石油污染对黄河口沉积物工程性质的影响     

王林昌  袁守启  邢可军 《中国海洋大学学报(自然科学版)》2010,40(1)

对黄河口胜利油田某油井附近沉积物进行石油污染状况调查研究,采用坑探试验现场调查污染范围,发现油井沉积物在一定范围内存在石油污染,污染多在0.2～1.5 m深度内,水平距离在140～440 m之间.原位测试污染沉积物强度,取样进行室内石油浓度和沉积物物理力学指标测试.石油污染沉积物物理力学性质与未污染的有较大差别,污染后沉积物的重度、渗透系数和强度等均有所降低.污染后的沉积物结构,多成块状和板状结构.  相似文献   

钱塘江口涌潮的二维数值模拟   总被引：16，自引：1，他引：16       下载免费PDF全文

谭维炎  韩曾萃 《水科学进展》1995,6(2):83-93

应用二维有限体积法、Osher格式及间断拟合法,计算了钱塘江河口涌潮产生、发展到消亡的全过程。该算法能保证水量和动量守恒,且能适应水深巨大变化和动边界。根据钱塘江涌潮的特点,可将其合理概化为一线潮。在网格尺寸较大情况下,计算的一线潮仍保持高分辨率,能准确满足水力学间断条件,且计算量小,可以在微机上实现。在对某实测半日小潮进行率定后,对随后的大潮进行了验证计算,涌潮的主要特征(如涌潮高度、移速、水位和流场等)与实测资料符合良好,证实了模型的合理性和模拟能力。  相似文献   

A comparison of the early diagenetic environment in intertidal sands and muds of the Manukau Harbour,New Zealand     

R. B. Williamson  T. M. Hume  J. Mol-Krijnen 《Environmental Geology》1994,24(4):254-266

The early diagenetic environment of intertidal sandy sediments (sands) and muddy sediments (muds) is described and compared from two cores taken from an unpolluted part of the Manukau Harbour, New Zealand. Extraction techniques characterized the form of the trace elements (Fe, Mn, S, C, Pb, Zn, Cu) at different depths in the sediment. Dissolved forms of Fe, Mn, and S were measured in interstitial water. Nonresidual metal concentrations, humic acid, FeS, and FeS₂ are an order of magnitude higher in the muds than in the sands because of dilution by unreactive sand particles. Muds contain a larger proportion of metals in the mobile fractions; exchangeable (Mn), carbonate (Mn, Fe, Zn), and easily-reducible oxide (Fe, Mn, Zn, Pb). This is due to greater surface area (for Mn adsorption); the favorable conditions for MnCO₃, FeCO₃, and FeS precipitation; and higher concentrations of easily reducible iron oxide and humic acid. Therefore, compared to the sands, muds are more important as reservoirs for toxic metals, both in terms of quantity and availability. At either site there was very little difference between the forms of Zn, Pb or Cu identified by sequential extraction as sediments changed from oxic to anoxic conditions. One reason for this is that the amounts and proportions of some of the important components that bind metals, viz., amorphous iron hydrous oxides, humic acids, and FeS₂, do not change much. Other components that do change with redox conditions, for example, manganese phases and FeS, are only minor components of the sediment. Redox conditions, then, have relatively little effect on trace-metal partitioning in the sediment matrix of these unpolluted sediments.  相似文献   

Levels of organochlorine pesticide residues in some organs of the Ganges perch, Lates calcarifer, from the Ganges-Brahmaputra-Meghna Estuary, Bangladesh     

Jabber SA  Khan YS  Rahman MS 《Marine pollution bulletin》2001,42(12):1291-1296

Levels of organochlorine pesticide residues (p,p′ DDT, DDD, DDE, Aldrin, Dieldrin, Lindane, Heptachlor and BHC) were analysed in the dry and wet seasons in four organs (muscle, liver, gut and egg samples) of Ganges Perch, Lates calcarifer, collected during October–November–December, 1996 and May–June–July, 1997 from the Ganges–Brahmaputtra–Meghna estuary. The residues were analysed by using gas-chromatography (GC) in electron capture detector (ECD) mode and were verified by thin layer chromatography (TLC). Among the four organs analysed, the residues were found in the order egg > gut > muscle > liver. The pesticide residues were found in the order ∑DDT > Heptachlor >Dieldrin > Aldrin. Higher levels of residues were found during the dry season due to high lipid content in fishes. A positive correlation was observed between the pesticide residues (∑DDT and ∑OCs) and lipid contents of fish, and the correlation was found to be linear. The concentrations of pesticide residues in muscle, liver and gut were below the FAO/WHO (1993) recommended permissible limit except in eggs.  相似文献   

