元素地球化学不活动组份判别--以库布苏金矿中矿带研究为例     

孙华山  高怀忠 《矿产与地质》2000,14(5)

利用 Gresens( 1967)质量平衡方程及 Brimhall等 ( 1987)提出的元素不活动组份ΔX- fv 图解 ,对复杂热液成矿体系的元素不活动组份进行了深入探讨。指出了复杂体系内部各个子体系间元素不活动组份及体积变化上的差异。并结合库布苏金矿中矿带元素不活动组份进行了研究。同时对一些矿床地质现象的形成及成矿物质来源从元素地球化学角度进行了解释和判断。  相似文献   

Hydrothermal alteration processes in the giant Dahutang tungsten deposit,South China: Implications from litho-geochemistry and mass balance calculation     

Hai-Bo Zhao  Yong Zhang  Lei Liu 《China Geology》2021,4(2):230-244

The giant Dahutang tungsten (W) deposit has a total reserve of more than 1.31 Mt WO₃. Veinlet-disseminated scheelite and vein type wolframite mineralization are developed in this deposit, which are related to Late Mesozoic biotite granite. Four major types of alterations, which include albitization, potassic-alteration, and greisenization, and overprinted silicification developed in contact zone. The mass balance calculate of the four alteration types were used to further understanding of the mineralization process. The fresh porphyritic biotite granite has high Nb, Ta, and W, but low Ca and Sr while the Jiuling granodiorite has high Ca and Sr, but low Nb, Ta, and W concentrations. The altered porphyritic biotite granite indicated that the Nb, Ta, and W were leached out from the fresh porphyritic biotite granite, especially by sodic alteration. The low Ca and Sr contents of the altered Neoproterozoic Jiuling granodiorite indicate that Ca and Sr had been leached out from the fresh granodiorite by the fluid from Mesozoic porphyritic biotite granites. The metal W of the Dahutang deposit was mainly derived from the fluid exsolution from the melt and alteration of W-bearing granites. This study of alteration presents a new hydrothermal circulation model to understand tungsten mineralization in the Dahutang deposit.  相似文献   

热液金刚石压腔(HDAC)高温高压实验平台简介          下载免费PDF全文

李胜虎  熊玉新  单伟  舒磊  迟乃杰 《山东国土资源》2021,37(1):50-52

热液金刚石压腔(HDAC)高温高压实验平台是在金刚石压腔的基础上发展起来的一种高温高压原位实验模拟设备.近年来,HDAC技术已经在地质科研领域取得了大量成果,多篇重要研究成果被《Science》《Nature》等知名期刊刊发.本文介绍了HDAC高温高压实验平台结构与组成、实验优势和应用前景.  相似文献   

云南香格里拉市热林铅锌银矿特征及找矿标志     

赵贤  孙涛  胡成军 《云南地质》2021,(1):42-46

云南香格里拉市热林铅锌银矿,矿体呈似层状赋存于三叠系上统曲嘎寺组三段(T3q3)之大理岩与板岩的层间构造破碎带中,矿体明显受断层构造及特定的岩性控制.该矿床属断层破碎带控制的热液型铅锌银矿床,断层破碎带和地球化学异常是直接的找矿标志,沿断层带出现的硅化、碳酸盐化、黄铁矿化和角岩化是间接的找矿标志.  相似文献   

纳米及微米级六角片状氢氧化镁的制备   总被引：2，自引：2，他引：0  

宋雪雪  李丽娟  姬连敏  刘志启  聂锋  曾忠民  宋富根  时东  彭小五  张利诚  李慧芳 《盐湖研究》2018,26(2):66-74, 80

以氯化钠为底料,水氯镁石和氢氧化钠为原料,不添加任何添加剂,采用双柱沉淀—水热法制备粒度分布均匀、分散性良好的氢氧化镁。研究了进料速度、2N_(Mg)/N_(Na)、物料浓度、水热温度、水热时间等因素对氢氧化镁粒径、形貌、过滤性能的影响。通过粒度分析仪、X射线衍射仪、低真空扫描电子显微镜对产品的粒度分布、结构和形貌进行了表征。结果表明,本研究得到的样品分散性好,粒度分布均匀,形貌为规则的六角片状,粒径为400~600 nm的纳米级氢氧化镁或者1~2μm的微米级氢氧化镁。  相似文献   

