Variability of NO₂ in different environments at a moderately polluted island over the southwestern Indian Ocean     

Chatrapatty Bhugwant  Jean-Luc Hoareau 《Atmospheric Research》2003,66(4):241-259

This work presents the temporal evolution and spatial distribution of nitrogen dioxide (NO₂) measured with the help of passive diffusion tubes in different environments: rural, sub-urban, urban, at La Réunion Island in December 1997 and November 2000 (austral spring), respectively. NO₂ concentration exhibits notable enhancement from 1997 to 2000. For instance, its mean concentration was 16 and 20 μg/m³ in December 1997 and November 2000, respectively, at La Réunion Island, especially in inhabited regions due to increase of local anthropogenic activities, mainly traffic circulation, in the absence of house heating and biomass burning. We also observe a net increase of pollutant levels by a factor two in rural/remote areas within 3 years, which is tied to the extension of inhabited areas and air-flows from enhanced local sources. The increase of atmospheric pollutants is mainly due to enhancement of anthropogenic activities (traffic) since the 1990s at La Réunion Island, which results from a constant increase of population and consequently, from a higher number of vehicles in circulation. Importantly, in cities like Saint-Denis, where traffic network has been subject to notable improvement (e.g. single to double lanes, etc.), pollutant levels exhibit little variability as in temperate continental latitudes. Semi-continuous NO₂ concentration measured in parallel with ozone in November 2000 also showed that daytime photochemical ozone production is influenced by pollutant and precursor (NO₂) levels at Saint-Denis, while nighttime ozone increase is mainly tied to dynamical processes. The November 2000 ozone diurnal pattern is notably different from that observed in September 1995, during which a daytime ozone loss was observed, pointing out that atmospheric conditions have been subject to notable changes, i.e., clean to moderately polluted, within a few years at La Réunion Island. The results presented here point out that the ‘source enhancement effect’ is superimposed on dynamical and photochemical processes to influence pollutants variability and hence atmospheric chemistry, in a quite ‘pristine’ tropical oceanic region.  相似文献   

矿物流体包裹体中的羧酸     

曾贻善  刘家齐 《矿物岩石地球化学通报》1997,(1)

矿物流体包裹体中的羧酸曾贻善刘家齐（北京大学地质系，北京１００８７１）（地矿部宜昌地质矿产研究所，宜昌４４３００３）关键词矿物包裹体浸取液羧酸离子色谱分析分子中含有羧基官能团（—ＣＯＯＨ）的物质称为羧酸。Ｆｅｉｎ［１］和Ｓｈｏｃｋ［２］曾概述羧酸在自...  相似文献   

沉积盆地流体—岩石相互作用研究的现状   总被引：17，自引：0，他引：17  

蔡春芳 《地球科学进展》1996,11(6):575-579

沉积盆地流体－岩石相互作用研究主要是通过实验地球化学和岩石学，地球化学模拟方法开展的，综述了这一领域的研究现状，主要包括有机酸来源和分布及期 对矿物稳定性的影响，地层水成因与演化、烃类与岩石间的氧化还原反应、以及储层润湿性的变化等，并展望了其 发展趋势。  相似文献   

Characterisation of brown coal humic acids and modified humic acids using pyrolysis gcms and other techniques     

W. R. Jackson  G. D. Bongers  P. J. Redlich  G. Favas  Y. Fei  A. F. Patti  R. B. Johns 《International Journal of Coal Geology》1996,32(1-4)

It has been proposed that Victorian brown coal can be considered as a two-component structure — a lignocellulosic “host”, containing various amounts of weakly bound or entrapped “guest” material together with very small amounts of inorganic and/or mineral matter. The latter predominantly consists of wax esters and/or terpenoid material. In this paper we describe attempts to gain structural information regarding the more complex, “host” component of the coal. Our initial model compound has been humic acid that can be readily obtained from the coal by alkaline extraction. It has been found that “pure” humic acid, free from material associated with the “guest” components of the coal, can be obtained by a highly selective, low-yielding alkaline extraction. This humic acid has been studied by nmr spectroscopy and pyrolysis gas chromatography-mass spectroscopy (py-gc/ms). The products arising from py-gc/ms have been compared with those obtained from similar pyrolysis of whole coals. Alkylation of humic acids using alkyl halides in the presence of base has been successfully carried out and reactivity of the resulting materials compared with those of the parent coal and humic acid.  相似文献   

The influence of marine inflows on the chemical composition of groundwater in small islands: the example of the Cyclades (Greece)     