Hydrocarbons in surface sediments from the Changjiang (Yangtze River) Estuary, East China Sea   总被引：9，自引：0，他引：9  

Bouloubassi I  Fillaux J  Saliot A 《Marine pollution bulletin》2001,42(12):1335-1346

Sedimentary aliphatic (AH) and polycyclic aromatic hydrocarbons (PAHs) were studied in the Changjiang Estuary and the adjacent East China Sea. Total AH ranged from 2.20 to 11.82 μg g⁻¹ and consisted of n-alkanes and a dominant petroleum-related unresolved complex mixture (UCM). Within the n-alkanes, terrestrial plant wax compounds prevailed at nearly all stations. Of the PAHs, biogenic perylene dominated at stations receiving riverine inputs. Anthropogenic PAHs originating from combustion/pyrolysis processes varied from 17 to 157 ng g⁻¹, while fossil PAH concentrations ranged from 42 to 187 ng g⁻¹. Both biogenic and anthropogenic hydrocarbons are primarily derived from riverine discharges and accumulate at shallow-water stations. Distinct phase associations lead, nevertheless, to different sedimentation patterns. Fossil PAHs are enhanced at offshore stations where they are introduced directly by shipping activities. Biomarker fingerprints ascribe their source to Chinese crude oils. The overall levels of anthropogenic hydrocarbons are low compared to relevant areas worldwide and reveal a low/moderate level of hydrocarbon pollution.  相似文献   

椒江河口沉积物As、Hg黄铁矿矿化程度及其生物有效性          下载免费PDF全文

叶思源钟少军  丁喜桂袁红明 《地质论评》2007,53(4):499-505

本文利用取自浙江椒江河口3个未扰动柱状沉积物样,进行了孔隙水化学测试、固相沉积物的活性分量与黄铁矿分量的分级提取和测试,结果表明：Hg主要以黄铁矿态形式存在于沉积物中。As在有机碳较高的河口区潮上带和沉积速率较慢的潮下带主要以黄铁矿形态存在[DTMP（degree of trace metal pyritization,痕量元素黄铁矿矿化程度）〉50%）],而在中潮带As的黄铁矿矿化程度略低（DTMP均值为40.99%）,研究区DOP（Fe的黄铁矿矿化程度）值普遍较低（〈35%）,Mn-DTMP低于3.32%。从而揭示了浙江椒江河口沉积物在数厘米以下,毒性痕量元素Hg和As被高度黄铁矿矿化的规律性,并指出在遇有海事活动或风暴潮事件对海底沉积物进行扰动时,河口沉积物与充氧的海水反应,高度黄铁矿矿化的痕量元素会转变成活性态,从而导致近海生态系统的毒性事件。  相似文献   

灌河口潮滩重金属累积特征及污染评价   总被引：6，自引：3，他引：6  

于文金  邹欣庆 《地球化学》2007,36(4):425-433

河口地区潮滩是重金属重要的"汇"。测定了灌河口(燕尾港)潮滩高中低滩的33个表面样粒度、重金属数据,研究了4根柱状样的重金属和粒度特征,利用地累积指数法、潜在生态危害指数法及富集指数法等评价指标,对灌河口重金属的污染状况进行了评价,并对其结果进行了相互比较和印证。分析结果显示,灌河口潮滩重金属的分布主要受水动力影响,特别是受粘土分布的控制。Cd与粒径Ф值相关性不显著,相关系数只有0.099,而与粘土含量呈明显正相关关系,Hg的变化趋势恰恰相反,其含量随着距离河口距离的加大反而有增加的趋势;其他元素的变化趋势不明显。重金属元素Zn、Pb、Cu、Hg含量变化走势基本相同,用Li作归一化标准元素归一化后,所有重金属元素的归一化值变化波动范围均比重金属含量值明显收窄,波峰和波谷有后延的趋势。灌河口滩涂总体重金属环境尚可,但存在一定程度的Hg、Cu污染富集。柱状样Hg、Cu的地累积污染指数总体上均呈现随深度增加而降低的趋势。  相似文献   

Factors Controlling Sulfide Geochemistry in Sub-tropical Estuarine and Bay Sediments     

