Detection of hydrocarbons in clay soils: A laboratory experiment using spectroscopy in the mid- and thermal infrared     

《International Journal of Applied Earth Observation and Geoinformation》2013

Remote sensing has been used for direct and indirect detection of hydrocarbons. Most studies so far focused on indirect detection in vegetated areas. We investigated in this research the possibility of detecting hydrocarbons in bare soil through spectral analysis of laboratory samples in the short wave and thermal infrared regions. Soil/oil mixtures were spectrally measured in the laboratory. Analysis of spectra showed development of hydrocarbon absorption features as soils became progressively more contaminated. The future application of these results airborne seems to be a challenge as present and future sensors only cover the diagnostic regions to a limited extent.  相似文献   

塔河油田十二区奥陶系油气分布规律及控制因素     

阳生国  王顺玉  明爽  邵晓州  吴小华  丁勇  陈红 《海相油气地质》2012,17(1):17-22

塔河油田十二区奥陶系油藏为碳酸盐岩岩溶缝洞型油藏,油气水分布规律复杂。对原油的物理性质、平面及纵向上的分布特征、油水界面等的分析表明,区内主要为高黏度、含蜡、高含硫的超重质原油。平面上密度分布呈西部和东部低、中部高的特点;纵向上原油密度与深度关系不大。高产油区多沿主断裂带分布。油水界面不统一,但从东向西随中奥陶统顶面的降低而降低。认为该区油气分布不受现今构造位置高低的控制,而是受区域构造背景、断裂带的分布、储集层的发育程度、成藏演化过程以及不整合面等因素综合控制。  相似文献   

下扬子地区中-新生代的挤压变形与伸展改造及其油气勘探意义   总被引：7，自引：3，他引：4  

李海滨  贾东  武龙  张勇 《岩石学报》2011,27(3):770-778

以地表变形特征、地层厚度变化和地震剖面为约束,构建了贯穿下扬子地区主要构造单元的三条地质大剖面。剖面展示了研究区早期褶皱逆冲、晚期伸展断陷的构造格局,并揭示了变形的空间差异。通过对褶皱卷入的层位、断层与地层的切割关系及不整合类型和发育特征的梳理,得出研究区北侧的褶皱逆冲主要形成于中-晚三叠世,南侧的褶皱逆冲主要形成 于中-晚侏罗世。两侧的挤压构造在晚白垩世开始都经历了强烈的拉张作用,北侧的断陷一直持续到古近纪,新近纪以拗陷为主,而南侧古近纪断陷规模较小,新近纪拗陷不发育。苏州-无锡地区的下古生界受后期改造作用较弱,是油气勘探的有利地区。  相似文献   

沉积盆地火成构造研究综述     

刘晓峰  齐荣 《地球科学进展》2011,26(2):166-170

岩浆活动在沉积盆地中是非常广泛的.随着油气勘探领域的扩展,对沉积盆地火成岩及相关构造的研究愈加重要.沉积盆地火成构造是指在沉积盆地中由岩浆侵入或喷发作用形成的岩浆和围岩及上覆层变形构造的总和.当前,利用三维地震数据研究岩席的几何学与侵位机制取得了重要进展,开启了沉积盆地火成构造研究的新时代.三维地震分析是沉积盆地火成构...  相似文献   

碳酸盐岩烃源岩判识与实践——以四川盆地为例   总被引：1，自引：0，他引：1  

黄籍中  吕宗刚 《海相油气地质》2011,16(3):8-14

碳酸盐岩可以成为烃源岩,并为油气藏提供丰富的烃源,但不是所有碳酸盐岩都可以视为烃源岩。碳酸盐岩在成藏进程中,往往作为输导层或储集层,并常有外源有机质的干扰。碳酸盐岩烃源岩应该是有机质原生赋存(与矿物结合成为沉积的一部分),具有一定丰度值,在适宜的热成熟阶段,同样可以形成液态烃和气态烃。碳酸盐岩烃源岩发育于低能环境的沉积相——开阔海台地相、局限海台地相、生物泥丘相、斜坡相,等等。泥质泥晶灰岩,生物泥—粒泥岩—泥粒岩微相,应该是碳酸盐岩烃源岩的主要岩类。碳酸盐岩烃源岩与油系泥质烃源岩比较,具有油窗凸显且高峰期前移、气态烃峰期不明显且有后延、液态烃产率高的特点。据对碳酸盐岩烃源潜量的评估,它在四川盆地烃源中占20%～25%,为油气成藏作出了重要贡献。  相似文献   

