An Algorithm for the Determination of All Significant Pathways in Chemical Reaction Systems     

Ralph Lehmann 《Journal of Atmospheric Chemistry》2004,47(1):45-78

When the output of a complex chemical model is analysed, a typical topic isthe determination of pathways, i.e., reaction sequences, that produce ordestroy a chemical species of interest.A representative example is the investigation of catalytic ozone destruction cycles in the stratosphere.An algorithm for the automatic determination of pathways in any given reactionsystem is presented. Under the assumption that reaction rates are known, it finds all significant pathways, i.e., all pathways with a rate above a prescribed threshold.The algorithm forms pathways step by step, starting from single reactions.The chemical species in the system are consecutively considered as `branching points'.For every branching-point species, each pathway producing it is connected witheach pathway consuming it.Rates proportional to `branching probabilities' are calculated.Pathways with a rate that is smaller than a prescribed threshold arediscarded.If a newly formed pathway contains sub-pathways, e.g., null cycles, it is split into these simpler pathways.In order to demonstrate the performance of the algorithm, it has been applied to the determination of catalytic ozone destruction cycles and methaneoxidation pathways in the stratosphere.  相似文献   

Le Silurien de la région d'Oulad Abbou (Meseta occidentale,Maroc) : une sédimentation péritidale sous contrôle tectonique     

Ahmed Attou  Naima Hamoumi 《Comptes Rendus Geoscience》2004,336(9):767-774

In the Oulad Abbou syncline, western coastal Meseta, the Silurian deposits exhibit siliciclastic or mixed siliciclastic/carbonate tidal facies that recorded alkaline basalt flows and syn-sedimentary deformations. These facies are staked into peritidal shallowing upward sequences reflecting the evolution from an infratidal to a supratidal environment. These sequences recorded low-amplitude and high-frequency sea-level variations. The built-up of these rhythmic sequences is related to distensive tectonic that allowed the development of isolated platform from extensive siliciclastic influx. This tectonic event is well recorded in the palaeogeographic evolution of the northern Gondwana platform during the Lower Palaeozoic time. To cite this article: A. Attou, N. Hamoumi, C. R. Geoscience 336 (2004).  相似文献   

内蒙古中西部地区震源参数和场地响应反演   总被引：15，自引：0，他引：15       下载免费PDF全文

高立新  郑斯华  丁风和 《地震工程学报》2005,27(2):109-114

采用Atkinson方法，基于遗传算法，利用呼和浩特数字地震台网7个子台记录的9次质量较高的地震事件资料，计算了内蒙古中西部地区的品质因子Q值和非弹性衰减系数c（f）。在所研究的频率范围内，前者和频率．厂有很好的线形关系：Q（f）=116．8f^1.000后者与频率．厂的变化关系不明显。在此基础上采用Moya方法反演了7个地震台的场地响应和地震的震源参数，并对它们之间的相互关系进行了讨论。结果显示在所研究的频率域内7个基岩台站的场地均不同程度的存在放大作用，其次震源参数间具有较好的线性关系。本文还详细介绍了Atkinson方法和Moya方法的原理和计算步骤。  相似文献   

Effects of low- to high-angle normal faults on sedimentary architectures in the Eocene Wenchang Formation,Enping Sag,Pearl River Mouth Basin,South China Sea     

Q. H. Liu  Y. Shu  X. M. Zhu  X. H. Yang  M. Tan 《Australian Journal of Earth Sciences》2016,63(7):903-922

The effects of low- to high-angle (>30°) normal faults on sedimentary architectural units in the Eocene Wenchang Formation, Enping Sag, Pearl River Mouth Basin (PRMB), South China Sea were investigated utilising a high-quality 3D seismic data set and restored paleogeomorphology. It has been shown that sequence stratigraphic units and sedimentary architecture are significantly controlled by the low- to high-angle normal faults. The Wenchang Formation, a second-order sequence, can be subdivided into two para-second-sequences (the Lower and Upper Wenchang sequences, E₂W^L and E₂W^U) and seven third-order sequences (from base to top: SQ1～SQ7). The low-angle fault confined sequence architecture of the Wenchang Formation is mainly characterised by lateral stacking with the ratio of the vertical subsidence (V) to horizontal slip (H) being reduced from 1/2 for E₂W^L to 1/6 for E₂W^U. In contrast, the high-angle fault confined sequence is characterised by vertical stacking with the ratio of V/H close to 1 for sequences SQ1 to SQ7. In the 3D seismic area, the features of sediment-dispersal pattern were interpreted based on an integrated analysis of paleogeomorphology, seismic reflection characteristics, stratal thickness distribution and multiple attribute clustering. The results show that the large-scale fan delta, belt-shape lacustrine deposit and bird-foot braided delta systems mainly developed in the low-angle fault confined sequences, whereas small-scale fan delta, rhombus-shaped lacustrine deposit and lobe-shaped braided delta systems inherited tectono-sedimentary architectures in the high-angle fault confined sequences.  相似文献   

