Evaluations of heavy metal pollution in sediment and Mullus barbatus from the Izmir Bay (Eastern Aegean) during 1997-2009     

Kucuksezgin F  Kontas A  Uluturhan E 《Marine pollution bulletin》2011,62(7):1562-1571

Izmir Bay is one of the great natural bays of the Mediterranean. The surface sediment and fish samples were collected during 1997-2009. The sediment concentrations of inner bay showed significant enrichments during sampling periods. Outer and middle bays exhibited low levels of metal enrichments except the estuary of Gediz River. The concentrations were generally higher than the background levels from the Mediterranean and Aegean except Cd and Pb levels gradually decreased. Metal EF is used as an index to evaluate anthropogenic influences of metals in sediments. Maximum metal enrichment was found for Hg in the outer bay, while Pb indicated maximum enrichment in the middle-inner bays. Metal levels were evaluated in sediments in accordance with the numerical SQG of the USEPA. The levels of fish tissues were lower than the results reported from polluted areas of the Mediterranean. The highest BAFs were detected for Hg and Cd in fish.  相似文献   

Spatial and temporal variations in trace metal concentrations in surface sediments of the Marennes Oléron Bay. Relation to hydrodynamic forcing     

Emilie Strady  Stéphane Kervella  Gérard BlancSerge Robert  Jean Yves StanisièreAlexandra Coynel  Jörg Schäfer 《Continental Shelf Research》2011,31(9):997-1007

Sediments quality assessment is of priority concern to provide a comprehensible overview of ecological and chemical state of an ecosystem. The Marennes-Oléron Bay, hosting the largest oyster production in France, is influenced by the historic polymetallic pollution of the Gironde Estuary. Despite, management efforts and decreasing emissions in the Gironde watershed, Cd levels in oysters from the bay are close to consumption limit (5 μg g⁻¹ dw, EC no. 466/2001). In this context, the aim of the study was to assess the priority metal (Ni, Cu, Zn, As, Ag, Cd, Hg, Pb and Th) concentrations in sediment within the Bay, by investigating spatial and temporal distribution variations and the role of hydrodynamic forcing. For that we selected three sites (east, west and south) characterizing different environments of the Bay and we observed metal concentrations, grain size distribution, bed elevation and wave activities during a year survey. The sampling strategy pointed out both spatial and temporal metal concentrations variability in sediment. In general, metal enrichments were close to geochemical background. The eastern part of the Bay, largely influenced by the Charente river particulate deposition, presented constant concentrations over the survey. In contrast, in the western part, bed elevation was strongly influenced by hydrodynamic forcing especially wave activities, and metal distribution showed constant metal concentrations except very located Cd minor enrichment related to the Gironde influence via the Antioche Strait (north). The southern part was disconnected from the rest of the Bay and showed minor to very located moderately severe Cd enrichment, related to the Gironde water discharges via the Maumusson Strait (south). Thus, the multi-disciplinary approach was relevant to characterize the interactions between hydrodynamic forcing on the environment and sediments and their metal quality state which (i) were close to geochemical background over a year for Ni, Cu, Zn, As, Ag, Hg and Pb (i) which presented enrichment of Cd in the western and southern part.  相似文献   

Strategies for Successful ANAMMOX Enrichment at Laboratory Scale     

Sinan Uyanik  Ozan K. Bekmezci  Adem Yurtsever 《洁净——土壤、空气、水》2011,39(7):653-657

Studies on anaerobic ammonium oxidation (ANAMMOX) have been increasing due to its advantages over traditional nitrification–denitrification systems. However, long and difficult start‐up periods of ANAMMOX reactors may sometimes be frustrating for researchers dealing with them first time in the lab. Therefore, a guide for starting up ANAMMOX reactors will greatly help them and enhance the use of this technology. Three trials, each has three reactors, have been carried out to reach successful start up in this study. An expected ANAMMOX enrichment could not be achieved in the first and second trials. Under the light of the experiences gained from the unsuccessful ones, the third trial resulted in >95% ammonium removals within 20–50 days. It is possible to startup or to enrich ANAMMOX reactors within 50 days by presented strategy guide.  相似文献   