Kinetic simulation of hydrocarbon generation from lacustrine type I kerogen from the Songliao Basin: Model comparison and geological application     

Wang Min  Lu Shuang-fangXue Hai-tao 《Marine and Petroleum Geology》2011,28(9):1714-1726

Eight lacustrine Type I kerogen samples from the Songliao Basin were pyrolyzed using the Rock-Eval equipment, and parallel first-order reaction models including the model with a single frequency factor and a discrete distribution of activation energies (SFF model) and the model with multiple frequency factors and a discrete distribution of activation energies (MFF model) were adopted to analyze kinetic characteristics of hydrocarbon generation of the Type I kerogen samples. The results show that the MFF and SFF models can satisfactory simulate hydrocarbon generation under laboratory conditions and the Type I kerogen shows relatively concentrated activation energy distributions (activation energies of MFF model range from 190 kJ/mol to 250 kJ/mol, activation energies of SFF model range from 220 kJ/mol to 240 kJ/mol), which indicates a homogeneous chemical bond structure of the Type I kerogen. The hydrocarbon generated curves from Type I kerogen were calculated by using the two models with a linear heating rate (3.3 K/Ma). It indicates that the hydrocarbon generation potentials (reaction fractions) are underestimated by using the SFF model during the kerogen thermal degradation for the components with chemical bond of lower and higher activation energies, while this problem can be avoided by using the MFF model. The calculated temperatures for 50% transformation ratio (TR) of all samples differ by as much as 20 °C. For the SFF model, the hydrocarbon generation curve obtained by using the weighted averaged kinetic parameters and the SFF model almost includes every curve calculated by using its own kinetic parameters. While the curve obtained by using the weighted averaged kinetic parameters and the MFF model cannot include every curve for all samples, it lies at the position of the averaged curve of all samples. The application of the MFF model in Songliao Basin shows that if TR 10% is taken as the onset of hydrocarbon generation, the threshold depth of hydrocarbon generation is about 1700 m, which is consistent with other geochemical parameters, such as S₁/TOC, S₁/(S₁ + S₂) and HC/TOC.  相似文献   

Oil-oil and oil-source rock correlations in the Alpine Foreland Basin of Austria: Insights from biomarker and stable carbon isotope studies     

Reinhard Gratzer  Achim BechtelReinhard F. Sachsenhofer  Hans-Gert LinzerDoris Reischenbacher  Hans-Martin Schulz 《Marine and Petroleum Geology》2011,28(6):1171-1186

The Alpine Foreland Basin is a minor oil and moderate gas province in central Europe. In the Austrian part of the Alpine Foreland Basin, oil and minor thermal gas are thought to be predominantly sourced from Lower Oligocene horizons (Schöneck and Eggerding formations). The source rocks are immature where the oil fields are located and enter the oil window at ca. 4 km depth beneath the Alpine nappes indicating long-distance lateral migration. Most important reservoirs are Upper Cretaceous and Eocene basal sandstones.Stable carbon isotope and biomarker ratios of oils from different reservoirs indicate compositional trends in W-E direction which reflect differences in source, depositional environment (facies), and maturity of potential source rocks. Thermal maturity parameters from oils of different fields are only in the western part consistent with northward displacement of immature oils by subsequently generated oils. In the eastern part of the basin different migration pathways must be assumed. The trend in S/(S + R) isomerisation of ααα-C₂₉ steranes versus the αββ (20R)/ααα (20R) C₂₉ steranes ratio from oil samples can be explained by differences in thermal maturation without involving long-distance migration. The results argue for hydrocarbon migration through highly permeable carrier beds or open faults rather than relatively short migration distances from the source. The lateral distance of oil fields to the position of mature source rocks beneath the Alpine nappes in the south suggests minimum migration distances between less than 20 km and more than 50 km.Biomarker compositions of the oils suggest Oligocene shaly to marly successions (i.e. Schoeneck, Dynow, and Eggerding formations) as potential source rocks, taking into account their immature character. Best matches are obtained between the oils and units a/b (marly shale) and c (black shale) of the “normal” Schöneck Formation, as well as with the so-called “Oberhofen Facies”. Results from open system pyrolysis-gas chromatography of potential source rocks indicate slightly higher sulphur content of the resulting pyrolysate from unit b. The enhanced dibenzothiophene/phenanthrene ratios of oils from the western part of the basin would be consistent with a higher contribution of unit b to hydrocarbon expulsion in this area. Differences in the relative contribution of sedimentary units to oil generation are inherited from thickness variations of respective units in the overthrusted sediments. The observed trend towards lighter δ¹³C values of hydrocarbon fractions from oil fields in a W-E direction are consistent with lower δ¹³C values of organic matter in unit c.  相似文献   

