Reactive Nitrogen Compounds at Spitsbergen in the Norwegian Arctic     

S. Solberg  T. Krognes  F. Stordal  OØ Hov  H. J. Beine  D. A. Jaffe  K. C. Clemitshaw  S. A. Penkett 《Journal of Atmospheric Chemistry》1997,28(1-3):209-225

Simultaneousindependent measurements of NO_y and NO_x(NO_x= NO + NO₂) by high-sensitivitychemiluminescence systems and of PAN (peroxyacetylnitrate) and PPN (peroxypropionyl nitrate) by GC-ECDwere made at Spitsbergen in the Norwegian Arcticduring the first half year of 1994. The average mixingratio of the sum of PAN and PPN (denoted PANs)increased from around 150 pptv in early winter to amaximum of around 500 pptv in late March, whereasepisodic peak values reached 800 pptv. This occurredsimultaneously with a maximum in ozone which increasedto 45–50 ppbv in March–April. The average NO_xmixing ratio was 27 pptv and did not show any cyclethrough the period. The NO_y mixing ratio showeda maximum in late March, while the difference betweenNO_y and PAN decreased during spring. This is anindication of the dominance of PAN in the NO_ybudget in the Arctic, but possible changes in theefficiency of the NO_y converter could alsocontribute to this. Although most PAN in theArctic is believed to be due to long range transport,the observations indicate local loss and formationrates of up to 1–2 pptv h^-1 in April–May.Measurements of carbonyl compounds suggest thatacetaldehyde was the dominant, local precursor ofPAN.Now at 1.  相似文献   

中国北西部地区地浸砂岩型铀矿床的成矿条件与分布规律   总被引：2，自引：0，他引：2  

罗梅 《物探化探计算技术》1996,(S5)

中亚地区发现大量可地浸砂岩型铀矿床引起了我国的重视 ,目前正在积极开展此类型铀矿的找矿工作。我国北西部是寻找类似中亚地区层间氧化带后生地浸砂岩型铀矿床最理想的地区 ,本文在论述了区域大地构造特征、地壳演化与区域铀成矿带形成的基础上 ,着重阐明了区域中新生代盆地地浸砂岩型铀矿床形成的铀源条件、盆地类型与结构及富铀性对形成地浸砂岩型铀矿的影响 ;并以区内已有层间氧化带地浸砂岩型铀矿床为例 (伊犁盆地、二连盆地与测老庙盆地砂岩型铀矿床 ) ,论述了盆地砂岩型铀矿床形成的岩相古地理条件、水文地质与层间氧化带发育条件及对铀成矿的影响 ;并阐述了本区层间氧化带地浸砂岩型铀矿床的分布规律  相似文献   

鄂西震旦系上统含磷岩系的划分与对比     

李钟模  郑文忠 《化工矿产地质》1996,18(1):47-52

上震旦统陡山沱组是鄂西地区最具工业价值的含磷地层。著名的磷矿有荆襄磷矿、宜昌磷矿、兴(山)神(农架)保(康)磷矿。迄今已有20多年的勘探史,但由于各矿区研究程度不一,又缺古生物依据,亦不能依靠同位素年龄来作划分对比,故在地层及磷矿层的划分、对比上认识不一。笔者结合磷矿特征及含磷岩系岩类组合、剖面结构特点、稀土元素特征等,将本区划分为4个磷矿分布区,将陡山沱组划分为3个岩性段、5个含磷层位。  相似文献   

钻孔灌注桩常见现场事故的分析与防治     

黄跃进 《江苏地质》1997,21(1):47-51

论述了钻孔灌注桩常见现场事故的预防，分析和治理等方面的几个问题，叙述了钢筋笼上浮，导管堵塞，钢筋笼掉入孔内，导管提出混凝土面，掉钻头，串孔等事故的原因和处理方法及预防措施。  相似文献   

全球观测系统实地观测的内容和要求   总被引：1，自引：0，他引：1  

赵晓英  张志强 《地球科学进展》1997,12(5):455-460

全球性观测系统在检测，监测和预测地球系统的变化中发挥着越工重要的作用。地球系统的复杂性，多尺度性，非线性性，突变性，非平衡性等要求各种全球性观测系统之间必须加强联系与协调。评述了全球性观测系统联系与协调的发展趋势，并依据《全球性观测系统实地观测的内容和体系纲要》、介绍了全球性观测系统实地观测的内容和规范要求。  相似文献   

