The Production of Methanol by Flowering Plants and the Global Cycle of Methanol   总被引：10，自引：0，他引：10  

I. E. Galbally  W. Kirstine 《Journal of Atmospheric Chemistry》2002,43(3):195-229

Methanol has been recognised as an important constituent of the background atmosphere, but little is known about its overall cycle in the biosphere/atmosphere system. A model is proposed for the production and emission to the atmosphere of methanol by flowering plants based on plant structure and metabolic properties, particularly the demethylation of pectin in the primary cell walls. This model provides a framework to extend seven sets of measurements of methanol emission rates to the global terrestrial biosphere. A global rate of release of methanol from plants to the atmosphere of 100 Tg y^–1 is calculated. A separate model of the global cycle of methanol is constructed involving emissions from plant growth and decay, atmospheric and oceanic chemical production, biomass burning and industrial production. Removal processes occur through hydroxyl radical attack in the atmosphere, in clouds and oceans, and wet and dry deposition. The model successfully reproduces the methanol concentrations in the continental boundary-layer and the free atmosphere, including the inter-hemispheric gradient in the free atmosphere. The model demonstrates a new concept in global biogeochemistry, the coupling of plant cell growth with the global atmospheric concentration of methanol. The model indicates that the ocean provides a storage reservoir capable of holding at least 66 times more methanol than the atmosphere. The ocean surface layer reservoir essentially buffers the atmospheric concentration of methanol, providing a physically based smoothing mechanism with a time constant of the order of one year.  相似文献   

某盆地油气勘查成本预算和风险分析     

王敏杰  徐国盛  刘树根  邱夕海 《矿物岩石》2002,22(1):99-104

某高原盆地的油气资源量较为丰富，可找到大型油气田。根据含油气盆地地质构造特征、生油岩的厚度与热演化程度、储集层和区域性盖层的发育情况等因素，确定了两个含油气远景区，拟作为重点找油气靶区。提出了两个可供选择的油气勘探布署方案。在此基础上，选用适当的成本预算基本参数，进行油气勘查成本估算，并对两个方案进行了优选对比与具体的风险分析，提出方案决策意见。  相似文献   

Heat flow and thermal modeling of the Yinggehai Basin, South China Sea   总被引：9，自引：0，他引：9  

Lijuan He  Liangping Xiong  Jiyang Wang 《Tectonophysics》2002,351(3)

Geothermal gradients are estimated to vary from 31 to 43 °C/km in the Yinggehai Basin based on 99 temperature data sets compiled from oil well data. Thirty-seven thermal conductivity measurements on core samples were made and the effects of porosity and water saturation were corrected. Thermal conductivities of mudstone and sandstone range from 1.2 to 2.7 W/m K, with a mean of 2.0±0.5 W/m K after approximate correction. Heat flow at six sites in the Yinggehai Basin range from 69 to 86 mW/m², with a mean value of 79±7 mW/m². Thick sediments and high sedimentation rates resulted in a considerable radiogenic contribution, but also depressed the heat flow. Measurements indicate the radiogenic heat production in the sediment is 1.28 μW/m³, which contributes 20% to the surface heat flow. After subtracting radiogenic heat contribution of the sediment, and sedimentation correction, the average basal heat flow from basement is about 86 mW/m².Three stages of extension are recognized in the subsidence history, and a kinematic model is used to study the thermal evolution of the basin since the Cenozoic era. Model results show that the peak value of basal heat flow was getting higher and higher through the Cenozoic. The maximum basal heat flow increased from 65 mW/m² in the first stage to 75 mW/m² in the second stage, and then 90 mW/m² in the third stage. The present temperature field of the lithosphere of the Yinggehai Basin, which is still transient, is the result of the multistage extension, but was primarily associated with the Pliocene extension.  相似文献   

Low-temperature thermodynamic properties of disordered zeolites of the natrolite group     

