镧-氨基酸络合物对球等鞭金藻的影响   总被引：3，自引：0，他引：3  

辛福言  曲克明  袁有宪 《海洋学报》1998,20(5):65-69

本文首次研究了镧-脯氨酸和镧-苯丙氨酸络合物对球等鞭金藻(Isochrysis galbana)的影响,结果表明,两种络合物对球等鞭金藻细胞繁殖及叶绿素的合成有明显的促进作用,浓度范围为5-20mg/dm3时,至第6天细胞数分别提高10.8%～17.2%,11.5%-20.5%(P<0.05);叶绿素浓度分别提高31.7%-37.5%,44.7%～48.4%(P<0.05),其中以浓度为10mg/dm3的实验组最高。镧的氨基酸络合物对球等鞭金藻的作用效果与镧相比是等同的。  相似文献   

Structural and kinematic analysis of the Corredoiras detachment: evidence for early Variscan synconvergent extension in the Ordenes Complex, NW Spain   总被引：1，自引：1，他引：0  

F. Díaz García  J. R. Martínez Catalán  R. Arenas  P. González Cuadra 《International Journal of Earth Sciences》1999,88(2):337-351

 An important detachment is described in the allochthonous Ordenes Complex, in the NW Iberian Massif, and its meaning is related to the kinematics of contemporaneous convergent structures. The Corredoiras Detachment (CD) separates a hangingwall unit, characterised by a medium-pressure metamorphic gradient, from a footwall high-pressure and high-temperature unit and an underlying ophiolitic unit. An associated ductile shear zone, nearly 2000 m thick, developed in the lower part of the hangingwall unit, where the Corredoiras Orthogneiss, a Lower Ordovician metagranite, was progressively transformed into augengneisses, mylonitic and ultramylonitic gneisses. The attitude of the stretching and mineral lineation in the mylonites varies due to late refolding at map scale, but the sense of movement can be estimated, being roughly top to the SE. According to crosscutting relationships, the CD developed subsequent to the thrusting of the high-pressure/high-temperature unit onto the ophiolitic unit, and prior to younger extensional detachments, upright folding and strike-slip tectonics. The geometric relationships of the CD with the previous structures in the footwall unit, the subtractive character of the metamorphic gap between its hangingwall and footwall, and the available isotopic data suggest that the CD is an early Variscan, ductile extensional detachment, the movement of which was roughly simultaneous with the onset of thrusting of the allochthonous complexes over their relative autochthon. Received: 17 November 1998 / Accepted: 4 April 1999  相似文献   

Adsorption of Au(III) and Au(I) complexes on δ-MnO2     

Yong Ran  Jiamo Fu  R. J. Gilkes  R. W. Rate 《中国科学D辑(英文版)》1999,42(2):172-181

The sorption of AuCl₄ ⁻,AuCl₂ ⁻ and Au(S₂O₃)^3- on δ-MnO₂ was investigated at pH2–11.6, 0.01 mol/L and 0.1 mol/L NaNO₃ solutions. At pH 4 in two electrolyte strength solutions, Au sorption densities on δ-MnO₂ are 0.18–0.21 and 0.28μmoL/m² for AuCl₄ ⁻ and Au(S₂O₃)₂ ^3-, respectively, and the Au surface coverage is approximate to or lower than 1%. This adsorption of the two Au complexes decreases as the solution pH increases, which conforms to the sorption regularity of the anion on δ-MnO₂. The Au sorption decreases in the sequence of Au(S₂O₃)₂ ^3- >AuCl₄ ⁻ >AuC1₂ ⁻. The intrinsic equilibrium constants (logK ^int) of the three Au complexes are 1.17–2.7, much higher than those of Cu and Cd. The hydrolysis products of AuCl₄ ^- are preferentially adsorbed by δ-MnO₂ and the inner-sphere Au-surface complexes are formed on the surface. Project supported by the National Studying-abroad Foundation, the National Natural Science Foundation of China (Grant No. 49573200) and the Australian Mining Industry.  相似文献   

A Review of Study on Fe-C Interaction and Their Adsorption Properties to Soil Heavy Metal     

Zhao Zhuanjun  Yang Yanyan  Pang Yu  Zhao Lifang  Guan Yuli  Zhang Zhaohu 《地球科学进展》2017,32(8):867-874

