Screening model for volatile pollutants in dual porosity soils     

Mohamed M. Hantush  Rao. S. Govindaraju  Miguel A. Marioand Zhonglong Zhang 《Journal of Hydrology》2002,260(1-4):58-74

This paper develops mass fraction models for transport and fate of agricultural pollutants in structured two-region soils. Mass fraction index models, based on a semi-infinite domain solution, are derived that describe leaching at depth, vapor losses through soil surface, absorption, and degradation in the dynamic- and stagnant-water soil regions. The models predict that leaching is the result of the combined effect of the upward vapor-phase transport relative to downward advection, residence time relative to half-life, dispersion, and lateral diffusive mass transfer. Simulations show that leached fraction of volatile compounds does not always decrease monotonically with increased residence time relative to the pollutant half-life, as a result of complex interactions among the different physical and biochemical processes. The results show that leaching, volatilization, and degradation losses can be affected significantly by lateral diffusive mass transfer into immobile-water regions and advection relative to dispersion (i.e. Peclet number) in the mobile-water regions. It is shown that solute diffusion into the immobile phase and subsequent biochemical decay reduces leaching and vapor losses through soil surface. Potential use of the modified leaching index for the screening of selected pesticides is illustrated for different soil textures and infiltration rates. The analysis may be useful to the management of pesticides and the design of landfills.  相似文献   

层控夕卡岩型矿床成矿系统的元素活动性及质量迁移--以铜陵冬瓜山铜矿床为例   总被引：7，自引：0，他引：7  

凌其聪  刘丛强 《矿物学报》2003,23(1):37-44

应用改善了的质量平衡方程研究冬瓜山层控夕卡岩型铜矿床成矿系统的元素活动性及质量迁移，结果表明：系统中Zr,Hf,Y和Nb为不活动元素，其余均为活动元素。主量元素中仅CaO为迁出组分，其质量迁移量为84％，其余均为带入组分，带入量最大的SiO2的质量迁移量高达2384％；稀土元素均为带入组分，其中，中稀土较轻稀土和重稀土的活动性更强；其它微量元素中，带入序列由强到弱为：Cr→Ta→Sn→Th，迁出序列由强至弱依次为：U→Sb→Ni—Sr→Ba→Bb→Co→W；成矿元素Cu和Ag为带入组分，其中Cu的带入量最大，质量迁移量高达1200％。本文还得出两点具普适性认识：①稀土元素较其它微量元素对体系条件的变化更为敏感，且往往表现出明显的规律性变化，能更好地示踪地质地球化学过程。②不同元素在不同体系中的行为特征差异极大，仅凭经验判定某一元素为不活动元素往往不可靠。因此，在开展质量平衡研究时，首先采用适当方法确认体系的不活动元素是一项不可或缺的前提工作。  相似文献   

Scaling effects on modeled surface energy-balance components using the NOAH-OSU land surface model   总被引：3，自引：0，他引：3  

V. Sridhar  Ronald L. Elliott  Fei Chen 《Journal of Hydrology》2003,280(1-4):105-123

As surface exchange processes are highly non-linear and heterogeneous in space and time, it is important to know the appropriate scale for the reasonable prediction of these exchange processes. For example, the explicit representation of surface variability has been vital in predicting mesoscale weather events such as late-afternoon thunderstorms initiated by latent heat exchanges in mid-latitude regions of the continental United States. This study was undertaken to examine the effects of different spatial scales of input data on modeled fluxes, so as to better understand the resolution needed for accurate modeling. A statistical procedure was followed to select two cells from the Southern Great Plains 1997 hydrology experiment region, each 20 km×20 km, representing the most homogeneous and the most heterogeneous surface conditions (based on soil and vegetation) within the study region. The NOAH-OSU (Oregon State University) Land Surface Model (LSM) was employed to estimate surface energy fluxes. Three scales of study (200 m, 2 and 20 km) were considered in order to investigate the impacts of the aggregation of input data, especially soil and vegetation inputs, on the model output. Model results of net radiation and latent, sensible and ground heat fluxes were compared for the three scales. For the heterogeneous area, the model output at the 20-km resolution showed some differences when compared with the 200-m and 2-km resolutions. This was more pronounced in latent heat (12% decrease), sensible heat (22% increase), and ground heat flux (44% increase) estimation than in net radiation. The scaling effects were much less for the relatively homogeneous land area with 5% increase in sensible heat and 4% decrease in ground heat flux estimation. All of the model outputs for the 2- and 20-km resolutions were in close agreement. The results suggested that, for this study region, soils and vegetation input resolution of about 2 km should be chosen for realistic modeling of surface exchange processes. This resolution was sufficient to capture the effects of sub-grid scale heterogeneity, while avoiding the data and computational difficulties associated with higher spatial resolutions.  相似文献   

两城水源地喀斯特水资源评价     

王延恩  李念国  韩汝钊 《地下水》2003,25(2):103-105

两城水源地具有较丰富的喀斯特水，根据长期观测资料，充分考虑水资源的各种补给和开采条件，应用水均衡原理，对其水资源量进行定量评价，获得允许可开采量，为工农业供水提供可靠依据。  相似文献   

应用RMi法估算岩体变形模量     

王亮清  胡静  章广成 《水文地质工程地质》2003,(Z1)