John W. Morse  Heather Thomson  David W. Finneran 《Aquatic Geochemistry》2007,13(2):143-156

The primary factors that control the concentration of total reduced (inorganic) sulfide in coastal sediments are believed to be the availability of reactive iron, dissolved sulfate and metabolizable organic carbon. We selected nine sites in shallow (<3 m), close to sub-tropical, estuaries and bays along the central Texas coast that represented a range in sediment grain size (a proxy for reactive iron), salinity (a proxy for dissolved sulfate), and total organic carbon (a proxy for metabolizable organic carbon). Based on these parameters a prediction was made of which factor was likely to control total reduced sulfide at each site and what the relative total reduced sulfide concentration was likely to be. To test the prediction, the sediments were analyzed for total reduced sulfide, acid volatile sulfide, and citrate dithionate-extractable, HCl-extractable and total Fe in the solid phase. Using solid-state gold–mercury amalgam microelectrodes and voltammetry, we determined pore water depth profiles of Fe(II) and ΣH₂S and presence or absence of FeS_(aq). At five of the nine sites the calculated degree of sufildization of citrate dithionite-reactive-iron was close to or greater than 1 indicating that rapidly reactive iron was probably the limiting factor for iron sulfide mineral formation. At one site (salinity = 0.9) dissolved Fe(II) was high, ΣH₂S was undetectable and the total reduced sulfide concentration was low indicating sulfate limitation. At the last three sites a low degree of sulfidization and modest total reduced (inorganic) sulfide concentrations appeared to be the result of a limited supply of metabolizable organic carbon. Fe(II)–S(-II) clusters (FeS_(aq)) were undetectable in 10 out of 12 bay sediment profiles where ΣH₂S was close to or below detection limits, but was observed in all other porewater profiles. Acid volatile sulfide, but not total reduced sulfide, was well correlated with total organic carbon and ranged from being undetectable in some cores to representing a major portion of total reduced sulfide in other cores. Although predicted controls on total reduced sulfide were good for very low salinity water or sandy sediments, they were only right about half the time for the other sediments. The likely reasons for the wrong predictions are the poor correlation of total organic carbon with grain size and differing fractions of metabolizable organic carbon in different sedimentary environments. Differences in sediment accumulation rates may also play a role, but these are difficult to determine in this region where hurricanes often resuspend and move sediments. This study demonstrates the need to examine more complex and often difficult to determine parameters in anoxic “normal marine” sediments if we are to understand what controls the concentration and distribution of sulfides.  相似文献   

闽江河口湿地资源动态变化的分形研究     

钟春棋  曾从盛  柳铮铮 《湿地科学与管理》2007,3(3):50-53

本研究以分形理论为基础,并借助GIS、RS技术,利用1986年和2002年两期TM遥感影像,提取获得了1986年和2002年闽江河口湿地资源的空间信息,根据分形理论中分形维数和稳定性指数的物理意义,揭示了闽江河口湿地资源动态变化情况。研究表明:闽江河口的湿地类型具有分形结构.并且由于受到较强的人类活动的干预,湿地斑块的形状较为复杂,且稳定性较差。  相似文献   

DRY-SEASON VARIABILITY IN SUSPENDED SEDIMENT CONCENTRATIONS IN THE SOUTH PASSAGE OF THE CHANGJIANG ESTUARY     

Wenxiang ZHANG Shilun YANG Jun ZHU Shiliang GONG Pingxing DING 《国际泥沙研究》2007,22(3):199-207

This paper reports the results of continuous monitoring of turbidity, water depth, salinity (using an Optical Backscatter Sensor (OBS)), and current velocity (using a Current meter (SLC9-2)) in the South Passage of the Changjiang Estuary over a spring–neap period in February 2003 (dry season). The turbidity measured via OBS was closely correlated with the suspended sediment concentration (SSC), which was highly variable. Over the study period, the SSC in the middle layer ranged from 110 to 1400 mg/l. The minimum SSC occurred during a late ebb tide, and the maximum SSC occurred during a late flood tide. On average, the SSC was 1.5 times higher during flood tide than during ebb tide. Vertically within the water column, SSC increased downward, with the ratio of SSC measured near the bed to that measured at the surface ranging from 1.90 to 18.3. The temporal variability in SSC is jointly governed by tides and wind-induced waves, whereas the vertical variability in SSC is attributed to the effect of gravity and vertical water circulation.  相似文献