Mineralogical and chemical transformation of Oldoinyo Lengai natrocarbonatites, Tanzania     

Anatoly N. Zaitsev  Jrg Keller 《Lithos》2006,91(1-4):191-207

The minerals of Oldoinyo Lengai natrocarbonatite lavas are unstable under atmospheric conditions. Subsolidus mineral assemblages in natrocarbonatites were studied in 105 samples from contemporary eruptions ranging from present day to about 100 years old. The subsolidus minerals in natrocarbonatites were formed (i) along cracks on the lava surface from hot gases escaping during cooling, (ii) as atmospheric alteration by solution of water-soluble minerals, in particular halides and gregoryite, and by hydration of nyerereite under the influence of meteoric water and (iii) by reaction with fumarole gases. After solidification, the lavas were cut by a network of thin cracks, the edges of which are covered by polymineralic encrustations. Samples collected 2–24 h after eruption contain nahcolite, trona, sylvite, and halite with accessory kalicinite and villiaumite. Atmospheric humidity results immediately (≥ 2 h after eruption) in alteration of black lavas that is marked by the appearance of white powdery thermonatrite with nahcolite on the lava surface. Subsequent reaction (weeks, months, years) of natrocarbonatite with meteoric water and the atmosphere results in the formation of pirssonite, gaylussite, shortite, trona, thermonatrite, nahcolite and calcite. Generally, the first important step is the formation of pirssonite and the end-members are calcite carbonate rocks or loose aggregates. Fumarolic activity is common for the active northern crater of the volcano. Reaction of hot (54–141 °C) fumarolic gases with natrocarbonatite leads to the formation of sulphur, gypsum, calcite, anhydrite, monohydrocalcite, barite and celestine. Changes in mineralogy of the natrocarbonatite lead to substantial chemical transformation. The most obvious chemical changes in this process are the loss of Na, K, Cl and S, combined with an increase in H₂O, Ca, Sr, Ba, F and Mn. The oxygen and carbon isotopic composition of altered natrocarbonatites shows a significant shift from the primary “Lengai Box” to high values of δ¹⁸O and δ¹³C. Calcite exhibits δ¹³C values between − 2‰ and − 4‰ PDB and δ¹⁸O values of + 23‰ to + 26‰ SMOW. The observed assemblages of secondary minerals formed by reaction with atmosphere and meteoric water, the changes in chemical composition of the natrocarbonatite and field observations suggest that alteration of natrocarbonatite is an open-system low-temperature process. It takes place at temperatures between 8 and 43 °C with the addition of H₂O to the system and the removal of Na, K, Cl and S from the carbonatites. Low-temperature thermodynamic models developed for alkali carbonate systems can be used for the interpretation of Oldoinyo Lengai subsolidus mineralization.  相似文献   

Heavy metals in freshly deposited sediments of the river Subernarekha, India: an example of lithogenic and anthropogenic effects   总被引：1，自引：0，他引：1  

A. K. Upadhyay  K. K. Gupta  J. K. Sircar  M. K. Deb  G. L. Mundhara 《Environmental Geology》2006,50(3):397-403

Heavy metal distribution patterns in river sediments aid in understanding the exogenic cycling of elements as well as in assessing the effect of anthropogenic influences. In India, the Subernarekha river flows over the Precambrian terrain of the Singhbhum craton in eastern India. The rocks are of an iron ore series and the primary rock types are schist and quartzite. One main tributary, the Kharkhai, flows through granite rocks and subsequently flows through the schist and quartzite layers. The Subernarekha flows through the East Singhbhum district, which is one of India’s industrialised areas known for ore mining, steel production, power generation, cement production and other related activities. Freshly deposited river sediments were collected upstream and downstream the industrial zone. Samples were collected from four locations and analysed in <63-μm sediment fraction for heavy metals including Zn, Pb, Cd and Cu by anodic stripping voltammetry. Enrichment of these elements over and above the local natural concentration level has been calculated and reported. Sediments of the present study are classified by Muller’s geo-accumulation index (I _geo) and vary from element to element and with climatic seasons. During pre-monsoon period the maximum I _geo value for Zn is moderately to highly polluted and for Cu and Pb is moderately polluted, respectively, based on the Muller’s standard. Anthropogenic, lithogenic or cumulative effects of both components are the main reasons for such variations in I _geo values. The basic igneous rock layer through which the river flows or a seasonal rivulet that joins with the main river may be the primary source for lithogenic components.  相似文献   