Nowadays, the Fe-C coprecipitate mechanism is recognized by more and more scholars and becomes the hot topic in the environmental science. On the basis of discussing the interaction between iron oxide and organic matter, and the adsorption research progress of Fe-C complexes on heavy metals, the immobilization potential of Fe-C complexes on heavy metals in polluted soil were illustrated. The surface properties and physical characterizations of iron oxide are changed regularly with the interaction of organic matter, which lead to the higher adsorption capacity of Fe-C complexes in contrast to single iron oxide. Besides, the influences of pH values, organic matter types and surface properties of iron oxides on the adsorption capacity of Fe-C complexes on heavy metals were discussed. The excellent adsorption performance of Fe-C complexes in certain conditions will provide important theoretical basis for contaminated soil remediation.  相似文献   

Mesozoic collision-related magmatism and crust–mantle interaction along the Anhui segment of the Yangtze River Valley,east-central China     

《International Geology Review》2012,54(14):1559-1575

The middle segment of the Yangtze River Deep Fault Belt, located in the foreland of the Dabie orogen, contains widely exposed volcanic–intrusive complexes that formed during two episodes of magmatism (post-collisional and post-orogenic), reflecting crust–mantle interactions during the Late Jurassic (J₃) to Early Cretaceous (K₁). This article summarizes research on the Mesozoic igneous suites and xenolith suites in the area along the Yangtze River. ‘Post-collisional magmatism’ occurred during lithospheric extension at ～145–130 Ma. Its beginning and end are marked by gabbroic xenoliths and pyroxene cumulates within intrusions at Tongling, and by alkali-rich magmatic rocks. The association includes peraluminous silicic rocks and metaluminous mafic–felsic igneous suites, ranging from medium-K to high-K calc-alkaline to shoshonitic compositions. Taking the Tongling region as an example, quartz monzodiorite yields a sensitive high resolution ion microprobe (SHRIMP) zircon U–Pb age of 139.5 ± 2.9 Ma, and granodiorite yields an age of 135.5 ± 4.4 Ma. These intrusive rocks contain 52.79–66.46 wt.% SiO₂, 13.12–17.73 wt.% Al₂O₃, 1.37–4.62 wt.% MgO, 3.86–6.84 wt.% FeO^T, and 4.71–7.87 wt.% total alkalis (Na₂O?+?K₂O). ACNK values range from 0.62 to 1.20, and ANK values from 1.45 to 3.48. ‘Post-orogenic magmatism’ occurred during lithospheric delamination at ～130–120 Ma. The start of magmatism was marked by the formation of gabbro containing spinel lherzolite xenoliths in the Nanjing–Wuhu Basin (NWB), and its end was marked by the generation of feldspathoid phenocryst-bearing phonolite in the NWB and the Lujiang–Zongyang Basin (LZB), respectively. The association that formed during this episode ranges from alkaline to peralkaline. Taking the Niangniangshan Formation in the NWB as an example, the Nosite phonolite yields a whole-rock monomineral Rb–Sr isochron age of 120 ± 9 Ma, and contains 49.92–60.09 wt.% SiO₂, 17.67–20.65 wt.% Al₂O₃, 0.08–2.45 wt.% MgO, 1.32–6.62 wt.% FeO^T, and 9.24–13.92 wt.% total alkalis (Na₂O?+?K₂O). ACNK values range from 0.72 to 1.24, and ANK values from 1.03 to 1.35.

The two magmatisms correspond to two episodes of crust–mantle interaction. The first involved intensive interaction between middle–lower crust and underplated basaltic magma derived from the upper mantle lithosphere, whereas the second involved minor interaction between the middle–lower crust and basaltic magma derived from the lower lithospheric mantle.  相似文献   

U–Pb zircon ages,geochemical and Sr–Nd–Pb isotopic constraints on the dating and origin of intrusive complexes in the Sulu orogen,eastern China     

