Structural and vibrational behaviour of fluorapatite with pressure. Part I: in situ single-crystal X-ray diffraction investigation     

P. Comodi  Yu Liu  P. F. Zanazzi  M. Montagnoli 《Physics and Chemistry of Minerals》2001,28(4):219-224

Using single-crystal X-ray diffraction from a diamond anvil cell, the compressibility of a synthetic fluorapatite was determined up to about 7?GPa. The compression pattern was anisotropic, with greater change along a than c. Unit cell parameters varied linearly with β _a =3.32(8)?10^?3 and β _c =2.40(5)?10^?3 GPa^?1, giving a ratio β _a :β _c =1.38:1. Data fitted with a third-order Birch-Murnaghan EOS yielded a bulk modulus of K ₀=93(4)?GPa with K′=5.8(1.8). The evolution of the crystal structure of fluorapatite was analysed using data collected at room pressure, at 3.04 and 4.72?GPa. The bulk modulus of phosphate tetrahedron is about three times greater than the bulk modulus of calcium polyhedra. The values were 270(10), 100(4) and 86(3) GPa for P, Ca1 (nine-coordinated) and Ca2 (seven-coordinated) respectively. While the calcium polyhedra became more regular with pressure, the distortion of the phosphate tetrahedron remained unchanged. The size of the channel extending along the [001] direction represented the most compressible direction. The Ca2–Ca2 distance decreased from 3.982 to 3.897?Å on compression from 0.0001 to 4.72?GPa. The anisotropic compressional pattern may be understood in terms of the greater compressibility of the channel size over the polyhedral units. The reduction of the channel volume was measured by the evolution of the trigonal prism, having the Ca2–Ca2–Ca2 triangle as its base and the c lattice parameter as its height. This prism volume changed from 47.3?ų at room pressure to 44.78?ų at 4.72?GPa. Its relatively high bulk moduli, 86(3) GPa, indicated that the channel did not collapse with pressure and the apatite structure could remain stable at very high pressure.  相似文献   

水稻本田期冠层叶色变化节奏的光谱监测     

陈玉泉  王延颐  孙玲  刘羽 《遥感学报》1996,(2)

以Ｅｘｏｔｅｃｈ１００ＢＸ光谱辐射计对不同类型水稻材料无肥处理本田期的监测结果表明，晚熟类型材料武育粳２号，冠层叶色显示出“三黑三黄”的变化节奏。“三黑”出现的时间是：移栽至分蘖末期，枝梗分化期至颖花分化期，花粉母细胞形成及减数分裂期至始穗期；“三黄”出现的时间是：分蘖末期至枝梗分化期，颖花分化期至花粉母细胞形成及减数分裂期，始穗至灌浆期。中熟类型材料汕优６３，冠层叶色显示出“二黑二黄”的变化节奏。“二黑”出现的时间是：移栽至颖花分化期，花粉母细胞形成及减数分裂期至始穗期：“二黄”出现的时间是：颖花分化期至花粉母细胞形成及减数分裂期，始穗至灌浆期。早熟类型材料亚优２号，冠层叶色显示出“一黑一黄”的变化节奏。“一黑”出现的时间是：移栽至颖花分化期；“一黄”出现的时间是：颖花分化期至灌浆期。  相似文献   

甘肃省东部旱作区土壤水分变化规律的研究   总被引：13，自引：1，他引：13  

仇化民  邓振镛 《高原气象》1996,15(3):334-341

甘肃省东部旱作区的气候条件，降水补给作用及作物生长发育状况的特殊性，导致土壤水分具有独特的时空分布规律，麦田２ｍ土层水分的周年变化呈一峰一谷型，可划分为旱季失墒消耗阶段和雨季蓄墒贮水阶段；其垂直变化呈“Ｓ”型，可划分为水分多变层、过渡层及稳定层。  相似文献   

A Eulerian air pollution model for Europe with nonlinear chemistry   总被引：1，自引：0，他引：1  

