南极威德尔海周边雪冰和大气气溶胶中的MSA,nssSO_4~(2-)浓度及其比率研究          下载免费PDF全文

韩建康 《极地研究》1998,10(4):4-14

分析了威德尔海周边雪冰和大气中ＭＳＡ和ｎｓｓＳＯ２－４浓度资料。结果表明,威德尔海是造成这一地区大气中高含量生物硫化物的“源”,其周边岛屿及冰架表层雪冰记载和反映了大气中生物硫化物的空间分布和季节变化特点。源区产出硫化物的强度存在显著差异：靠近南极半岛一侧高于靠近Ｆｉｌｃｈｎｅｒ－Ｒｏｎｎｅ冰架一侧。尽管诸多因素对输运和沉降过程发生影响,表层积雪ＭＳＡ和ｎｓＳＯ２－４浓度仍呈现出很有规律性的空间分布：随沉降地点离海距离和海拔高度的增加,浓度值递减;但在一定海拔之下,“高程效应”不显著。冰芯中ＭＳＡ浓度垂向分布显示出季节分配“滞后”现象,在表层表现为受天气条件制约的输运过程造成的相位差,在深层则归因于有待验证的“迁移”机制作用的结果。大气和雪冰样品对比研究结果表明,在类似威德尔海这样的高纬地区,大气中的ＳＯ２－４和ＭＳＡ“信号”在雪冰样品中会遭到不同程度的减弱。但就空间变化趋势和季节分布而言,表层雪冰仍是大气中组分（在本文是ＳＯ２－４和ＭＳＡ）的良好载体。十分接近的大气和雪冰ＭＳＡ对ｎｓｓＳＯ２－４（或ＳＯ２－４）比率证实,这两种大气组分在由大气洗净和沉降到冰雪过程中只发生微弱的分离作用。这也就是大气和雪冰中  相似文献   

磺化层柱状有机膦酸锆的合成及催化反应研究     

谢同  彭广志  杨义芳  王桂芬 《盐湖研究》1998,(Z1)

在氢氟酸溶液中,混合亚磷酸、4,4’-联苯二膦酸和锆离子反应生成4,4’-联苯二膦酸锆／亚磷酸锆（简称MCZP）,改变有机酸和亚磷酸的比例,可以合成具有相同组分但结构不同的一系列化合物。通过磺化反应,在苯环上接上磺酸基团后,它具有类似强酸性阳离子交换树脂特性．该文首次对这类化合物催化酯化、醚化等典型的酸催化有机反应进行了研究,结果表明其催化转化率高、催化剂可重复使用和再生,是一种很有发展前途的新型固体酸催化剂．  相似文献   

LiMn_2O_4的溶胶─凝胶─酯化法合成及性能Ⅱ　立方尖晶石的形成及其形貌     

尉继英  孙长敏  高海春 《盐湖研究》1998,(1)

以溶胶-凝胶-酯化法在220℃即可得到纯相的LixMn2O4（0.762＜x＜1.139）尖晶石粉体材料。它在880℃时发生立方相向四方相的转变：900℃－1000℃间,四方相渐变为正交相LiMnO2,过程中有Li2MnO3生成。应用SEM、TEM观测了材料的粘度及形貌,其粒度10－40nm,粒子间极易团聚成为1-206μm的团块。以BET法测其比表面为3.6m2／g。  相似文献   

Renewable, controlled and environmentally safe phosphorus release in soils from mixtures of NH4 +-phillipsite tuff and phosphate rocks     

I. M. Dwairi 《Environmental Geology》1998,34(4):293-296

 The renewable and controlled-release fertilization system investigated here uses NH₄ ⁺-exchanged phillipsite tuff, from Jordan, to help in the dissolution of phosphate rock. Accordingly, controlled and renewable soluble nitrogen, phosphate and Ca are released as nutrients for plants. NH₄ ⁺ phillipsite can sequester Ca ions released by the dissolution of phosphate rock, therefore, leading to further phosphate rock dissolution. In this study the results show that the amount of phosphate released is more than that released by phosphate rock alone. This method offers an alternative to the use of highly soluble fertilizers and may avoid environmental problems associated with their extensive use in agriculture. Received: 22 May 1997 · Accepted: 12 August 1997  相似文献   

Oxygen isotope fractionation in mantle minerals     

Yongfei Zheng  Chunsheng Wei  Gentao Zhou  Baolong Xu 《中国科学D辑(英文版)》1998,41(1):95-103

