Factors influencing the oxidation,reduction, methylation and demethylation of mercury species in coastal waters     

Lindsay Whalin  Eun-Hee Kim  Robert Mason 《Marine Chemistry》2007

The objective of this study was to examine the redox reactions and other transformations of mercury (Hg) species in surface waters, and the factors determining the rates of these reactions. For the redox studies completed at the Chesapeake Biological Laboratory (CBL), two isotopes (¹⁹⁹Hg^II and ²⁰²Hg⁰) were added into different types of filtered water (fresh to seawater) to examine the oxidation and reduction reactions. Further studies of both the redox reactions and methylation/demethylation reactions of Hg were conducted with unfiltered water on board research vessels during cruises in May and July 2005 on the Chesapeake Bay and shelf. While CH₃¹⁹⁹Hg^II was added to allow the examination of demethylation, ²⁰¹Hg^II was used to examine both reduction and methylation, and ²⁰²Hg⁰ was used to examine oxidation. Overall, the results showed that both Hg oxidation and reduction were simultaneously occurring and were photochemically mediated in the waters investigated. In contrast to the previously assumed “unreactive” nature of Hg⁰, the studies found that the magnitude of the rate constant for Hg⁰ oxidation was greater than that for reduction, indicating its importance in estuarine and coastal waters. In addition, both experiments at CBL and on board ship showed that Hg^II reduction was similar in magnitude, suggesting that biotic processes were relatively unimportant. While no measurable methylation occurred during the incubation period during the on board studies, concentration of CH₃¹⁹⁹Hg^II decreased over the time during the experiments. It appeared that the demethylation processes were not dominantly photochemically driven, but could be microbially mediated. Further studies are needed in order to help better understand Hg redox and transformations in natural water systems.  相似文献   

Modeling erosion of sedimentary coasts in the western Russian Arctic     

I. O. Leont'yev   《Coastal Engineering》2003,47(4):413-429

Morphodynamic modeling is employed in the present work to predict the long-term evolution (over the next 100 years) of typical sedimentary coasts in the western Russian Arctic. The studied objects are the coasts of Varandey (the Barents Sea), Baydaratskaya Bay and Harasavey (the Kara Sea). The model developed takes into account both the short-term processes (storm events) and long-term factors (for example, changes in sea level, inter-annual variations in gross sediment flux, lack or excess of sediment supply). Predicted and observed morphological changes in coastal profiles are shown to agree well for time scales ranging from weeks to decades. It is revealed that under given environmental conditions, the morphological evolution is strongly influenced by storm surges and associated wind-driven circulation. The water level gradient created by a surge generates a seaward flow at the bed. This outflow is shown to be an important destructive mechanism contributing to the erosion and recession of Arctic coasts. The rate of change is found to depend on both the exposure of the coast (relative to the direction of dominant winds) and its height above the sea. The open coast of Varandey is expected to retreat as much as 300–500 m over 100 years, while recession of the less exposed coasts of Baydaratskaya Bay would not exceed about 100 m/century. If long-term sediment losses are insignificant, the rate of erosion decays with time and the morphodynamic system may tend toward equilibrium. It is concluded that the expected relative sea-level rise (up to 1 m over the nearest 100 years) is non-crucial to the future coastal evolution if an erosion activity is already high enough.  相似文献   

中国东南沿海潮灾与防潮对策研究   总被引：2，自引：0，他引：2  

吴培木 《台湾海峡》1994,13(3):308-315

中国东南沿海是中风暴潮灾害的最严得岸段，本文针对闽，粤，海南三省台风暴潮灾害概况，防潮现状及其存在问题，提出防潮减灾的对策和见解，以祈提醒人们居安思危，防患未然。  相似文献   

Modelling morphological processes in the vicinity of shore-parallel breakwaters     

Julio A. Zyserman  Hakeem K. Johnson 《Coastal Engineering》2002,45(3-4)

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闽浙沿岸上升流的数值模拟   总被引：1，自引：1，他引：1  