“Source-Diagenesis-Accumulation” enrichment and accumulation regularity of marine shale gas in southern China     

《China Geology》2018,1(3):319-330

After the breakthrough of shale gas exploration and development in the Ordovician Wufeng Formation (Fm.) and Silurian Longmaxi Fm. of Chongqing Jiaoshiba area, Changning-Weiyuan area, etc. in Sichuan basin, a series of discovery and breakthrough were obtained by China Geological Survey in the Cambrian Niutitang Fm. and Sinian Doushantuo Fm. shale of the areas with complicated structure outside Sichuan basin. Based on the understanding of the law of shale gas enrichment in Longmaxi Fm. in the basin, this paper puts forward three elements of the formation and enrichment of shale gas, which are the “Source”, the “Diagenesis” and the “Accumulation”, after deeply studying the law shale gas enrichment and accumulation in Sinian-Cambrian reservoir of the complex structure area outside the basin. The “Source” means the sedimentary environment and petrological characteristics of organic shale. The “Diagenesis” means the basin tectonic subsidence and hydrocarbon generation and expulsion process of organic matter. The “Accumulation” means the tectonic uplift and shale gas preservation. It is proposed that the Sinian-Cambrian and Ordovician-Silurian black shale series in the middle and upper Yangtze region of southern China were both formed in the deep-water shelf environment of rift trough and foreland basin respectively. The dessert intervals were formed in the strong reduction environment under transgressive system tract. The shale lithology belongs to calcium-siliceous and charcoal-siliceous respectively. Based on the summary of structural evolution in Yangtze area, the correlation of structural burial depth with shale diagenesis and the coupling evolution of organic matter with pore structure are discussed. Combining with structural styles, the preservation conditions of shale gas are discussed. Five types of shale gas reservoir control models are further described. Two types of future exploration directions, which are reverse fault syncline and paleo-uplift margin in complex structural area outside the basin, are proposed.  相似文献   

安徽池州马头铜钼矿主成矿元素分布特征及富集机理     

陈雪  马春  刘荣芳 《江苏地质》2014,38(4):575-582

马头铜钼矿床是江南过渡带池州段达到详查级别的矿床。根据该矿床的矿化分布特征、6个钻孔的成矿元素分析结果,结合镜下鉴定分析认为,马头铜钼矿床岩浆热源中心位于15线以南的西山岩体深部,成矿流体运移方向呈南南西→北北东、西山岩体深部→浅部、岩体中心→远离岩体的迁移规律。Cu、Mo、W等金属元素的迁移、沉淀、富集不是某一种因素单独造成的,而是各种物理化学和地质因素共同作用的结果,是不同期次成矿流体产物的叠加。研究区成矿流体至少有2期,一期为富含以钼为主、伴生铜的热液,另一期为以富铜为主的热液。  相似文献   

南方海相页岩气“二元富集”规律——四川盆地及周缘龙马溪组页岩气勘探实践认识   总被引：9，自引：0，他引：9  

郭旭升 《地质学报》2014,88(7):1209-1218

继JY1井龙马溪组页岩测试获得高产工业气流,实现南方海相页岩气的战略突破之后,近期焦石坝地区多口开发井获得高产天然气流,展现出四川盆地海相页岩气勘探的良好前景。通过对四川盆地及周缘多口井的岩性、有机地球化学、岩石矿物含量、物性、储集类型、微观孔隙结构特征、裂缝发育程度、含气量和气井产量、压力等钻探成果及分析测试资料进行深入解剖研究,探索并提出了复杂构造区海相页岩气"二元富集"规律,即:深水陆棚优质泥页岩发育是页岩气"成烃控储"的基础;良好的保存条件是页岩气"成藏控产"的关键。本文对中国南方海相页岩气的高效勘探开发具有重要的借鉴、指导意义。  相似文献   

Chronology of mercury enrichment factors in reef corals from western Venezuela     

Ruth Ramos  Roberto Cipriani  Elia García 《Marine pollution bulletin》2009,58(2):222-229