The increment method is adopted to calculate oxygen isotope fractionation factors for mantle minerals, particularly for the polymorphic phases of MgSiO₃ and Mg₂SiO₄. The results predict the following sequence of¹⁸O-enrichment:pyroxene (Mg, Fe, Ca)₂Si₂O₆>olivine (Mg, Fe)₂SiO₄ > spinel (Mg, Fe)₂SiO₄> ilmenite (Mg, Fe, Ca) SiO₃>perovskite (Mg, Fe, Ca) SiO₃. The calculated fractionations for the calcite-perovskite (CaTiO₃) System are in excellent agreement with the experimental calibrations. If there would be complete isotopic equilibration in the mantle, the spinel-structured silicates in the transition zone are predicted to be enriched in¹⁸O relative to the perovskite-structured silicates in the lower mantle but depleted in¹⁸O relative to olivines and pyroxenes in the upper mantle. The oxygen isotope layering of the mantle might result from differences in the chemical composition and crystal structure of mineral phases at different mantle depths. Assuming isotopic equilibrium on a whole earth scale, the chemical structure of the Earth’s interior can be described by the following sequence of¹⁸O-enrichment:upper crust>lower crust>upper mantle>transition zone>lower mantle>core. Project supported by the National Natural Science Foundation of China and the Chinese Academy of Sciences.  相似文献   

利用空间测地技术结果估计地球平均下地幔粘性(英)     

杨志根  真锅盛二  黄山一  河野宣之 《天文学报》1998,(3)

基于IEC－4G冰期后地壳反弹模型,和地球上Laurentia,Fennoscandia,Antarctica,andGreenland四大冰盖最近21000年以来的冰融参数,计算了对地球最大主转动惯量的影响△I33,并进而由现代空间测地技术观测资料分析得到的地球自转非潮汐加速项为约束,估计了地球平均下地幔（670km以下）粘性vLM为（0．9～2．5）·1022Pas,这个结果表明了vLM应具有1022Pas量级．  相似文献   

准四年周期的北半球夏季遥相关与东亚夏季风环流的相互关系   总被引：3，自引：3，他引：0  

谭言科  何金海 《南京气象学院学报》1998,21(1):70-79

利用ＮＭＣ的２００ｈＰａ和８５０ｈＰａ风场资料研究了北半球夏季遥相关和东亚夏季风异常环流在准４年时间尺度上的相互关系。研究发现当北半球夏季出现积雪强迫型遥相关时,东亚－西太平洋地区既存在异常纬向环流,也存在异常经向环流;而当出现东亚太平洋型遥相关时,东亚－西太平洋地区以异常纬向环流为主。分析还发现源于北太平洋的异常涡旋在向南传播的过程中,先取西南路径,在到达菲律宾东部以后折向东南。  相似文献   

Assessment of δ13C and C/N ratios in bulk organic matter as palaeosalinity indicators in Holocene and Lateglacial isolation basin sediments,northwest Scotland     

Elizabeth A. V. Mackie  Jeremy M. Lloyd  Melanie J. Leng  Michael J. Bentley  Carol Arrowsmith 《第四纪科学杂志》2007,22(6):579-591

Carbon isotopes (δ¹³C) and C/N ratios from bulk organic matter have recently been used as alternative proxies for relative sea‐level (RSL) reconstruction where there are problems associated with conventional biological indictors. A previous study on a single isolation basin (Upper Loch nan Eala) in northwest Scotland has shown a clear relationship between δ¹³C, C/N ratios and palaeosalinity from Younger Dryas and Holocene aged sediments. In this paper we present results of δ¹³C and C/N ratio analyses from other isolation basins in northwest Scotland over the Holocene and the Lateglacial period in order to validate this technique. The results from the Holocene sequences support the earlier findings that this technique can be used to identify RSL change from isolation basins over the Holocene in this region. The relationship between δ¹³C, C/N ratios and RSL change is not apparent in sediments of Lateglacial age. Other environmental variables such as atmospheric CO₂ concentration, poor vegetation development and temperature influence δ¹³C values during this period. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

三维空间中简单线与体之间的拓扑关系研究     

李姣姣  李光强  徐锐 《测绘科学》2009,34(6)

三维空间对象的拓扑关系对于研究三维空间对象的操作及其算法至关重要。本文在详细研究拓扑关系的9-交和4-交模型的基础上,指出了它们在表达简单线与体拓扑关系上的局限性,9-交模型的线性相关性以及4-交模型的不完备性。进而提出简单线与体拓扑关系表达的扩展4-交模型,运用扩展4-交模型详细分析了简单线与体的拓扑关系,并给出图示。接着对所提扩展4-交模型线性无关性及完备性进行了论证。最后对所提出的扩展4-交模型进行了总结性说明。  相似文献   

用硫酸镁和造纸草浆黑液制备吸附剂及其对活性黄ST-4RFN吸附研究     

郭鲁钢  王海增  邢坤 《中国海洋大学学报(自然科学版)》2008,38(1):107-110,134

利用硫酸镁和造纸草浆黑液制备含镁氧化合物的吸附剂,通过化学分析、表面性质分析、X射线衍射和红外光谱等对吸附剂进行了表征.考察了吸附剂焙烧温度、投加量、吸附时间以及pH值等因素对活性黄ST-4RFN吸附性能的影响,吸附过程可用Freundlich模型来描述.  相似文献