Geochemical behavior of rare earth elements in hydrothermally altered rocks of the Kuroko mining area,Japan     

N. Shikazono  Y. Ogawa  M. Utada  D. Ishiyama  T. Mizuta  N. Ishikawa  Y. Kubota 《Journal of Geochemical Exploration》2008

In this study we analyzed the chemical composition of hydrothermally altered dacite and basalt from the Kuroko mining area, northeastern Honshu, Japan, by REE (rare earth element). Features of rare earth element analyses include: (1) altered footwall dacite exhibits a negative Eu anomaly compared with fresh dacite, suggesting preferential removal of Eu²⁺ from the altered dacite via hydrothermal solutions, (2) altered hangingwall dacite and basalt and dacite and basalt adjacent to ore deposits exhibit positive Eu anomalies compared with fresh dacite and basalt, suggesting addition of Eu²⁺ from hydrothermal solutions, (3) LREE ratio (∑LREE/∑REE) from altered dacite of chlorite–sericite zone and K-feldspar zone show a negative relationship with δ¹⁸O, and La/Sm ratios show a positive correlation with the K₂O index. These trends indicate the addition of light rare earth elements such as La to the altered dacite from hydrothermal solution and/or leaching of heavy rare earth elements such as Sm and Yb, (4) Principal component analysis (PCA) indicates that light rare earth elements enrichment is related to the formation of sericite zone near the Kuroko deposits but not to the formations of chlorite and K-feldspar zones, and (5) The correlations among REE features (LREE ratio, MREE ratio, HREE ratio, Eu/Eu?), δ¹⁸O and K₂O index are not found for montmorillonite zone, mixed layer clay mineral zone and mordenite zone. Therefore, it is inferred that sericite, chlorite and K-feldspar alterations are related to the Kuroko and vein-type mineralization, but montmorillonite and mordenite alterations are not related to the mineralizations, and probably they formed at the post-mineralization stage.  相似文献   

Platinum-group minerals from the Jinbaoshan Pd–Pt deposit,SW China: evidence for magmatic origin and hydrothermal alteration     

Christina Yan Wang  Hazel M. Prichard  Mei-Fu Zhou  Peter C. Fisher 《Mineralium Deposita》2008,43(7):791-803

The Jinbaoshan Pt–Pd deposit in Yunnan, SW China, is hosted in a wehrlite body, which is a member of the Permian (∼260 Ma) Emeishan Large Igneous Province (ELIP). The deposit is reported to contain one million tonnes of Pt–Pd ore grading 0.21% Ni and 0.16% Cu with 3.0 g/t (Pd + Pt). Platinum-group minerals (PGM) mostly are ∼10 μm in diameter, and are commonly Te-, Sn- and As-bearing, including moncheite (PtTe₂), atokite (Pd₃Sn), kotulskite (PdTe), sperrylite (PtAs₂), irarsite (IrAsS), cooperite (PtS), sudburyite (PdSb), and Pt–Fe alloy. Primary rock-forming minerals are olivine and clinopyroxene, with clinopyroxene forming anhedral poikilitic crystals surrounding olivine. Primary chromite occurs either as euhedral grains enclosed within olivine or as an interstitial phase to the olivine. However, the intrusion has undergone extensive hydrothermal alteration. Most olivine grains have been altered to serpentine, and interstitial clinopyroxene is often altered to actinolite/tremolite and locally biotite. Interstitial chromite grains are either partially or totally replaced by secondary magnetite. Base-metal sulfides (BMS), such as pentlandite and chalcopyrite, are usually interstitial to the altered olivine. PGM are located with the BMS and are therefore also interstitial to the serpentinized olivine grains, occurring within altered interstitial clinopyroxene and chromite, or along the edges of these minerals, which predominantly altered to actinolite/tremolite, serpentine and magnetite. Hydrothermal fluids were responsible for the release of the platinum-group elements (PGE) from the BMS to precipitate the PGM at low temperature during pervasive alteration. A sequence of alteration of the PGM has been recognized. Initially moncheite and atokite have been corroded and recrystallized during the formation of actinolite/tremolite, and then, cooperite and moncheite were altered to Pt–Fe alloy where they are in contact with serpentine. Sudburyite occurs in veins indicating late Pd mobility. However, textural evidence shows that the PGM are still in close proximity to the BMS. They occur in PGE-rich layers located at specific igneous horizons in the intrusion, suggesting that PGE were originally magmatic concentrations that, within a PGE-rich horizon, crystallized with BMS late in the olivine/clinopyroxene crystallization sequence and have not been significantly transported during serpentinization and alteration.  相似文献   