Mining and deforestation in the early 20th century, the development of petrochemical industries during the 1950s, and the constant weathering of natural deposits of cinabrium (HgS) have made Golfo Triste, Venezuela, a region impacted by mercury (Hg). We studied the chronology of Hg in coral skeletons of Siderastrea siderea (1 colony, 1900-1996) and Montastraea faveolata (2 colonies, 1930-1999) from Parque Nacional San Esteban. Maximum values of Hg/Ca ratios and standard deviations of Hg enrichment factors occurred in the 1940s, 1960s, and 1980s, and matched maxima of decadal rainfall. Values from the 1950s and 1970s matched periods of abundant but constantly decreasing rainfall and hence were best explained by the combination of runoff and the sudden bioavailability of Hg in the region. This sudden availability likely was associated with activities of the chlorine-caustic soda and fertilizer plants of Morón petrochemical complex, industries that started producing large amounts of Hg in 1958.  相似文献   

Assessment of the sources of chemical elements in sediment from Arak Mighan Lake   总被引：2，自引：0，他引：2  

Feridon GHADIMI 《国际泥沙研究》2014,29(2):159-170

Five sediment zones（20 samples） were collected in Mighan Lake,near Arak city in Markazi province,and were analyzed to reveal element sources and assess the quality of metal contamination.Both anthropogenic and natural origins were identified by correlation,factor,and cluster analyse.According to the enrichment factors（EF） of trace metals（Ba,Co,Cr,Cu,Ni,Pb,Rb,Sr,Zr,and Zn）,three groups were identified.Enriched trace elements included：Ni,Zn,and Sr.Comparisons with contamination degree and benchmark sediment quality criteria and guidelines showed that Mighan Lake has potential for adverse effects on aquatic biota because of Ni,Zn,and Cr.  相似文献   

Unsteady soil erosion due to rainfall impact: a model of sediment sorting on the hillslope   总被引：4，自引：0，他引：4  

P. B. Hairsine  G. C. Sander  C. W. Rose  J. -Y. Parlange  W. L. Hogarth  I. Lisle  H. Rouhipour 《Journal of Hydrology》1999,220(3-4):115-128

A new method is presented for predicting sediment sorting associated with soil erosion by raindrop impact for non-equilibrium conditions. The form of soil erosion considered is that which results from raindrop impact in the presence of shallow overland flow itself where the flow is not capable of eroding sediment. The method specifically considers early time runoff and erosion when sediment leaving an eroding area is generally finer and thus may have a higher potential for transport of sorbed pollutants. The new mechanism described is the formation of a deposited layer on the soil surface, which is shown to lead to sediment sorting during an erosion event. The deposited layer is taken to have two roles in this process: to temporarily store sediment on the surface between successive trajectories, and to shield the underlying soil from erosive stresses. Equations describing the dynamics of the suspended sediment mixture and the deposited layer are developed. By integrating these equations over the length of eroding land element and over the duration of the erosion event, an event-based solution is proposed which predicts total sediment sorting over the event. This solution is shown to be consistent with experimentally observed trends in enrichment of fine sediment. Predictions using this approach are found to only partly explain measured enrichment for sets of experimental data for two quite different soils, but to be in poor agreement for an aridsol of dispersive character. It is concluded that the formation of the deposited layer is a significant mechanism in the enrichment of fine sediment and associated sorbed pollutants, but that processes in the dispersive soil are not as well described by the theory presented.  相似文献   

西双版纳国防铁矿控矿条件及矿体分布规律     

杨建华  高旭焦  谭晓伟 《云南地质》2012,(3):335-339

铁矿体赋存于中元古界大勐龙群疆峰旋回第二、四段。含矿岩石为变中基性熔岩、角闪(阳起)斜长变粒岩、透辉钠长(斜长)变粒岩,分为上(Ⅰ)和下(Ⅱ)矿层。上矿层不稳定,下矿层由4个矿体组成复式矿。铁质就地运移、聚集、变质,典型的受变质火山汽液磁铁矿床。  相似文献