潘玉萍  沙文钰 《海洋预报》2004,21(2):86-95

本文将闽浙沿岸作为研究海区,采用坐标下三维斜压非线性的浅海陆架模式,综合考虑风、边界流(台湾暖流、黑潮、长江冲淡水)及地形等动力因子对上升流形成的影响,较好地模拟了闽浙沿岸上升流的分布。得出夏季闽浙沿岸近海岸区域有三个比较强的上升流中心,分别位于2520′N,12000′E、2640′N,12015′E、2720′N,12045′E附近,并且在对闽浙沿岸水文结构的模拟中,同样得出夏季沿岸的低温高盐区与计算出的三个较强的上升中心一致。冬季沿岸上升流的强度和范围都明显减弱,但在2520′N,12000′E和2600′N,12030′E及2830′~3000′N,12200′E附近仍有相对较强的上升流存在。  相似文献   

Sea Grant in Latin America?: Adapting the US Sea Grant model of linked applied research,extension, and education to a Latin American Context—Is there a fit?     

S. Matthew Wilburn  James Tobey  Jill Hepp  Stephen Olsen  Barry Costa-Pierce 《Marine Policy》2007

This paper explores the application of the US Sea Grant model of applied research, extension, and education to two case studies in Latin America: Coastal Ecuador and the Gulf of Fonseca. The analysis is based on a series of meetings and roundtables with in-country partners and leaders of the US Sea Grant program. We conclude that the Sea Grant model provides an institutional structure that Latin America lacks and the model's features would improve governance of marine and coastal resources through more effective linkages between coastal communities, universities, and policy/decision makers at local, national, and international levels.  相似文献   

An Assessment of Surface – Dynamics Observed Offshore Ancona with HF Radar     

Giorgio Budillon  Federica Grilli  Annalisa Ortona  Aniello Russo  Marco Tramontin 《Marine Ecology》2002,23(S1):21-37

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海岸带专题地图编绘相关问题     

顾燕  张鹰 《海洋技术学报》2004,23(2):103-106

海岸带是影响人类活动的重要地带，海岸带专题地图能够详细表示出海岸带的特性。随着海洋经济的发展，海岸图的需求日益增加。从地图的数学要素出发，提出目前海岸图绘制存在的问题，并从地图学、海洋学、遥感地学的角度，对地图投影的选择、坐标系转换、比例尺对海岸图编绘的影响及控制点的确定等问题进行了综合分析。  相似文献   

Intercomparison of coastal area morphodynamic models     

J. Nicholson  I. Broker  J. A. Roelvink  D. Price  J. M. Tanguy  L. Moreno 《Coastal Engineering》1997,31(1-4)

Five different coastal area morphodynamic models have been set up to run on the same offshore breakwater layout and an intercomparison carried out on the hydrodynamic and morphodynamic output produced by each scheme. In addition, the predicted morphodynamics was checked against available laboratory and field data.It is concluded that the models are capable of producing realistic estimates for the dominant morphodynamic features associated with offshore breakwaters. Coupling of the wave, current and sediment transport components of each scheme is shown to yield bathymetry which attains a state of equilibrium, unlike models which are based on the initial transport field only.  相似文献   

A phase-resolving cross shore sediment transport model for beach profile evolution     

K. A. Rakha  R. Deigaard  I. Brker 《Coastal Engineering》1997,31(1-4)

A phase-resolving wave transformation module is combined with an intra-wave sediment transport module to calculate the on-/offshore sediment transport rates. The wave module is based on the Boussinesq equations extended into the surf zone. The vertical variation of the mean undertow and the intra-wave sediment concentrations are calculated. The net sediment transport rates are calculated, and the equation for conservation of sediment is solved to predict the beach profile evolution. The results of the present paper showed that the undertow contribution to the sediment transport rates is not dominating in all parts of the surf zone, even for eroding beaches, suggesting that other contributions should not be neglected. The present model also showed that for the same offshore wave energy the time series of the oscillatory motion is important and that the effect of wave groups cannot be disregarded.  相似文献