青藏高原东北缘贵德坳陷源岩时代及勘探潜力     

马新民  张跃中  张弘强  周苏平  李永奎  张红欣 《地质学报》2013,87(1):133-138

青藏高原东北缘贵德坳陷发育一套烃源岩,长期以来,其时代归属不统一,其生烃能力认识不清,制约了该坳陷油气资源勘探的进程.本文通过野外踏勘、露头剖面实测和样品分析及连续电磁剖面(CEMP)测量结果得出以下认识:①根据沉积特征及孢粉组合,结合区域地质资料,确定了该套地层形成时代为早白垩世,沉积环境为浅湖—半深湖;②借助野外实测剖面及连续电磁剖面(CEMP)资料,确定了该套烃源岩的发育规模;③通过对剖面样品的有机质丰度、热演化程度等实验分析,对该套烃源岩的油气勘探潜力进行了综合评价,认为该套烃源岩分布范围广,厚度大,有机质丰度高,热演化程度适中,可以作为贵德坳陷的有效烃源岩,提升了贵德坳陷油气勘探潜力;④利用野外调查结果及连续电磁剖面(CEMP)资料对贵德坳陷生储盖组合进行综合分析,并指出了有利的勘探方向.  相似文献   

天然气水合物与传统油气资源共生成藏模式初探     

雷新华  林功成  苗永胜  张新  刘豪杰 《海相油气地质》2013,(1):47-52

天然气水合物与常规油气资源的成藏在时空上存在密切联系,在一定条件下可以共生成藏。存在泄漏共生、封盖共生和遮盖侧储三种基本的共生成藏模式。泄漏共生模式是先期形成了传统油气藏,而后由于发生油气泄漏并在其上方形成天然气水合物,其特征是在水合物的下方生、储、盖齐备;封盖共生模式则是先在上部形成天然气水合物,同时作为下部传统油气藏的盖层,其特征是水合物之下的传统油气藏具备生、储成藏条件,但缺乏盖层成藏要素;遮盖侧储模式是由于水合物矿藏的遮盖作用,迫使在下部形成的烃类物质向上运移时改道,在旁侧具成藏条件的邻区成藏。实际的地质成藏可能会出现这些基本模式的组合形式。  相似文献   

深层气理论分析和深层气潜势研究   总被引：9，自引：3，他引：9  

史斗  刘文汇  郑军卫 《地球科学进展》2003,18(2):236-244

近年来的一些文献表述深层气时在"深层"和"深部"名词概念上容易造成不必要的费解。就沉积层而言,宜将生油主带（生油窗）作为"深"的界限,从此界限开始到基底以上地层范围的天然气统统称为"深层气";就整个地球而言,宜将沉积层结晶基底和该基底以下的天然气统统称为"深部气"。当然,还应更多地注意来源于深部"深生浅储"的"深层气"。深层气的形成与地壳烃类形成的垂直分带性有关。在一定的历史时期和一定的沉积盆地油气形成分带性理论对勘探实践发挥了一定的指导作用,随着油气地质科研和勘探实践的发展,人们逐渐发现了油气形成分带性理论中油相消失和气相生成带开始门限指标的局限性。不同盆地有不同深度的生油主带,因而也有不同深度范围生气主带（干气带）。腐泥型有机质的演化需要更高的活化能,而需更高的温度和更大的深度,其生气主带深于腐殖型有机质源岩层的位置。生气主带有机质演化受多种因素控制,其中温度、深度和时间是重要因素,引起深层温度升高的条件有地球动力和深部热流等。古生界以前的重大生物地质事件为深层气形成准备了有机质及其演化条件,从物质基础上讲,深层气有巨大的资源潜势。油气形成的地球动力学观点及其他新观点为研究深层气提供了新的思路,岩石圈的烃类资源远未枯竭,被发现和开采的资源仅是其中的一部分,更多的需在深部去发掘。  相似文献