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41.
The kinetics of the reactions of C2H radical with ethane (k1), propane (k2), and n-butane (k3) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C2H decay profiles in the presence of both the alkane reactant and O2 are monitored by the CH(A2Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k1(T) = (0.51 ± 0.06) × 10−10 exp[(−76 ± 30)K/T] cm3 molecule−1 s−1 (T = 96-800 K), k2(T) = (0.98 ± 0.32) × 10−10exp[(−71 ± 60)K/T] cm3 molecule−1 s−1 (T = 96-361 K), and k3(T) = (1.23 ± 0.26) × 10−10 cm3 molecule−1 s−1 (T = 96-297 K). At T = 296 K, k1 is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   
42.
Paul Withers  S.W Bougher 《Icarus》2003,164(1):14-32
Mars Global Surveyor accelerometer observations of the martian upper atmosphere revealed large variations in density with longitude during northern hemisphere spring at altitudes of 130-160 km, all latitudes, and mid-afternoon local solar times (LSTs). This zonal structure is due to tides from the surface. The zonal structure is stable on timescales of weeks, decays with increasing altitude above 130 km, and is dominated by wave-3 (average amplitude 22% of mean density) and wave-2 (18%) harmonics. The phases of these harmonics are constant with both altitude and latitude, though their amplitudes change significantly with latitude. Near the South Pole, the phase of the wave-2 harmonic changes by 90° with a change of half a martian solar day while the wave-3 phase stays constant, suggesting diurnal and semidiurnal behaviour, respectively. We use a simple application of classical tidal theory to identify the dominant tidal modes and obtain results consistent with those of General Circulation Models. Our method is less rigorous, but simpler, than the General Circulation Models and hence complements them. Topography has a strong influence on the zonal structure.  相似文献   
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莱州湾南岸潍河下游地区咸水入侵灾害成因及特征   总被引:8,自引:1,他引:7  
通过对莱州湾南岸咸水入侵较严重地潍河下游地区晚更新世以来沉积特征及现代自然环境条件变化的分析,探讨了沉积相对咸水入侵产生及空间范围特征的环境机理。晚更新世以来的三次海平面升降变化造成了潍河下游地区海陆沉积环境交替,形成了巨厚的海陆交互相沉积层。海进时期,大面积的滨海平原被淹没,在近海平原洼地滞留的海水经过蒸发、浓缩变为卤水,成为咸水入侵的物源;海退后陆源碎屑在滨海地区沉积形成了巨厚的古河道砂层。20世纪70年代末期以来,随着对地下淡水的过度开采,淡咸水水头压力差减小.卤水通过古河道砂层快速南侵。通过对潍河下游地区100余个地质钻孔水化学连续监测资料分析,阐明了咸水入侵的特征,有针对性地提出了咸水入侵的防治措施。  相似文献   
47.
Mobile Agent技术是一门新兴的技术,具有移动性、智能性和异步计算的特点,已成为计算机网络和分布式系统最具活力的发展方向.现对Mobile Agent的概念、系统结构及其关键技术进行了分析和探讨.  相似文献   
48.
基于SAR干涉点目标分析技术的城市地表形变监测   总被引:1,自引:0,他引:1  
通过深入研究干涉点目标的相位模型,提出基于空间搜索的邻近点目标干涉相位差解缠方法,用以计算点目标的地形残差和线性形变,以及分离点目标大气延迟相位和非线性形变相位的时空域滤波方法,解决干涉点目标分析中的关键问题.最后,以苏州地区地表沉降监测为应用试验,利用形成的SAR干涉点目标形变信息提取技术,获取苏州市区1992-2002年间的地表沉降信息.研究结果与已有文献记录保持比较好的一致性,证明SAR干涉点目标技术完全可以发展成为应用于城市地表形变监测的实用化技术.
Abstract:
Interferometric point target analysis (IPTA) is one of the latest developments in radar interferometric processing. It is achieved by analysis of the interferometric phases of some individual point targets, which are discrete and present temporarily stable backscattering characteristics, in long temporal series of interferometric SAR images. This paper analyzes the interferometric phase model of point targets, and then addresses two key issues within IPTA process. Firstly, a spatial searching method is proposed to unwrap the interferometric phase difference between two neighboring point targets. The height residual error and linear deformation rate of each point target can then be calculated, when a global reference point with known height correction and deformation history is chosen. Secondly, a spatial-temporal filtering scheme is proposed to further separate the atmosphere phase and nonlinear deformation phase from the residual interferometric phase. Finally, an experiment of the developed IPTA methodology is conducted over Suzhou urban area. Totally 38 ERS-1/2 SAR scenes are analyzed, and the deformation information over 3 546 point targets in the time span of 1992-2002 are generated. The IPTA-derivecl deformation shows very good agreement with the published result, which demonstrates that the IPTA technique can be developed into an operational tool to map the ground subsidence over urban area.  相似文献   
49.
Optimal deflection of NEOs en route of collision with the Earth   总被引:1,自引:0,他引:1  
Ralph Kahle  Gerhard Hahn 《Icarus》2006,182(2):482-488
Recently, a method for the n-body analysis of the velocity change required to deflect a hazardous near-Earth object (NEO) was presented by Carusi et al. [Carusi, A., Valsecchi, G.B., D'Abramo, G., Boattini A., 2002. Icarus 159, 417-422]. We extent this method in order to optimize the velocity change vector instead of its along-track magnitude. From an application of both methods to a fictitious NEO we find Carusi's parallel approach to be reasonable for phases of unperturbed two-body motion. But, for orbit phases inhering third-body perturbations, i.e., for planetary close approaches or prior to a collision, the results obtained from the new method show the radial component of deflection impulse to play a major role. We show that a fivefold greater efficiency can be achieved by a deflection impulse being non-parallel to orbital velocity. The new method is applied to two possible 99942 Apophis impact trajectories in order to provide constraints for future Apophis deflection mission analysis.  相似文献   
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