Comparison of Aircraft and Ground-Based FluxMeasurements during OASIS95     

P. R. Isaac  J. Mcaneney  R. Leuning  J. M. Hacker 《Boundary-Layer Meteorology》2004,110(1):39-67

Aircraft and ground-based measurements made during the1995 Australian OASIS field campaign are compared. The aircraft data were recorded during low-level flightsat 6 m above ground level and grid flights at altitudes of between 15 and 65 m, allin unstable atmospheric conditions. The low-level flights revealed an inadequate temperaturesensor response time, a correction for which was determined from subsequent work ina wind tunnel. Aircraft and ground-based measurements of mean wind speed, wind directionand air temperature agree to within 0.2 m s^-1, 4° and 0.9 °C respectively.Comparisons between aircraft and ground-based observations of the standarddeviations of vertical velocity, horizontal wind speed, air temperature and specifichumidity have slopes of 0.96, 0.97, 0.92 and 0.99 respectively but the observed scatter isroughly twice the random error expected due to the averaging length of the aircraft data andthe averaging period of the ground-based data. For the low-level flights, the ground-basedand aircraft measurements of sensible and latent heat flux show mean differences of 27 and-25 W m^-2 respectively, which reduce to 11 and -4 W m^-2 respectivelywhen analysis of aircraft data is limited to areas immediately adjacent to the fluxtowers. For the flights at 15 to 65 m above ground level, the mean differences between theground-based and aircraft measurements of sensible and latent heat flux are -22 and-1 W m^-2 respectively and these change to -1 and -7 W m^-2 respectively oncethe effect of surface heterogeneity is included. Aircraft and ground-based measurementsof net radiation agree to within 6% at one ground-based site but differ by 20% at a second.Aircraft measurements of friction velocity at 6 m above the ground agree well withground-based data, but those from flights between 15 and 65 m above ground level do not.This is because at these heights the aircraft measurements provide the local shear stress,not the surface shear stress. Overall, the level of agreement allows confidence in the aircraftdata provided due care is taken of instrument response times and differences in thesurfaces sampled by aircraft and ground-based systems.  相似文献   

Investigating the Halogen Chemistry From High-Latitude Nighttime Stratospheric Measurements of OClO and NO2     

Emmanuel Damien Rivière  Michel Pirre  Gwenaël Berthet  Jean-Baptiste Renard  Franck Lefèvre 《Journal of Atmospheric Chemistry》2004,48(3):261-282

Two cases of simultaneous nighttime measurements of NO₂ and OClO in the winter polar stratosphere are analyzed in order to test our present knowledge of halogen chemistry in the presence of high amount of NO₂ at low temperature. Comparisons with Lagrangian model calculations using several hypotheses are performed. First simulations, using the admitted constant rates of chemical reaction, strongly underestimate the measured OClO while the NO₂ profiles are correctly reproduced. If uncertainties in actinic fluxes calculations are taken into account, simulation results do not show a significant reduction of the underestimation. A better agreement can be achieved if the formation of unstable isomers of ClONO₂ and of BrONO₂ occurs in the cold conditions of the polar stratosphere. An approximate value of the branching ratios of the channels leading to ClONO₂ and ClOONO, and to BrONO₂ and BrOONO, necessary to reproduce both OClO and NO₂ is given and discussed.  相似文献   

原位磁化X射线粉末衍射法测还原铁粉的微观磁致伸缩系数     

罗新  刘世雄 《华东地质学院学报》2004,27(2):178-180

首次报导X射线粉末衍射法测量铁粉晶胞的磁致伸缩系数。还原铁粉样品原位磁化后 ,铁立方晶胞产生磁致伸缩效应 ,晶胞参数的变化引起衍射峰位置和晶面间距的变化。实验测得铁晶胞λ1 0 0 为 3 .3 3× 10 - 4,此结果表明铁晶胞的微观磁致伸缩系数比棒状、薄膜或粉末压片的系数大约 16倍。对此现象进行了合理的理论解释 ,指出大块材料中的粉末多晶之间具有较大的空隙 ,从而使得宏观磁致伸缩系数变小  相似文献   

Recent Progress and Future Prospects in Solar Physics, and Their Relevance for Planet Earth     

Roger M. Bonnet  Anuschka pauluhn 《Surveys in Geophysics》2004,25(5-6):371-440

Understanding our star, the Sun, is of fundamental interest for life on Earth. In this paper, the status of knowledge in solar physics of roughly two decades ago is summarised, and the most recent developments in this very active field are shown, many of them achieved by means of space based missions. The Sun–Earth connection is described and, finally, an outlook on future solar research is given.  相似文献   

Geological controls on rock mass classification of coal from Huntly East Mine, New Zealand     

Vicki Moon  Trisha Roy 《Engineering Geology》2004,75(2):201-213

Rock Mass Rating (RMR) measurements from 65 sites within Huntly East underground coal mine are presented. All measurements are in coal, for which the dominant discontinuities are vertical cleat. Basic RMR values using two discontinuity spacings are presented: overall RMR based on the average spacing of all individual discontinuities; and cleat zone RMR based on the average spacing between zones of cleat. Cleat orientations are highly variable, but on average approximately parallel horizontal stress axes (face cleat follows maximum horizontal stress axis, butt cleat follows minimum horizontal stress axis).Contours of RMR variations throughout the mine are used to compare rock mass conditions with geological structure. It is apparent that: (1) RMR is least within downthrown fault blocks, and particularly immediately on the downthrown sides of faults, and greatest in upthrown fault blocks; and (2) RMR contours parallel horizontal stress axes within fault-bounded blocks, and bend to parallel faults at block boundaries. From similar contours for parameters contributing to RMR, the Rock Quality Designation (RQD), groundwater rating, and discontinuity condition rating create most of the observed variations in RMR. RQD is determined from the measured discontinuity frequency and hence is a measure of the degree of fracturing of the rock mass. This is interpreted as influencing the groundwater and condition parameters directly by allowing greater water ingress. Discontinuity frequency is greatest (least spacing) in the immediate vicinity of faults, and in downthrown fault blocks, generating low RMR values. Within fault blocks RQD varies little, so RMR contours align with cleat orientations.As RMR contours, faults, stress field and cleat orientation are clearly interrelated, there is unequivocally a connection between RMR and structural geology; this allows some predictive capacity in terms of ground conditions. If geological features can be accurately defined through either drilling programs or seismic surveys, then ground conditions may be predicted before panels are driven.  相似文献