湖南省热液硅化成矿作用与找矿   总被引：2，自引：0，他引：2  

童潜明 《湖南地质》1991,10(2):129-134

根据成矿作用与热液硅化极为密切的锡矿山锑矿床、康家湾铅锌金矿床、磺厂雄磺矿床和320铀矿床的地质特征,对热液硅化、角砾化、矿质沉淀和矿床剖面结构的形成机理进行了讨论,认为这类矿床属于浅成热液类型矿床或热泉型矿床,进而认为对司空见惯的硅化带的找矿意义要重新认识,由此提出了寻找这种类型矿床的地质、地球化学、地球物理的找矿标志。  相似文献   

热液烃的生成与深部油气藏   总被引：25，自引：1，他引：25  

张景廉  王先彬  曹正林 《地球科学进展》2000,15(5):545-552

热液烃不仅分布于洋底,在大陆也有广泛分布,实验表明:热液对碳酸盐岩和沉积有机质的作用均有油气生成;洋底火山岩流体包裹体、原油、有机质Pb、Sr、Nd同位素均表明地幔流体在油气生成中的作用。认识热液烃的存在对开拓深部油气藏的勘探有重要意义。  相似文献   

Dissolution-precipitation reactions controlling fast formation of dolomite under hydrothermal conditions     

《Applied Geochemistry》2016

In laboratory experiments, the precipitation of dolomite at ambient temperature is virtually impossible due to strong solvation shells of magnesium ions in aqueous media and probably also due to the existence of a more intrinsic crystallization barrier that prevents the formation of long-range ordered crystallographic structures at ambient surface conditions. Conversely, dolomite can easily form at high temperature (>100 °C), but its precipitation and growth requires several days or weeks depending on experimental conditions. In the present study, experiments were performed to assess how a single heat-ageing step promotes the formation of dolomite under high-carbonate alkaline conditions via dissolution-precipitation reactions. This reaction pathway is relevant for the so-called hydrothermal dolomite frequently observed in carbonate platforms, but still ill-defined and understood. Our precipitation route is summarized by two main sequential reactions: (1) precipitation of Mg-calcite at low temperature (∼20 °C) by aqueous carbonation of synthetic portlandite (Ca(OH)₂) in a highly alkaline medium (1 M of NaOH and 1 M of MgCl₂), leading to precipitation of oriented nanoparticles of low- and high-Mg calcite (∼79 wt%) coexisting with aragonite (∼18 wt%) and brucite (∼3 wt%) after 24 h; (2) fast dolomitization process starting from 1 h of reaction by a single heat-ageing step from ∼20 to 200, 250 and 300 °C. Here, the Mg-calcite acts as a precursor that lowers the overall kinetics barrier for dolomite formation. Moreover, it is an important component in some bio-minerals (e.g. corals and seashells). Quantitative Rietveld refinements of XRD patterns, FESEM observations and FTIR measurements on the sequentially collected samples suggest fast dolomite precipitation coupled with dissolution of transient mineral phases such as low-Mg calcite (Mg < 4 mol%), high-Mg calcite (Mg > 4 mol%), proto-dolomite (or disordered dolomite; Mg > 40 mol%) and Ca-magnesite. In this case, the dolomite formation rate and the time-dependent mineral composition strongly depend on reaction temperature. For example, high-purity dolomitic material (87 wt% of dolomite mixed with 13 wt% of magnesite) was obtained at 300 °C after 48 h of reaction. Conversely, a lower proportion of dolomite (37 wt%), mixed with proto-dolomite (43 wt%), Ca-magnesite (16 wt%) and high-Mg calcite (4 wt%), was obtained at 200 °C after 72 h. The present experiments provide an additional mechanism for the massive dolomite formation in sedimentary environments (ex. deep sea organic-rich carbonate-sediments) if such sediments are subjected to significant temperature variations, for example by hot fluid circulations related to volcanic activity. In such systems, organic degradation increases the carbonate alkalinity (HCO₃⁻) necessary to induce the dolomitization process at low and high temperature.  相似文献