I. E. Paukov  N. K. Moroz  Yu. A. Kovalevskaya  I. A. Belitsky 《Physics and Chemistry of Minerals》2002,29(4):300-306

 The heat capacity of paranatrolite and tetranatrolite with a disordered distribution of Al and Si atoms has been measured in the temperature range of 6–309 K using the adiabatic calorimetry technique. The composition of the samples is represented with the formula (Na_1.90K_0.22Ca_0.06)[Al_2.24Si_2.76O₁₀]·nH₂O, where n=3.10 for paranatrolite and n=2.31 for tetranatrolite. For both zeolites, thermodynamic functions (vibrational entropy, enthalpy, and free energy function) have been calculated. At T=298.15 K, the values of the heat capacity and entropy are 425.1 ± 0.8 and 419.1 ±0.8 J K⁻¹ mol⁻¹ for paranatrolite and 381.0 ± 0.7 and 383.2 ± 0.7 J K⁻¹ mol⁻¹ for tetranatrolite. Thermodynamic functions for tetranatrolite and paranatrolite with compositions corrected for the amount of extraframework cations and water molecules have also been calculated. The calculation for tetranatrolite with two water molecules and two extraframework cations per formula yields: C _p (298.15)=359.1 J K⁻¹ mol⁻¹, S(298.15) −S(0)=362.8 J K⁻¹ mol⁻¹. Comparing these values with the literature data for the (Al,Si)-ordered natrolite, we can conclude that the order in tetrahedral atoms does not affect the heat capacity. The analysis of derivatives dC/dT for natrolite, paranatrolite, and tetranatrolite has indicated that the water- cations subsystem within the highly hydrated zeolite may become unstable at temperatures above 200 K. Received: 30 July 2001 / Accepted: 15 November 2001  相似文献   

Dissolved silica budget in the North basin of Lake Lugano     

Annette Hofmann  Didier RoussyMontserrat Filella 《Chemical Geology》2002,182(1):35-55

We studied the dissolved silica cycle in the water column of the North basin of Lake Lugano, Switzerland/Italy. Lake Lugano is a meromictic, eutrophic lake, permanently stratified below 100-m depth. A one-box model was used to calculate a silica mass-balance over 1993, based on various lake measurements, such as sediment traps, sediment cores, water analysis and biota countings. We found that the North basin of Lake Lugano is at steady state as far as dissolved silica is concerned. The primary source of dissolved silica in the lake is river input (about 80%), with diffusion from bottom sediments and groundwater input also playing a role. Atmospheric input is negligible. The main export of dissolved silica occurs via biogenic uptake by diatoms and final burial of their frustules in the bottom sediment. Loss of dissolved silica through the lake outflow only represents 15% of the total output. Of the total amount of Si exported to the lake bottom through diatom sinking, less than 20% is re-supplied to the surface water by diffusion. Thus, the lake acts as an important permanent sink for silica. The long residence time of dissolved silica in the lake (7 years) is related to the strong physical stratification of the lake. Only about 10% of the standing stock are available to phytoplankton uptake.  相似文献   

Riparian alder fens — source or sink for nutrients and dissolved organic carbon? — 2. Major sources and sinks     

Lilian B. Busse  Günter Gunkel 《Limnologica》2002,32(1)

Natural riparian forest wetlands are known to be effective in their ability to remove nitrate by denitrification and sediments with attached phosphorus via sedimentation. On the other hand, litter input and decomposition is a process of crucial importance in cycling of nitrogen and phosphorus in a forest ecosystem.In this study we investigated the amount of nitrogen and phosphorus entering the alder fen ecosystem through leaf litter and its decomposition and the removal capacity of nitrogen and phosphorus by measuring denitrification and sedimentation in the alder fen.We found an average input of leaf litter during fall 1998 of 226 g m⁻² yr⁻¹ DW with nutrient concentration of 0.17% P and 1.6% N. This means a yearly input of 0.4 g m⁻² yr⁻¹ P and 3.6 g m⁻² yr⁻¹ N. The decomposition of leaf litter using litter bags with small and large mesh size resulted in bags with macroinvertebrates (large mesh size) and without macroinvertebrates (small mesh size). After 57 days the litter bags with macroinvertebrates had a decomposition rate of 79%.Denitrification was measured in May and June of 1997 using the acetylene inhibition technique on intact soil cores and slurry-experiments. The average annual denitrification rate was 0.2 g m⁻² yr⁻¹ N using data from the core experiments. The denitrification rate was higher after addition of nitrate, indicating that denitrification in the riparian alder fen is mainly controlled by nitrate supply.The sedimentation rate in the investigated alder fen ranged from 0.47 kg m⁻² yr⁻¹ DW to 4.46 kg m⁻² yr⁻¹ DW in 1998 depending on the study site and method we used. Sedimentation rates were lower in newly designed plate traps than in cylinder traps. The alder fen also showed lower rates than the adjacent creek Briese. Average phosphorus removal rate was 0.33 g m⁻² yr⁻¹ P.Input sources for the surface water of the alder fen are sediment mineralization and decomposition of leaf litter; output sources are sedimentation and denitrification. This study showed that a nutrient input of 24.58 kg ha⁻¹ yr⁻¹ N, 8.8 kg ha⁻¹ yr⁻¹ P and 419 kg ha⁻¹ yr⁻¹ DOC into the surface water of the alder fen is possible. Alder fens cannot improve water quality of an adjacent river system. This is only true for a nearly pristine alder fen with the hydrology of 10 months flooded conditions and 2 months non-flooding conditions a year.  相似文献   

