Defining the geochemical baseline: a case of Hong Kong soils     

H. B. Zhang  Y. M. Luo  M. H. Wong  Q. G. Zhao  G. L. Zhang 《Environmental Geology》2007,52(5):843-851

A geochemical baseline provides the means to distinguish between the pedogenic origin and the anthropogenic origin of the trace element in the environmental compartments. We collected 271 soil samples representative of different parent rocks and soil types from the whole territory of Hong Kong and analyzed the composition of clay mineralogy and the contents of 15 chemical elements (Fe, Cd, As, etc.) for these samples. The baseline was predicted with the method of the normalization procedure combined with the relative cumulative frequency curve. The result indicated that Fe was the best reference element for the normalization procedure among the five potential reference elements (Fe, Al, Sc, Ti, and Mn), followed by Sc and Ti. A poor correlation was found between Sc, Ti, and Cu. The predicted baseline was much lower than the A-value of the Dutch List used usually in screening the polluted soil of Hong Kong, implying that the extent of heavy metal pollution might have been underestimated with respect to local lands. We also applied the cluster analysis to distinguish the geochemical associations of the trace elements due to its importance to the baseline. Approximately three major associations including the Fe–Mn-oxides related, Al oxides or Al-bearing-clay-mineralogy related and sulfide- related associations were observed from the dendrogram.  相似文献   

High-resolution climate variability of southwest China during 57-70 ka reflected in a stalagmite δ18O record from Xinya Cave   总被引：1，自引：0，他引：1  

Li TingYong  Yuan DaoXian  Li HongChun  Yang Yan  Wang JianLi  Wang XinYa  Li JunYun  Qin JiaMing  Zhang MeiLiang  Lin YuShi 《中国科学D辑(英文版)》2007,50(8):1202-1208

A 26-cm-long stalagmite (XY2) from Xinya Cave in northeastern Chongqing of China has been ICP-MS ²³⁰Th/U dated, showing a depositional hiatus at 2.3 cm depth from the top. The growth of the 2.3–26 cm interval determined by four dates was between 57 ka and 70 ka, with a linear growth rate of 0.023 mm/a. We have analyzed 190 samples for δ ¹⁸O and δ ¹³C, mostly in the 2.3–26 cm part. The δ ¹⁸O and δ ¹³C values between 57 ka and 70 ka reveal decadal-to-centennial climatic variability during the glacial interval of Marine Isotope Stage 4 (MIS4), exhibiting much higher resolution than that of the published Hulu and Dongge records during this interval. Speleothem δ ¹⁸O in eastern China, including our study area can be used as a proxy of summer monsoon strength, with lighter values pointing to stronger summer monsoon and higher precipitation, and vice versa. Two decreases in the δ ¹⁸O signature of XY2 record around 59.5 and 64.5 Ka are argued to correspond to the Dansgaard-Oeschger (D-O) events 17 and 18 respectively. The Heinrich event 6 (H6) can be identified in the record as a heavy δ ¹⁸O peak around 60 ka, indicating significant weakening of the monsoon in Chongqing during the cold period. The XY2 δ ¹⁸O record shows very rapid change toward to the interstadial condition of the D-O event, but more gradual change toward to the cold stadial condition. This phenomenon found in the Greenland ice core records is rarely observed so clearly in previously published speleothem records. According to SPECMAP δ ¹⁸O record, the glacial maximum of MIS 4 was around 64.5 ka with the boundary of MIS 3/4 around 60 ka. Unlike the marine record, the speleothem record of XY2, China, exhibits much high frequency variations without an apparent glacial maximum during MIS 4. However, the timing of MIS 3/4 boundary seems to be around 60 ka when the H6 terminated, in agreement with the marine chronology. The growth period of sample XY2 during glacial times probably reflects a local karstic routing of water, rather than having climatic significance. Supported by the National Natural Science Foundation of China (Grant Nos. 40672165, 90511004, 40672202) and the Academician Special Project of Chongqing Science Committee (Grant No. 2003-7835)  相似文献   