Z. Zlatev  J. Christensen  Ø. Hov 《Journal of Atmospheric Chemistry》1992,15(1):1-37

A long-range transport model with nonlinear chemical reactions is described. The model contains 35 pollutants and 70 chemical reactions. This is a Eulerian model defined on a space domain containing the whole of Europe. The spherical space domain (corresponding to the Earth's surface covered by the model) is mapped into a square plane domain and discretized by using a 32×32 grid. The grid increments are equidistant (both along the Ox axis and along the Oy axis). The choice of values of the physical parameters involved in the model and the numerical treatment of the model are shortly discussed. The model is tested with meteorological data for 1985 and 1989. The numerical results are compared with measurements at stations located in different European countries. Extensive comparisons of ozone concentrations for July 1985 with measurements taken at 24 European stations are also carried out. Results concerning three episodes in July 1985 as well as results obtained in the study of the sensitivity of the ozone concentrations to variations of NO _x and/or anthropogenic VOC emissions are presented. The advantages and the limitations of such a model are discussed. The model is continuously improved by adding new modules to it. The plans for improvements in the near future are outlined.  相似文献   

长周期地震观测中的环境干扰     

邱国荣 《地震地磁观测与研究》1992,13(2):61-66

文章根据长周期地震观测的理论和我国763长周期台网的观测实践,分析了长周期观测中的环境干扰。认为长周期观测对环境干扰(主要指温、湿度)敏感,但影响长周期仪器正常工作的关键是潮湿,尤其是记录室的潮湿。文章以763台网优秀台站的观测实践为例,认为只要掌握了环境干扰的规律,在防潮问题上采取有效措施,长周期地震观测是完全可以做到仪器工作稳定,管理得心应手。  相似文献   

青海可可西里无人区夏季温度分布特征   总被引：1，自引：0，他引：1  

张琳 《高原气象》1992,11(2):203-207

  相似文献   

双线偏振雷达雨区衰减订正问题的模拟计算与讨论   总被引：1，自引：6，他引：1  

刘黎平  徐宝祥 《高原气象》1992,11(3):235-240

  相似文献   

菏泽5.9级地震前后水准测量与承压水变化关系的研究     

王瑞田  赵宪超 《内陆地震》1992,6(4):383-387

利用深层承压水头观测结果,对东明——菏泽长水准测线8——9号测段的高差变化进行了回归计算和相关分析。认为菏泽市城区9号测点下沉的主要原因是受深层承压水头变化的影响。排除地下水影响因素后证实,1983年11月7日菏泽5.9级地震前后仅3mm左右的升降变化,表明9号测点对这次中强地震仅能反映微弱的形变信息量。  相似文献   

高温高压下上地幔岩石电导率实验研究          下载免费PDF全文

高春杨  黄晓葛  代唯琪  陈祖安 《地球物理学报》1954,63(9):3409-3419

为了建立具有普遍适用性的上地幔电性结构,本文利用Kawai-1000t压机和Solartron IS-1260阻抗/增益-相位分析仪,在4.0~14.0 GPa、873~1673 K的条件下,采用交流阻抗谱法（频率范围10^-1~10⁶Hz）测量了不含水的地幔岩电导率.实验结果显示,岩石的电导率随温度升高而大幅度的增大;在较大的温度范围内岩石的导电机制发生了变化,中低温时为小极化子导电,此时激活焓为0.94 eV （±0.13） eV,激活体积为0.11（±0.92） cm³·mol^-1,高温时为和镁空穴相关的离子导电,此时激活焓为1.6~3.17 eV,激活体积为6.75（±7.43） cm³·mol^-1;本次测量的电导率比低压下岩石的电导率要高,比矿物的电导率也要高.用本次的实验结果回归计算得到Fennoscandian地区的上地幔的一维电导率剖面,发现200 km以上本次实验计算的结果和大地电磁测深的电导率剖面吻合的比较好,在200 km以下本次实验得到的要比野外测量的电导率稍稍高一点,可能是因为实验过程中没有完全避免水的影响.本次的实验结果比用有效均匀介质方法计算得到的pyrolite矿物模型的电导率要高出两个数量级,这样的结果显示只用一种矿物的电导率或是几种矿物理论计算的结果有一定的不合理性.  相似文献   

藏北高原D110点不同季节土壤温度的日变化特征   总被引：11，自引：0，他引：11  

杨梅学  姚檀栋  丁永建  王绍令  陈贤章  小池俊雄 《地理科学》1999,19(6):570-574

利用１９９８年ＧＡＭＥ－Ｔｉｂｅｔ加强观测期间取得的一个年周期的土壤温度资料,对藏北高原Ｄ１１０点土壤温度日变化特征的月际变化进行了分析。结果表明,在夏半年（５－９）月土壤温度存在明显的日变化,且基本上按正弦曲线变化,但相位随深度的增加而滞后;冬半年土壤温度尽管也存在日变化,但变幅较小。  相似文献