J. Dazy  C. Drogue  P. Charmanidis  Ch. Darlet 《Environmental Geology》1997,31(3-4):133-141

 Marine contamination of groundwater may be caused by seawater intrusion and by salt spray. The role of both processes was studied in the Cyclades archipelago on four small islands (45–195 km²) whose aquifers consist essentially of fractured, weathered metamorphic rocks. Annual rainfall ranges from 400 to 650 mm and precipitation has high total dissolved solids contents of 45–223 mg l^–1. The chemical characteristics of the groundwater, whose salinity is from 0.4 to 22 g l^–1, are strongly influenced by seawater intrusion. However, the effect of atmospheric input is shown in certain water sampling locations on high ground elevation where the dissolved chloride contents may attain 200 mg l^–1. Received: 14 November 1995 · Accepted: 9 September 1996  相似文献   

中国海洋地球物理进展   总被引：2，自引：2，他引：2       下载免费PDF全文

刘光鼎 《地球物理学报》1997,40(Z1):46-49

在中国地球物理学会50周年之际，总结海洋地球物理工作是十分重要的文章从中国海油气普查、近海工程地质调查。大洋多金属结核调查和中国海基础调查四个方面简要地阐述它们的进展。  相似文献   

电法勘探的发展和展望   总被引：9，自引：1，他引：9       下载免费PDF全文

何继善 《地球物理学报》1997,40(Z1):308-316

电法勘探在经历了近一个世纪的发展后，其方法理论、仪器设备、野外数据采集、处理和解释等方面都经历了一系列重大变化．本文以方法理论的进展为主线，回顾、展望了目前电法勘探中几个重要而令人关注的研究焦点．这些问题的研究进展将会对21世纪的电法勘探产生深远的影响．  相似文献   

在1996年南方油气勘探工作会议上的讲话(主要部分) 努力实现南方海相油气勘探重大突破     

周永康 《海相油气地质》1997,(1)

南方地质条件有四方面的特点:碳酸盐岩区与特提斯域有关,具有良好的含油气前景;叠置在碳酸盐岩区上的南、北两大前陆盆地带,对古生界原型盆地烃源岩的演化、油气藏形成和保存起到重要作用;南方海相地层具有丰富的烃源岩;后期多旋回构造运动,使南方海相油气系统变得十分复杂。南方油气选区评价的关键是保存条件,在含油气系统中“保存单元”是优选勘探目标的重要依据。“九五”期间,一要主攻中、下扬子区,获重大突破;二要积极做好滇黔桂地区三个盆地(南盘江盆地、楚雄盆地、十万大山盆地)的预探;三要进一步搞好区域评价。  相似文献   

南方海相油气勘探为什么久攻不下？   总被引：7，自引：0，他引：7  

冯增昭  鲍志东 《海相油气地质》1997,2(4):4-7

中国南方从震旦纪到三叠纪８个地质时代海相地层厚度巨大，具有很大的生烃能力。然而除四川地区之外，至今油气勘探尚无重大突破。积十二年对南方５个地质时代海相地层基础地质研究及制图的经验，认为南方海相油气勘探久攻不下的原因是：（１）对整个南方还缺乏全面的、历史的，整体的和深刻的认识；（２）还不于用什么方法或顺序去认识它。建议重视基础地质研究，并以中国南方二叠纪及三叠纪的岩相古地理研究和制图为例，提出基础地  相似文献   

中国南方海相含油气保存单元的层次划分与综合评价   总被引：1，自引：0，他引：1  

梁兴  叶舟  马力  吴少华  张廷山  刘家铎  徐克定 《海相油气地质》2004,(Z1)

以最近十年中国南方的海相新区油气勘探评价成果为依托 ,以油气成藏和整体封闭保存体系评价为核心 ,在渝东—湘鄂西、中下扬子和滇黔桂三大区域划分出 9个有利区块 5 1个含油气保存单元 ,并将其归纳为四个层次。综合评价认为 ,方西和石柱保存单元具有较好的整体封存体系 ,属持续性含油气保存单元 ,为首选勘探目标 ;江汉盆地南部、句容—海安区块、南鄱阳坳陷、楚雄盆地东北部具备或基本具备整体封存条件 ,属于沉积重建型含油气保存单元 ,通过精细勘探可望获得商业性油气流 ;楚雄盆地西北部、南盘江坳陷、十万大山盆地和渝东—湘鄂西地区利川复向斜由于晚期强烈构造改造而仅存在部分封存体系 ,需要攻关探索 ;思茅、渝东—湘鄂西地区的花果坪和桑植—石门地区已失去整体封闭保存条件 ,仅局部存在封存体系 ,地质条件高度复杂 ,勘探风险甚高。  相似文献