Predicting average annual groundwater levels from climatic variables: an empirical model   总被引：8，自引：0，他引：8  

Zhuoheng Chen  Stephen E. Grasby  Kirk G. Osadetz 《Journal of Hydrology》2002,260(1-4):102-117

On the basis of one-dimensional theoretical water flow model, we demonstrate that the groundwater level variation follows a pattern similar to recharge fluctuation, with a time delay that depends on the characteristics of aquifer, recharge pattern as well as the distance between the recharge and observation locations. On the basis of a water budget model and the groundwater flow model, we propose an empirical model that links climatic variables to groundwater level. The empirical model is tested using a partial data set from historical records of water levels from more than 80 wells in a monitoring network for the carbonate rock aquifer, southern Manitoba, Canada. The testing results show that the predicted groundwater levels are very close to the observed ones in most cases. The overall average correlation coefficient between the predicted and observed water levels is 0.92. This proposed empirical statistical model could be used to predict variations in groundwater level in response to different climate scenarios in a climate change impact assessment.  相似文献   

A New Model for Heat Flow in Extensional Basins: Estimating Radiogenic Heat Production   总被引：1，自引：0，他引：1  

Waples  Douglas W. 《Natural Resources Research》2002,11(2):125-133

Radiogenic heat production (RHP) represents a significant fraction of surface heat flow, both on cratons and in sedimentary basins. RHP within continental crust—especially the upper crust—is high. RHP at any depth within the crust can be estimated as a function of crustal age. Mantle RHP, in contrast, is always low, contributing at most 1 to 2 mW/m² to total heat flow. Radiogenic heat from any noncrystalline basement that may be present also contributes to total heat flow. RHP from metamorphic rocks is similar to or slightly lower than that from their precursor sedimentary rocks. When extension of the lithosphere occurs—as for example during rifting—the radiogenic contribution of each layer of the lithosphere and noncrystalline basement diminishes in direct proportion to the degree of extension of that layer. Lithospheric RHP today is somewhat less than in the distant past, as a result of radioactive decay. In modeling, RHP can be varied through time by considering the half lives of uranium, thorium, and potassium, and the proportional contribution of each of those elements to total RHP from basement. RHP from sedimentary rocks ranges from low for most evaporites to high for some shales, especially those rich in organic matter. The contribution to total heat flow of radiogenic heat from sediments depends strongly on total sediment thickness, and thus differs through time as subsidence and basin filling occur. RHP can be high for thick clastic sections. RHP in sediments can be calculated using ordinary or spectral gamma-ray logs, or it can be estimated from the lithology.  相似文献   

Global heat budget, plate tectonics and climatic change   总被引：1，自引：0，他引：1  

Stuart A. Harris 《Geografiska Annaler: Series A, Physical Geography》2002,84(1):1-9

For the past 2000 Ma, the temperature of the Earth's surface has fluctuated around a mean similar to that of today, although individual locations have undergone long-term changes of ∼30°C at different times in different places. Water bodies absorb at least five times as much solar radiation as land surfaces, and ocean currents transport the excess heat absorbed in the tropics towards the poles. Changes in the distribution of land and sea due to plate tectonics explain the major temperature fluctuations (>25°C) around the globe in the last 350 Ma, and are first-order controls. Large-scale changes in ocean currents and thermohaline circulations are probably second-order controls (15–25°C). The Milankovitch orbital cycles are third-order controls producing variations in air temperature of the order of 10°C, while massive volcanic eruptions and changes in carbon dioxide are amongst the fourth-order controls producing minor perturbations (<5°C). The major climatic fluctuations are continuous but regional in effect and not global. Extraterrestrial factors may not cause major changes in climate when viewed from a geological perspective.  相似文献   

辽河盆地东部凹陷热历史及构造—热演化特征   总被引：9，自引：5，他引：9  

王永新  汪集旸  胡圣标 《地质科学》2003,38(2):214-220

根据辽河盆地东部凹陷大地热流测量和镜质体反射率数据,恢复了该区的热历史,结果表明:东部凹陷热流呈现古热流高现今热流低的变化特征,沙河街组三段沉积期到东营组沉积期(距今43～25Ma)盆地热流为66～82mWm²,现今热流值为47～70mWm²。构造沉降史分析显示,盆地经历了早期的裂谷阶段(距今43～25Ma)和后期的热沉降阶段,裂谷阶段包含了两个裂谷亚旋回。盆地现今较低的大地热流和较高的古热流及典型的裂谷型构造沉降样式为东部凹陷的构造—热演化提供了重要认识。  相似文献