华北陆块南部熊耳群火山岩的地球化学特征与成因   总被引：16，自引：12，他引：16  

金成伟  翟明国  夏斌  周美夫  赵太平 《岩石学报》2002,18(1):56-69

分布于华北陆块南部的熊耳群火山岩由玄武质到流纹质火山岩组成,并以玄武安山岩、安山岩为主,次为英安-流纹岩,SiO2=62％±的岩石较少,显示双峰特点。中基性熔岩的主要造岩矿物是辉石和斜长石,没有角闪石和黑云母,表明熊耳群火山岩形成于相对无水的环境。岩石地球化学上的显著特点是,富K2O、FeO,低Al2O3、MgO、CaO;富含大离子亲石元素(LILE,如K、Rb、Ba)和轻稀土元素(LREE),相对亏损高场强元素(HFSE,Nb、Ta、Ti),表现出岛弧型火山岩的地球化学亲合性。文中详细的岩石地球化学证据表明,熊耳群火山岩具有岛弧型地球化学特征的主要原因是其地幔源区遭受俯冲带组分的改造,而岩浆在上升到地表的过程中混染地壳物质是次要的。基于熊耳群及下伏结晶基底的地质学和地球化学特征,表明熊耳群形成于夭折的三叉裂谷环境,推断俯冲带组分的改造和富集事件发生在华北陆块南部古元古代大陆壳的形成和 拼贴过程中,由于洋壳和地壳物质再循环到上地幔中,使陆下岩石圈地幔源区富集LILE、LREE并亏损HFSE。熊耳期岩浆作用正是源于这样的保留有早期俯冲带组分改造特征的陆下岩石圈富集地幔。  相似文献   

萨拉乌苏河流域150 ka BP以来的粒度旋回   总被引：18，自引：1，他引：18  

张宇红  李保生  靳鹤龄  阎满存  祝一志  李后信  姚春霞  罗开利 《地理学报》2001,56(3):332-344

萨拉乌苏河流域米浪沟湾地层剖面150kaBP以来古流动砂丘砂与河湖相和古土壤在粒度上具有多次显著的粗细韵律交替变化，粒度参数-Mz、σ、Sk、Kg和SC/D亦随之响应为多波动峰谷交替的态势，同时，粒度特征值-φ5、φ16φ、φ25、φ50、φ84、φ9相应地表现为非常有节奏地跳动，据此，将米浪沟湾剖面划分为27个粒度粗细沉积旋回，并认为其是150kaBP以来在东亚冬夏古代季风交替影响下沙漠演变的一个颇为完整的气候-地质过程记录。  相似文献   

Transition of Quaternary glacial cyclicity in deep-sea records at Nansha, the South China Sea     

WANG Pinxian  TIAN Jun  CHENG Xinrong 《中国科学D辑(英文版)》2001,44(10):926-933

High-resolution oxygen isotope records over the last 2249 ka (MIS 1–86) have been obtained from cores of the upper section (105.08 m) at ODP Site 1143 (water depth of 2772 m) drilled in the Nansha area, southern South China Sea. The sampling resolution is at about 2 ka intervals, resulting in one of the best oxygen isotope records over the global ocean. The oxygen isotope curves, displaying details in the Pleistocene glacial cycles, have revealed a nearly 300 ka long stage of transition from a predominant 40 ka to 100 ka periodicity. Therefore, the “Mid-Pleistocene Revolution” should be considered as a process of transition rather than an abrupt change. Within the 100 ka glacial cycles, the changes in tropical sea surface water were found to lead those in high-latitude ice sheet. Our comparisons show that the ice sheet expansion and the glacial stage extension in the Northern Hemisphere with the 100 ka cycles must have been driven not by ice sheet itself, but by processes outside the high latitudes of the Northern Hemisphere.  相似文献   

冀东地区油气微渗漏地植物的遥感基础研究     

黄秀华  张磊 《遥感学报》1992,(2)

本文通过已知含油区及背景区地植物及地表土壤多种微量金属元素和吸附烃的综合分析,并利用遥感资料与物探资料作复合评价,讨论了冀东油气微渗漏地区的遥感植物地球化学标志。  相似文献   

