一种合成2,2-二甲基-4-戊烯酸的方法     

钱佐国  孙明昆  李东慧  邹忠英 《中国海洋大学学报(自然科学版)》1999,(2)

报道一种合成２,２－二甲基－４－戊烯酸的新方法。由异丁醛与烯丙醇缩合得到２,２－二甲基－４－戊烯醛,后者经氧化银选择氧化生成２,２－二甲基－４－戊烯酸。此法氧化产率（９６％）高于分子氧氧化法（６１％）和歧化法（４１％）。反应中析出的金属银能定量回收,循环使用。  相似文献   

鸭绿江口溶解有机碳的研究   总被引：3，自引：2，他引：1  

王江涛  于志刚  张经 《中国海洋大学学报(自然科学版)》1998,(3)

１９９６年５月采样测定鸭绿江口溶解有机碳（ＤＯＣ）的含量,得出分布变化特征,并同其它一些河口的溶解有机碳进行了比较。鸭绿江口表层水溶解有机碳的平均含量为２０８μｍｏｌＣ／Ｌ。在盐度大于１．６的河口区,溶解有机碳的分布主要受海水稀释作用控制;在盐度０～１．６的区域溶解有机碳的浓度随盐度的增加而明显增加。在最大混浊带,ＤＯＣ的浓度最高,表明有颗粒有机碳转化为溶解有机碳。丹东市以上流段,河水中溶解有机碳的含量相对较低,说明由丹东市引入的工业及生活污水对鸭绿江水体中溶解有机碳的含量有一定的影响。  相似文献   

Dynamics of DOC of euphotic layer in the Taiwan Strait——Diurnal variation of large range     

Peng Xingyue  Hong Huasheng  Shang Shaoling 《海洋学报(英文版)》1998,17(4):483-493

ThisstudywassupportedbytheStateEducationalCommittee(SEC)ofChina.INTRODUCTIONThedissolvedorganiccarbon(DOC),ordissolvedorganicmatter(DOM),isoneofthemostimPortantorganiccarbonreservoiroftheworld,whichmayaffectthecontentofCO2intheatmospherewithatime-scaleof1OOO~1OOOOyears(Hedges,1992).Theratesofproduction,degradationortransPortationofDOCareseveralmaindynamicalparametersofDOCintheeu-photiclayer.Inthispaper,wefocusonthediurnalvariationsofDOCinordertoestimatetheseparameters.METso…  相似文献   

TOC-IRMS联用在线高温氧化测定溶解有机碳稳定同位素组成的方法研究          下载免费PDF全文

粟蓉  申凯文  尹希杰  杨海丽 《应用海洋学学报》2023,42(2):339-345

本研究利用总有机碳分析仪联用稳定同位素质谱仪（TOC-IRMS）技术,探讨了高温氧化法测试水体中溶解有机碳（Dissolved Organic Carbon, DOC）含量及稳定碳同位素组成。根据溶解有机碳的组成特征,从氧化难易程度、分子结构等方面选取5种可溶于水的化合物：咖啡因、葡萄糖、邻苯二甲酸、乙酸钾和腐殖酸钠,配置成DOC溶液。通过改变溶液碳含量、氧化温度、通氧量大小,载气流速等参数,研究不同实验条件对DOC碳转化率及δ¹³C值的影响。TOC-IRMS在氧化温度850 ℃,通氧时长20 s（流速10 cm³/min）,载气流速80 cm³/min的条件下,测得5种化合物不同浓度DOC溶液的平均碳转化率为95.69%~103.57%;δ¹³C值与标定参考值基本一致,差值范围为--0.82‰~0.55‰。在上述实验条件下,测得不同类型水样的DOC含量相对标准偏差小于3.7%,δ¹³C值的标准偏差小于0.2‰,结果表明TOC-IRMS联用在线高温氧化法测定不同类型水样的DOC含量和稳定碳同位素值满足测试精度要求。  相似文献   

Total Organic Carbon (TOC) as a Sum Parameter of Water Pollution in Selected Polish Rivers (Vistula,Odra, and Warta)     

J. Siepak 《洁净——土壤、空气、水》1999,27(5):282-285

This paper reports on total organic carbon (TOC) and its fractions dissolved organic carbon (DOC) and particulate organic carbon (POC) studied in different Polish rivers. The samples investigated came from the Vistula, Odra, and Warta rivers, and were compared with similar data on river waters available in the literature. The DOC concentrations ranged from 10.0 to 14.2 mg/L and did not vary during the vegetative season. The POC values considerably increased from May through September and reached a maximum in summer. Results for the years 1991τ1996 evidenced a significant increase in the POC value for the Polish rivers from 10.8 to 24.5 mg/L, in comparison with analogous values for West European rivers and North American ones. The enhanced values of TOC and POC were interpreted as being due to anthropogenic pollution.  相似文献   

Dissolved Carbohydrate Concentration,Composition, and Bioavailability to Microbial Heterotrophs in Stream Water     