A GIS-based automated procedure for landslide susceptibility mapping by the Conditional Analysis method: the Baganza valley case study (Italian Northern Apennines)   总被引：14，自引：0，他引：14  

Aldo Clerici  Susanna Perego  Claudio Tellini  Paolo Vescovi 《Environmental Geology》2006,50(7):941-961

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Groundwater study using remote sensing and geographic information systems (GIS) in the central highlands of Eritrea   总被引：3，自引：1，他引：3  

Semere Solomon  Friedrich Quiel 《Hydrogeology Journal》2006,14(6):1029-1041

Remote sensing, evaluation of digital elevation models (DEM), geographic information systems (GIS) and fieldwork techniques were combined to study the groundwater conditions in Eritrea. Remote sensing data were interpreted to produce lithological and lineament maps. DEM was used for lineament and geomorphologic mapping. Field studies permitted the study of structures and correlated them with lineament interpretations. Hydrogeological setting of springs and wells were investigated in the field, from well logs and pumping test data. All thematic layers were integrated and analysed in a GIS. Results show that groundwater occurrence is controlled by lithology, structures and landforms. Highest yields occur in basaltic rocks and are due to primary and secondary porosities. High yielding wells and springs are often related to large lineaments, lineament intersections and corresponding structural features. In metamorphic and igneous intrusive rocks with rugged landforms, groundwater occurs mainly in drainage channels with valley fill deposits. Zones of very good groundwater potential are characteristic for basaltic layers overlying lateritized crystalline rocks, flat topography with dense lineaments and structurally controlled drainage channels with valley fill deposits. The overall results demonstrate that the use of remote sensing and GIS provide potentially powerful tools to study groundwater resources and design a suitable exploration plan.The online version of the original article can be found at  相似文献   

Effect of a submerged bay-mouth breakwater on tsunami behavior analyzed by 2D/3D hybrid model simulation     

Koji Fujima 《Natural Hazards》2006,39(2):179-193

The hybrid numerical model had been developed to simulate a complicated 3D flow around structures generated by tsunami. In the model, the conventional 2D model is adopted for the wide region far from structures and the 3D non-hydrostatic pressure model is used in the limited region adjacent to structures. The applicability of the model is shown by comparisons of the numerical results with the experimental results of the laboratory model tests and the numerical analysis results of the conventional whole 2D simulation. In addition, the effect of a submerged structure at the opening of a breakwater is discussed from the numerical simulations by the hybrid model. The submerged structure improves the stability of the rubble mound and reduces the tsunami inflow into the bay, while it increases the water surface velocity around the opening of the breakwater. The increase of surface velocity causes the increases of impulsive forces by collision with drafts and so on.  相似文献   

Water–rock interaction during the process of steam stimulation exploitation of viscous crude oil in Liaohe Shuguang Oil Field, Liaoning, China     

Qian Hui  Yang Zhenghua  Li Yunfeng  Xu Wancai  Sun Yaqiao 《Environmental Geology》2006,50(2):229-236

In the process of steam stimulation exploitation of viscous crude oil, the injected water, at high temperature and under high pressure, reacts intensively with the host rock. This kind of water–rock interaction in Liaohe Shuguang Oil Field was studied on the basis of analysis of water composition changes, laboratory experiments, mineral saturation indices analysis, and mass balance calculation. Compared with the injected water, the changes of the composition of discharged water are mainly the distinct decrease of pH, Na⁺, SiO₂ and Cl⁻, as well as the increase of K⁺, Ca²⁺, Mg²⁺, SO ₄ ²⁻ and HCO ₃ ⁻ . Laboratory experiments under field conditions showed: the dissolution sequence of minerals quantitatively is quartz>potassium feldspar>albite, and the main change of clay minerals is the conversion of kaolinite to analcime. Mass balance calculation indicated during the process of steam stimulation, large quantities of analcime are precipitated with the dissolution of large amounts of quartz, kaolinite, potassium feldspar, and CO₂. These results correlated very well with the experimental results. The calculated results of Liaohe Shuguang Oil Field showed that during the steam stimulation for viscous crude oil, the amounts of minerals dissolved (precipitated) are huge. To control the clogging of pore spaces of oil reservoirs, increased study of water–rock interaction is needed.  相似文献   