山门银矿地球化学特征及异常模式     

高始河 《吉林地质》1992,11(1):99-105

本文着重论述了山门银矿地球化学特征;水系沉积物,土壤及原生地球化学异常特征和分带性。初步概括出山门银矿床地球化学异常模式及找矿标志。  相似文献   

Use of lichens in detecting environmental risk and in geochemical prospecting     

G. Dongarrà  D. Ottomello  G. Sabatino  M. Triscari 《Environmental Geology》1995,26(3):139-146

This paper provides data on variations in the contents of As, Sb, Ni, V, Pb, Cu, Cr, Au, Zn, Sc, and Al, measured in the thalli of a saxicolous lichen species,Xanthoria calcicola Ochsner s.l., collected in northeastern Sicily, near an industrial zone and along a belt crossing areas of known ores containing sulfides of heavy metals. A total of 91 lichen samples were collected on roof tiles (39) and on rocks (52). In the industrial zone, analysis of lichen thalli revealed high contents of nickel and vanadium, decreasing at increasing distances from the source of contamination. The results have also revealed the versatility ofXanthoria calcicola in geochemical prospecting for heavy metals such as Pb, Zn, As, Au, Sb, Ni, V, and Cu. The contents of these elements in the analyzed lichens highlight the same geochemical associations observed in prospecting surveys on samples of river sediments and identify similar anomalies. Interpretation of data in terms of enrichment factors (EFs) turned out to be particularly useful.  相似文献   

Circulation and fertility of waters in Concepcion Bay     

Ahumada B. Ramón  Rudolph G. Anny  Martinez M. Victorino 《Estuarine, Coastal and Shelf Science》1983,16(1):95-105

The spatial and temporal distributions of oxygen, nutrients and pigments in the waters of Concepcion Bay, Chile (36°40′S, 73°01′W) are described for 1978–1979. Analysis of the seasonal fluctuations shows the upwelling of water poor in oxygen and rich in nutrients inside the bay during summer. The upwelled water fertilizes the bay and produces progressive eutrophication, causing mass mortalities, discoloured water and mineralization of organic matter.  相似文献   

青藏高原拉萨地块碰撞-后碰撞岩浆作用的三种类型及其对大陆俯冲和成矿作用的启示：Sr-Nd同位素证据   总被引：19，自引：13，他引：19  

莫宣学  赵志丹  DonJDEPAOLO 周肃  董国臣   《岩石学报》2006,22(4):795-803

青藏高原拉萨地块是揭示印度与亚洲大陆碰撞的最重要的地区之一,其中广泛发育的碰撞-后碰撞岩浆作用记录了这一地区从特提斯洋俯冲消减到印度大陆陆内俯冲的全过程.本文基于对最新的Sr-Nd同位素资料的分析,从高原岩石圈的三种主要地球化学端元入手,分析了拉萨地块碰撞-后碰撞岩浆作用的类型及其在大陆俯冲与成矿作用方面的意义.青藏高原岩石圈可以分为三种主要的地球化学端元,一是青藏高原北部地球化学省（包括羌塘、可可西里和西昆仑）代表的青藏原始岩石圈地幔地球化学端元,42Ma以来在高原北部广泛分布的钾质岩浆岩的Nd-Sr同位素成分比较均一和稳定,同位素比值的范围较窄,^87Sr/^86Sr=0.707101～0.710536,εNd=-2～-9,tDM=0.7～1.3Ga;二是雅鲁藏布江蛇绿岩代表的新特提斯洋地幔端元,^87Sr/^86Sr=0.703000～0.706205,εNd=＋7.8～＋10,呈印度洋型MORB特征,属于印度洋型地幔域;三是喜马拉雅带地壳基底和花岗岩类显示的喜马拉雅地壳地球化学端元,εNd=-12～-25,^87Sr/^86Sr=0.733110～0.760000,具相对古老的Nd模式年龄,tDM=1.9～2.9Ga.拉萨地块碰撞-后碰撞岩浆作用可以划分出三种地球化学类型,即拉萨地块原地型、亲特提斯洋型和亲喜马拉雅型.这三种岩浆作用类型受控于上述三种地球化学端元在其源区的比例及相互作用.其中,拉萨地块原地型与青藏高原北部地球化学省特征一致,亲特提斯洋型代表了与新特提斯洋俯冲消减及其后的再循环有关的岩浆作用,亲喜马拉雅型岩浆岩的Sr-Nd同位素特征则可能指示了喜马拉雅大陆地壳端元的参与.超钾质火山岩是揭示印度大陆岩石圈向北俯冲的重要证据,印度大陆岩石圈俯冲作用可能同时控制了超钾质岩石和盐类矿床的产出,古老地壳物质作为源区参与了超钾质岩石和盐类矿床的成岩与成矿作用.拉萨地块中部地区的含矿斑岩属于亲特提斯洋型岩浆作用,因此具亲特提斯洋型特征的火山岩、浅成斑岩和深成侵入岩,是进一步寻找铜、钼、金矿床的重要目标.  相似文献