《International Geology Review》2012,54(1):61-83

TPost-orogenic intrusive complexes from the Sulu belt of eastern China consist of pyroxene monzonites and dioritic porphyrites. We report new U–Pb zircon ages, geochemical data, and Sr–Nd–Pb isotopic data for these rocks. Laser ablation-inductively coupled plasma-mass spectrometry U–Pb zircon analyses yielded a weighted mean ²⁰⁶Pb/²³⁸U age of 127.4 ± 1.2 Ma for dioritic porphyrites, consistent with crystallization ages (126 Ma) of the associated pyroxene monzonites. The intrusive complexes are characterized by enrichment in light rare earth elements and large ion lithophile elements (i.e. Rb, Ba, Pb, and Th) and depletion in heavy rare earth elements and high field strength elements (i.e. Nb, Ta, P, and Ti), high (⁸⁷Sr/⁸⁶Sr)_i ranging from 0.7083 to 0.7093, low ?_Nd(t) values from ?14.6 to ? 19.2, ²⁰⁶Pb/²⁰⁴Pb = 16.65–17.18, ²⁰⁷Pb/²⁰⁴Pb = 15.33–15.54, and ²⁰⁸Pb/²⁰⁴Pb = 36.83–38.29. Results suggest that these intermediate plutons were derived from different sources. The primary magma-derived pyroxene monzonites resulted from partial melting of enriched mantle hybridized by melts of foundered lower crustal eclogitic materials before magma generation. In contrast, the parental magma of the dioritic porphyrites was derived from partial melting of mafic lower crust beneath the Wulian region induced by the underplating of basaltic magmas. The intrusive complexes may have been generated by subsequent fractionation of clinopyroxene, potassium feldspar, plagioclase, biotite, hornblende, ilmenite, and rutile. Neither was affected by crustal contamination. Combined with previous studies, these findings provide evidence that a Neoproterozoic batholith lies beneath the Wulian region.  相似文献   

A multi-method approach for the study of lanthanum speciation in coastal and estuarine sediments     

Parthasarathi Chakraborty  P.V. Raghunadh BabuV.V. Sarma 《Journal of Geochemical Exploration》2011

Two independent analytical methods (sequential extraction and kinetic extraction methods) were applied in order to understand the distribution and speciation of La in the coastal and estuarine sediments from the central east coast of India. Sequential extraction study revealed that La was primarily present as inert complexes (~ 50–60% of the total La) in all the sediments. Amounts of ~ 20–30% of the total La in all the sediments were found to associate with the total organic carbon (TOC) in the sediments. The dissociation rate constants of La–sediment complexes obtained from kinetic extraction studies revealed that the concentration of thermodynamically weak complexes of La gradually increased with the increasing La/TOC ratio in the sediments.  相似文献   

Structural controls on Quaternary deepwater sedimentation, mud diapirism, and hydrocarbon distribution within the actively evolving Columbus foreland basin, eastern offshore Trinidad     

Emilio Garciacaro  Alejandro Escalona  Paul Mann 《Marine and Petroleum Geology》2011,28(1):149-176

Eastward migration of the Caribbean plate relative to the South American plate has caused lithospheric loading along the northern margin of South America, which is recorded by an 1100-km-long foreland basin which is oldest in the west (Maracaibo basin, 65-55 Ma) and youngest in the east (Columbus basin, eastern offshore Trinidad, 15-0 Ma). The Orinoco River has been the primary source of sediment for the basin since early Miocene. We have integrated approximately 775 km of deep-penetration 2D seismic lines acquired in the area of eastern offshore Trinidad as part of the 2004 “Broadband Ocean-Land Investigations of Venezuela and the Antilles arc Region” (BOLIVAR) project, 8000 km² of shallow industry 3D seismic data, and published industry well data from offshore eastern Trinidad. Active mud diapirism in the Columbus basin is widespread and is related to overthrusting and tectono-sedimentary loading of upper Miocene-lower Pliocene age mud. Analysis of the shallow 3D seismic data reveals the presence of extensive gravity-flow depositional elements on the Columbus basin slope and the deepwater area. These stacked gravity-flow deposits are characterized by mass-transport deposits at the base, turbidite frontal-splay deposits, leveed-channel deposits, and capped by fine-grained condensed-section deposits. Exploration targets in the deepwater area are located towards the center of the Columbus basin, where northeast-trending fault-propagation folds are important Plio-Pleistocene trap-forming elements. Deep basin wells drilled in recent years have proven that turbidites were transported into the deepwater Columbus basin during the Plio-Pleistocene. Analysis of these well results suggests that a deeper oil charge is present within the deepwater Columbus basin area. The primary uncertainty for this variable hydrocarbon system is whether fault or diapiric pathways connect or divert the petroleum charge at depth with shallower reservoir rocks.  相似文献   