RMR法与Q法是国内外八、九十年代岩体质量和参数估算的常用方法,然而RMR法和Q法对质量较差的岩体不太实用,而RMi法是一种既适用于软岩又适用于硬岩的岩体质量评价和参数估算方法。本文在介绍RMi法基本原理的基础上,对贵州省鱼简河水库坝基岩体变形模量进行确定。  相似文献   

Compositional Geometry and Mass Conservation   总被引：1，自引：0，他引：1  

Robert F. Shurtz 《Mathematical Geology》2003,35(8):927-937

A geometrical structure is imposed on compositional data by physical and chemical laws, principally mass conservation. Therefore, statistical or mathematical investigation of possible relations between data values and such laws must be consistent with this structure. This demands that geometrical concepts, such as points that specify both mass and composition in linear space, and lines in projective space that specify composition only, be clearly defined and consistent with mass conservation. Mass thus becomes the norm in composition space in place of the Euclidean norm of ordinary space. Coordinate transformations inconsistent with this geometry are accordingly unnatural and misleading. They are also unnecessary because correlation arising from the constant mass presents no unusual difficulty in the analysis of the underlying quadratic form.  相似文献   

Use of accessory zircon for the quantification of volume changes in ductile shear zones cutting plutonic rocks     

Robert Sturm  Hans Peter Steyrer 《Chemie der Erde / Geochemistry》2003,63(1):31-54

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陆面过程模式的改进及其检验   总被引：11，自引：0，他引：11  

周锁铨  代刊  陈涛  屠其璞  陈万隆 《气象学报》2003,61(3):275-290

文中对陆面过程模式 (BATS)进行了改进 ,改进后的模式能较好地模拟地表物理量的年、季和日变化 ,它有两方面的特点 :采用热扩散方程模拟 7层土壤温度 ,模拟的温度可与实测值进行比较 ;在BATS的地表径流方案中 ,考虑了空间不均匀性的一般地表径流 (GVIC)过程 ,研究结果表明 :⑴模式能很好地模拟各层土壤温度的年、季和日变化。冬季土壤温度下层高于上层 ,而在夏季上层高于下层 ,这种上下层温度的转换时间大约在 4和 10月份 ,这与实测土壤温度的年变化非常一致。较为准确地模拟了各层土壤温度日变化的时滞效应。⑵用南京和武汉站的资料 ,将BATS地表径流方案模拟的地表水分分量与GVIC方案进行比较 ,BATS地表径流方案模拟的地表水分分量 ,与总水量的平衡相差较大 ,而GVIC模拟的效果相对较好 ,地表总水量基本上与降水总量达到了平衡  相似文献   

Quantitative Evaluation of Water Deposited By Dew on Monuments   总被引：1，自引：0，他引：1  

Dario Camuffo  Roberta Giorio 《Boundary-Layer Meteorology》2003,107(3):655-672

Samples of White and Green Carrara marble, and three types oflimestone and brick exposed in the field vertically and horizontally were used to evaluate condensationon monuments during clear sky nights. Experiments in a simulation chamber under controlledconditions led to a general equation for the actual amount of water deposited on a surface by dew.This is determined by: How much and for how long the surface temperature falls below the dew point,the moisture content in the air and the ventilation. On clear nights, the condensation on buildingstructures facing the sky may reach some 0.2 kg m^-2 (or 0.2 mm), whereas condensation on verticalsurfaces is very small. Computation of the seasonal trend of night-time condensationshowed that the maximum amount of water condensed per night occurs in the autumn, with the moreabundant concentration of moisture in the air. The total amount of water condensed per month isfound to be a maximum in the summer-autumn period. Morning condensationfor the thermal inertia of monuments is also relevant, and has been calculated to reach the same order of magnitude as thenocturnal dew. A detailed analysis of the temperature and mixing ratio profiles near a condensingsurface has shown two different situations. In still air, the two profiles follow an exponentiallaw and the thermal and the concentration layers lie within a few tens of millimetres. Inthe presence of turbulence, the thickness of these two layers is dramatically reduced. In still air, infront of a vertical, chilly surface, the deposition rate of air pollutants by thermophoresis and/orStefan flow is increased by 3 or 4 times in comparison with a horizontal surface. In the presence ofturbulence, the thickness of the thermal and concentration layers was dramatically reduced, makingthese two kinds of deposition much faster.  相似文献   

The climatic impacts of land surface change and carbon management, and the implications for climate-change mitigation policy   总被引：4，自引：0，他引：4  

Gregg Marland  Roger A. Pielke Sr. 《Climate Policy》2003,3(2):149-157

Strategies to mitigate anthropogenic climate change recognize that carbon sequestration in the terrestrial biosphere can reduce the build-up of carbon dioxide in the Earth’s atmosphere. However, climate mitigation policies do not generally incorporate the effects of these changes in the land surface on the surface albedo, the fluxes of sensible and latent heat to the atmosphere, and the distribution of energy within the climate system. Changes in these components of the surface energy budget can affect the local, regional, and global climate. Given the goal of mitigating climate change, it is important to consider all of the effects of changes in terrestrial vegetation and to work toward a better understanding of the full climate system. Acknowledging the importance of land surface change as a component of climate change makes it more challenging to create a system of credits and debits wherein emission or sequestration of carbon in the biosphere is equated with emission of carbon from fossil fuels. Recognition of the complexity of human-caused changes in climate does not, however, weaken the importance of actions that would seek to minimize our disturbance of the Earth’s environmental system and that would reduce societal and ecological vulnerability to environmental change and variability.  相似文献