四川会理天宝山矿床深部新发现铜矿与铅锌矿的成因关系探讨   总被引：2，自引：1，他引：1  

孙海瑞  周家喜  黄智龙  樊海峰  叶霖  罗开  高建国 《岩石学报》2016,32(11):3407-3417

天宝山矿床是川滇黔接壤铅锌矿集区内的代表性铅锌矿床之一,赋存于上震旦统灯影组白云岩中。近年来,该矿床深部发现了以铜为主的矿化,甚至形成铜矿体。目前,对铜矿成因及其与铅锌矿的关系尚不清晰。本文报道新发现铜矿的矿物学和同位素地球化学资料,以期揭示铜矿的成矿物质来源,结合铅锌矿的相关研究,探讨铜矿形成机制及其与铅锌矿的成因关系。镜下观察和扫描电镜分析显示,铜矿石中主要金属矿物为黄铜矿和银黝铜矿,其次为方铅矿和毒砂,含少量闪锌矿和黄铁矿;铅锌矿石中闪锌矿是主要金属矿物,方铅矿和黄铁矿次之,含少量黄铜矿和深红银矿。铜矿石中闪锌矿主要呈半自形-他形粒状,与黄铜矿共生或被其包裹,方铅矿主要呈细脉状充填在黄铜矿、银黝铜矿和毒砂的裂隙中或呈他形粒状分布在这些矿物中;铅锌矿石中黄铜矿主要呈浸染状分布于闪锌矿之中。两类矿石金属矿物的组构特征,显示铜矿物与铅锌矿物具有密切的共生、穿插和包裹关系,应属同期成矿。同位素地球化学数据显示,铜矿石中黄铜矿的δ34SCDT值为3.9‰~4.2‰(均值为4.1‰,n=3),铅锌矿石闪锌矿的δ34SCDT值为3.3‰~3.9‰(均值为3.5‰,n=3),十分相近,暗示它们具有相似的S源,应均属赋矿地层海相蒸发岩中硫酸盐热化学还原作用的产物。铜矿石中黄铜矿的~(206)Pb/~(204)Pb=18.441~18.476(均值为18.461,n=3),~(207)Pb/~(204)Pb=15.731~15.751(均值为15.741,n=3),~(208)Pb/~(204)Pb=38.809~38.873(均值为38.849,n=3),μ=9.72~9.76;铅锌矿石中方铅矿的~(206)Pb/~(204)Pb=18.442~18.480(均值为18.455,n=3),~(207)Pb/~(204)Pb=15.746~15.763(均值为15.752,n=3),~(208)Pb/~(204)Pb=38.793~38.892(均值为38.840,n=3),μ=9.75~9.78。两者具有相近的Pb同位素组成且其壳源特征明显,表明它们的成矿金属来源相似,均来自上地壳,与赋矿沉积岩有关。综上,矿物学和同位素地球化学证据表明,天宝山矿床深部新发现铜矿与铅锌矿具有明显的同期共生关系和相似的成矿物质来源,是同一成矿热液体系不同阶段演化的产物。天宝山铜铅锌矿床与MVT矿床的成矿特征不同,暗示其成矿作用(环境)特殊,可能与矿床所处的地质背景有关,其成因认识对川滇黔接壤区同类型矿床深部找铜矿具有重要的指导意义。  相似文献   

