained quartz–oligoclase host pegmatite contain crystalline aggregates and an orthoboric-acid fluid. The portion of FMI in inclusion assemblages decreases and the volume of fluid in inclusions increases from the early to the late growth zones in the pocket quartz. No FMI have been found in the late growth zones. Significant variations of solid/fluid ratios in the neighboring FMI result from heterogeneous entrapment of coexisting melts and fluids by a host mineral. Raman spectroscopy, SEM EDS and EMPA indicate that the crystalline aggregates in FMI are dominated by mica minerals of the boron-rich muscovite–nanpingite CsAl₂[AlSi₃O₁₀](OH,F)₂ series as well as lepidolite. Topaz, quartz, potassium feldspar and several unidentified minerals occur in much lower amounts. Fluid isolations in FMI and FI have similar total salinity (4–8 wt.% NaCl eq.) and H₃BO₃ contents (12–16 wt.%). The melt inclusions in host-pegmatite quartz homogenize at 570–600 °C. The silicate crystalline aggregates in large inclusions in pocket quartz completely melt at 615 °C. However, even after those inclusions were significantly overheated at 650±10 °C and 2.5 kbar during 24 h they remained non-homogeneous and displayed two types: (i) glass+unmelted crystals and (ii) fluid+glass. The FMI glasses contain 1.94–2.73 wt.% F, 2.51 wt.% B₂O₃, 3.64–5.20 wt.% Cs₂O, 0.54 wt.% Li₂O, 0.57 wt.% Ta₂O₅, 0.10 wt.% Nb₂O₅, 0.12 wt.% BeO. The H₂O content of the glass could exceed 12 wt.%. Such compositions suggest that the residual melts of the latest magmatic stage were strongly enriched in H₂O, B, F, Cs and contained elevated concentrations of Li, Be, Ta, and Nb. FMI microthermometry showed that those melts could have crystallized at 615–550 °C.

Crystallization of quartz–feldspar pegmatite matrix leads to the formation of H₂O-, B- and F-enriched residual melts and associated fluids (prototypes of pockets). Fluids of different compositions and residual melts of different liquidus–solidus P–T-conditions would form pockets with various internal fluid pressures. During crystallization, those melts release more aqueous fluids resulting in a further increase of the fluid pressure in pockets. A significant overpressure and a possible pressure gradient between the neighboring pockets would induce fracturing of pockets and “fluid explosions”. The fracturing commonly results in the crushing of pocket walls, formation of new fractures connecting adjacent pockets, heterogenization and mixing of pocket fluids. Such newly formed fluids would interact with a primary pegmatite matrix along the fractures and cause autometasomatic alteration, recrystallization, leaching and formation of “primary–secondary” pockets.  相似文献   

The reflection of plane waves in a poroelastic half-space saturated with inviscid fluid   总被引：8，自引：2，他引：8  

Chi-Hsin Lin  Vincent W. Lee  Mihailo D. Trifunac   《Soil Dynamics and Earthquake Engineering》2005,25(3):205-223

This paper discusses surface displacements, surface strain, rocking, and energy partitioning during reflection-of-plane waves in a fluid-saturated poroelastic half-space. The medium is modeled by Biot's theory, and is assumed to be saturated with inviscid fluid. A linear porosity-modulus relation based on experimental data on sandstones is used to determine the material parameters for Biot's model. Numerical results in terms of angle of incident waves and Poisson's ratio are illustrated for various porosities and degrees of solid frame stiffness. The results show that the amount of solid frame stiffness controls the response of a fluid-saturated porous system. A poroelastic medium with essentially dry-frame stiffness behaves like an elastic medium, and the influence of pore fluid increases as dry-frame stiffness is reduced. The effects of a second P-wave become noticeable in poroelastic media with low dry-frame stiffness.  相似文献