Assessment of sand encroachment in Kuwait using GIS     

Anwar B. Al-helal  Jasem M. Al-awadhi 《Environmental Geology》2006,49(7):960-967

Assessment of sand encroachment in Kuwait using Geographical Information System (GIS) technology has been formulated as a Multi-Criteria Decision Making problem. The Delphi method and Analytical Hierarchy Process were adopted as evaluating techniques, in which experts’ judgments were analyzed for objectively estimating and weighting control factors. Seven triggering factors, depicted in the form of maps, were identified and ordered according to their priority. These factors are (1) wind energy; (2) surface sediment; (3) vegetation density; (4) land use; (5) drainage density; (6) topographic change and (7) vegetation type. The factor maps were digitized, converted to raster data and overlaid to determine their possible spatial relationships. Applying a susceptibility model, a map of sand encroachment susceptibility in Kuwait was developed. The map showed that the areas of very high and high sand encroachment susceptibility are located within the main corridor of sand pathway that coincides with the northwesterly dominant wind direction.  相似文献   

Experimental and numerical studies of rock salt strain hardening     

M. Hamami 《Geotechnical and Geological Engineering》2006,24(5):1271-1292

The work presented in this paper comes as part of a research program dealing with the thermomechanical behaviour of rock salt. It aims to study laboratory and in-situ long-term behaviour by means of creep tests with deviator and temperature changes. The laboratory results, using a triaxial multi-stages creep tests, highlighted the strain hardening character of rock salt. Furthermore, the in-situ results, using a borehole dilatometer multi-step creep test, have shown that the drilling is carried out in a weakly stressed pillar. The interpretation of the laboratory results, using the J.LEMAITRE law, did not indicate full agreement with all the test results. As a result a ‘double’ J.LEMAITRE model, which takes into account a double strain hardening variable, has been put forward. The validation of this model on the laboratory creep tests is very satisfactory. Furthermore, the activation energy seems satisfactory to represent the influence of the temperature. The in-situ behaviour modelling is clearly more complex than the modelization based on laboratory tests. In fact, it seems that if the rock salt behaviour is maintained by J.LEMAITRE law, it is necessary to vary with the stress, at least, one of the parameters assumed constant in the basic law.  相似文献   

A Bay–River Coupled Model for Storm Surge Prediction Along the Andhra Coast of India     

Neetu Agnihotri  P. Chittibabu  Indu Jain  P. C. Sinha  A. D. Rao  S. K. Dube 《Natural Hazards》2006,39(1):83-101

The paper describes a two-dimensional bay–river coupled numerical model for storm surges along the Andhra coast of India. The effect of the Krishna and Godavari rivers on the surge development is analysed. A comparative study of the surge generated by a tropical cyclone with and without the inclusion of rivers is done in detail. Three cyclones that struck the Andhra coast in November 1977, May 1990 and November 1996 were used for the simulation studies. It is found that the idealized model without a river overestimates the sea-level elevation as compared to a more realistic bay–river coupled model. The temporal variation of surge values at the mouth of the rivers is also studied for all three cyclone cases. It is found that the effect of the presence of rivers depends on the strength of the cyclone, its point of landfall and the location of the rivers with respect to the landfall point.  相似文献   

A Connectivity Index for Discrete Fracture Networks     

C. Xu  P. A. Dowd  K. V. Mardia  R. J. Fowell 《Mathematical Geology》2006,38(5):611-634

Connectivity is an important measure for assessing flow transport in rock, especially through fractures. In this paper, rock fracture systems are modelled by a discrete fracture model simulated by a marked point process. A connectivity index is then introduced to quantify the connectivity between any two points in space. Monte Carlo simulation is used to evaluate the connectivity index for stationary cases and relationships between the connectivity index and the parameters of the discrete fracture model are analysed. The average number of intersections per fracture, X_f, and the fracture intensity, P12 (P32), are calculated and the relationships between these parameters and the connectivity index are investigated, concluding that X_f is the more suitable parameter for the classification of rock mass flow properties. The relationships between the connectivity index and the percolation state of the fractured medium are also discussed. An edge correction is briefly discussed and a practical example is used to demonstrate the method of computing the connectivity index.  相似文献