Hydrothermal Dolomite: A Review and PerspectiveEI北大核心CSCD     

Li Q.  Bao Z. 《大地构造与成矿学》2018,(4):699-717

Hydrothermal dolomite commonly closely associates with oil-gas reservoirs and sediment-hosted Pb-Zn deposits, the Mississippi Valley-type (MVT) Pb-Zn deposits in particular. Host rocks of MVT deposits usually experienced extensive dolomitization, and indeed, hydrothermal dolomite is considered as a useful prospective indicator for MVT mineralization. However, genetic link between the hydrothermal dolomitization and MVT Pb-Zn mineralization is a matter of debate. This paper briefly reviewed the nomenclature and research history of hydrothermal dolomite, introduced the major geological, geochemical characteristics, and distribution of hydrothermal dolomite, spatial and possibly genetic relationship between hdyrothermal dolomite and hdyrothermal ore deposits and oil-gas reservoirs based on case studies including the occurrence of hydrothermal dolomites in MVT deposits in Southwest China. The temporal and genetic relationships between dolomitizaiton and thermal sulfate reduction, sulfide precipitation and thus the location of ore mineralization well worthy more attention, and comprehensive geological and isotope geochemical and state of art in situ techniques will contribute to understanding of the genesis of hydrotherml dolomite and the spatially related ore deposits and oil-gas reservoirs. © 2018, Science Press. All right reserved.  相似文献   

五大连池第四纪火山岩层序划分及其构造与生态意义     

曾普胜  丘顺帆  李睿哲  刘斯文  王十安  赵九江 《地球学报》2021,42(6):785-802

大量前人成果和1:5万区调钻孔资料证实,五大连池第四纪火山地层属于水平岩层.因此,该地区第四纪火山地层的划分,是在地表岩石层序与钻孔岩石层序充分划分与对比的基础上进行的.从沉积角度看,五大连池火山地层属于松嫩盆地连续沉积过程中的第四纪短暂幕式火山喷发所形成的水平岩层.本文结合K-Ar同位素测年新资料,将该区第四纪岩石地层重新划分为11个组级地层单位.其中的火山岩石地层可以自下而上划分为:下更新统焦得布玄武岩(1.214—1.113 Ma);中更新统尾山玄武岩(0.62—0.285 Ma);中更新统笔架山玄武岩(0.24—0.132 Ma)和全新统老黑山玄武岩(距今290～288 a),对夹于其间的正常沉积地层也进行了相应的划分.对层状火山岩层序的层位划分和空间分布研究对于理解五大连池火山群的构造背景和生态环境具有特别重要的意义,五大连池火山群处于中国大陆内部的大同—大兴安岭火山岩带的最北东端,是地幔流体向北东方向流动的最前缘;这类富钾的碱性玄武岩的火山喷发活动对东北富饶的黑土地的形成具有重要贡献,火山岩在嫩江平原上塑造的台地和火山锥地形地貌对生态多样性和优质地下水的生态要素具有重要影响.  相似文献   

湖南滑石矿床类型的划分及找矿方向     

陈民苏  车勤建 《湖南地质》1989,8(1):35-43

湖南滑石矿床类型可分为变质型、沉积风化残余型、中低温热液交代型三类。变质型又可分为区域动力变质和接触变质交代两个亚型。据湖南滑石矿床分布特点、成矿地质条件,全省滑石矿可划为四个成矿带、九个远景区,作为今后滑石找矿方向。  相似文献   

Palaeoenvironmental interpretation of Holocene coastal sequences in the southern bay of Biscay     

A. Cearreta 《International Journal of Earth Sciences》1993,82(2):234-240

The main sedimentary features of the northern coast of the Iberian Peninsula during the Holocene transgression are characterized by the formation of estuaries, the deposition of sand bars and sand beaches, and the accumulation of aeolian dunes. These coastal deposits are very favourable for identifying Quaternary sea-level changes as they contain great volumes of well preserved sediments including marine, brackish and freshwater beds. The micropalaeontological analysis (benthic foraminifera) of diverse littoral sequences has allowed different microfaunal assemblages to be recognised and their corresponding depositional environments determined. Two recurrent phases of sediment build-up as the sea level rose have been distinguished. They have been interpreted as the consequence of two different marine advances in this region: one dated at around 8 000 years BP and the second around 2 500 years BP.  相似文献   

吉林省浑江市荒沟山区花岗岩成因类型探讨   总被引：4，自引：0，他引：4  

王速  邢树文 《吉林地质》1994,13(2):36-41

本文根据吉林省浑江市荒沟山区中生代花岗岩的岩石学、地球化学及同位素地质学研究，论述了该区花岗岩的成因类型，即老秃顶子岩体、梨树沟岩体、草山岩体均为同熔型。  相似文献