Th. J. Gremm  L. A. Kaplan 《洁净——土壤、空气、水》1998,26(3):167-171

Dissolved total carbohydrates (DTCH), dissolved free monosaccharides (DFMS), dissolved organic carbon (DOC), biodegradable DOC (BDOC), and humic substances (HS) were measured in White Clay Creek (WCC), a stream in southeastern Pennsylvania Piedmont, USA. Samples were collected over different seasons and under baseflow and stormflow conditions. DOC concentrations ranged from 1.0 to 12.8 mg/L C with the highest concentrations associated with stormflows. Carbohydrates ranged from 0.42 to 12.4 μM and accounted for 2.9 to 12.7% of the DOC. Humic substances represented the major DOC fraction, accounting for 55 to 72% of the DOC pool under all flow conditions. The humic fraction had a lower carbohydrate content (4.4%) than the non-humic fraction of DOC (7.2%). Stormflow DOC was enriched in carbohydrates relative to baseflow DOC, but the percentage of humic-C changed little. Carbohydrates were primarily present as dissolved polysaccharides (55%), but a significant fraction was bound to humic substances (40%), while a small proportion was present as monosaccharides (5%). The major monosaccharides in stream water, listed in order of decreasing concentration, included glucose, galactose, rhamnose, xylose, arabinose, mannose, and fucose. On average (30.6 ± 7.4)% (n = 44) of the stream water DOC was biodegradable, and carbohydrates accounted for 9.9 to 17.7% of the BDOC.  相似文献   

Impact of the water salinity on the hydraulic conductivity of fen peat          下载免费PDF全文

Lennart Gosch  Manon Janssen  Bernd Lennartz 《水文研究》2018,32(9):1214-1222

Coastal peatlands represent an interface between marine and terrestrial ecosystems; their hydrology is affected by salt and fresh water inflow alike. Previous studies on bog peat have shown that pore water salinity can have an impact on the saturated hydraulic conductivity (K_s) of peat because of chemical pore dilation effects. In this study, we aimed at quantifying the impact of higher salinities (up to 3.5% NaCl) on K_s of fen peat. Two experiments employing a constant‐head upward‐flow permeameter and differing in measurement and salinity change duration were conducted. Additionally, a third experiment to determine the impact of water salinity on the release of dissolved organic carbon (DOC) of the studied peat type was carried out. The results show a decrease of K_s with time, which does not depend on the water salinity but is differently shaped for different peat types. We assume pore clogging due to a conglomerate of physical, chemical, and biological processes, which rather depend on water movement rate and time than on water salinity. However, an increased water salinity did increase the DOC release. We conclude that salinity‐dependent behaviour of K_s is a function of peat chemistry and that for some peat types, salinity may only affect the DOC release without having a pronounced impact on water flow.  相似文献   

Increasing Iron Concentrations in UK Upland Waters     

C. Neal  S. Lofts  C. D. Evans  B. Reynolds  E. Tipping  M. Neal 《Aquatic Geochemistry》2008,14(3):263-288

Iron distributions in rainfall, streams, soils and groundwaters are described for the Upper River Severn catchment of mid-Wales. Iron is mainly supplied from within-catchment sources with highest concentrations occurring under reducing conditions. Iron concentrations have doubled over the past 20 years (~5.0 μg yr⁻¹ for the forest and ~3.7 μg yr⁻¹ for the moorland). For the forested sites, the gradients are particularly high post-1993. UK rivers/lakes monitored by the UK Acid Waters Monitoring Network show similar increases. Generally, Fe correlates with dissolved organic carbon (DOC). The greatest rates of Fe increase coincide with those for DOC. Thermodynamic modelling using WHAM/Model VI indicates that Fe(III) is mainly in microparticulate form (probably oxyhydroxides) apart from under reducing conditions. It is proposed that Fe increases for surface waters are associated with increased microparticulate Fe(III) due to stabilisation against aggregation by binding of DOM to its surface. The results relate to acidification declines and deforestation leading to land disturbance and wetter conditions within the soil. There will be greater acidification reversal following tree harvesting due to lowering of atmospheric SO_x scavenging and this may have resulted in the greater increase in Fe in the later years of the study.  相似文献   

Comparative study on projected clustering methods for hyperspectral imagery classification     

Anand Mehta  Onkar Dikshit 《国际地球制图》2016,31(3):296-307

In this study, projected clustering is introduced to hyperspectral imagery for unsupervised classification. The main advantage of projected clustering lies in its ability to simultaneously perform feature selection and clustering. This framework also allows selection of different sets of dimensions (features/bands) for different clusters. This framework provides an effective way to address the issues associated with the high dimensionality of the data. Experiments are conducted on both synthetic and real hyperspectral imagery. For this purpose, projected clustering algorithms are implemented and compared with k-means and k-means preceded by principal component analysis. Preliminary analyses of studied algorithms on synthetic hyperspectral imagery demonstrate good results. For real hyperspectral imagery, only ORCLUS is able to produce acceptable results as compared to other unsupervised methods. The main concern lies with identification of right parameter settings. More experiments are required in this direction.  相似文献   

Estimating dissolved organic carbon concentration in turbid coastal waters using optical remote sensing observations     

《International Journal of Applied Earth Observation and Geoinformation》2016

Dissolved Organic Carbon (DOC) is an important component in the global carbon cycle. It also plays an important role in influencing the coastal ocean biogeochemical (BGC) cycles and light environment. Studies focussing on DOC dynamics in coastal waters are data constrained due to the high costs associated with in situ water sampling campaigns. Satellite optical remote sensing has the potential to provide continuous, cost-effective DOC estimates. In this study we used a bio-optics dataset collected in turbid coastal waters of Moreton Bay (MB), Australia, during 2011 to develop a remote sensing algorithm to estimate DOC. This dataset includes data from flood and non-flood conditions. In MB, DOC concentration varied over a wide range (20–520 μM C) and had a good correlation (R² = 0.78) with absorption due to coloured dissolved organic matter (CDOM) and remote sensing reflectance. Using this data set we developed an empirical algorithm to derive DOC concentrations from the ratio of R_rs(412)/R_rs(488) and tested it with independent datasets. In this study, we demonstrate the ability to estimate DOC using remotely sensed optical observations in turbid coastal waters.  相似文献