江西相山火山-侵入杂岩体锆石SHRIMP定年及其地质意义   总被引：13，自引：2，他引：11  

陈正乐 王 永周永贵  韩凤彬王平安  宫红良邵 飞唐湘生  徐金山 《中国地质》2013,40(1):217-231

采用锆石SHRIMP微区U-Pb测年技术,测定了江西相山铀矿田火山-侵入杂岩的时代。采自于相山西北部的石马山和西部南陂的鹅湖岭组碎斑熔岩的SHRIMP锆石206Pb/238U表面年龄加权平均值分别为(134.6±1.0)Ma(MSWD=1.5)和(134.1±1.0)Ma(MSWD=0.65),可以限定相山第二火山喷发旋回的结束时代为134 Ma;采自于相山北部巴泉和南部浯漳的似斑状花岗岩的SHRIMP锆石206Pb/238U表面年龄加权平均值为(133.3±0.8)Ma(MSWD=0.82)和(134.7±0.9)Ma(MSWD=1.08),与碎斑熔岩的年龄在误差范围内基本一致,结合野外地质事实和前人的地球化学测试分析结果,确认碎斑熔岩和似斑状花岗岩属于同期、同来源的火山喷发-侵入的产物,形成于134～133 Ma。书堂钻孔ZK111A-1中打鼓顶组顶部流纹英安岩的锆石206Pb/238U表面年龄加权平均值为(141.6±1.7)Ma(MSWD=0.9),表明第一旋回火山喷发的时代应结束于142 Ma,大部分属于晚侏罗世火山活动。岗上英钻孔岩心中石英二长花岗斑岩的锆石206Pb/238U表面年龄加权平均值为(136.4±1.0)Ma(MSWD=1.7),如意亭剖面第二采石场流纹质英安斑岩的锆石206Pb/238U表面年龄加权平均值为(137.4±1.7)Ma(MSWD=1.11);推测这两者应属于早晚两期火山喷发旋回间隔期的次火山-侵入岩,进而限定136～137 Ma为相山两期火山喷发旋回的间隔时期。综合前人资料和本文测试分析结果,可将相山火山喷发第二旋回鹅湖岭组的时代限定为136～133 Ma,应属于早白垩世的火山活动,进而认为将相山地区"鹅湖岭组"的地层时代划归为早白垩世较为合适。  相似文献   

Cenozoic geodynamic evolution of the Andaman–Sumatra subduction margin: Current understanding     

Partha P.  Chakraborty  Prosanta K.  Khan 《Island Arc》2009,18(1):184-200

The Andaman–Sumatra margin displays a unique set‐up of extensional subduction–accretion complexes, which are the Java Trench, a tectonic (outer arc) prism, a sliver plate, a forearc, oceanic rises, inner‐arc volcanoes, and an extensional back‐arc with active spreading. Existing knowledge is reviewed in this paper, and some new data on the surface and subsurface signatures for operative geotectonics of this margin is analyzed. Subduction‐related deformation along the trench has been operating either continuously or intermittently since the Cretaceous. The oblique subduction has initiated strike–slip motion in the northern Sumatra–Andaman sector, and has formed a sliver plate between the subduction zone and a complex, right‐lateral fault system. The sliver fault, initiated in the Eocene, extended through the outer‐arc ridge offshore from Sumatra, and continued through the Andaman Sea connecting the Sagaing Fault in the north. Dominance of regional plate dynamics over simple subduction‐related accretionary processes led to the development and evolution of sedimentary basins of widely varied tectonic character along this margin. A number of north–south‐trending dismembered ophiolite slices of Cretaceous age, occurring at different structural levels with Eocene trench‐slope sediments, were uplifted and emplaced by a series of east‐dipping thrusts to shape the outer‐arc prism. North–south and east–west strike–slip faults controlled the subsidence, resulting in the development of a forearc basins and record Oligocene to Miocene–Pliocene sedimentation within mixed siliciclastic–carbonate systems. The opening of the Andaman Sea back‐arc occurred in two phases: an early (～11 Ma) stretching and rifting, followed by spreading since 4–5 Ma. The history of inner‐arc volcanic activity in the Andaman region extends to the early Miocene, and since the Miocene arc volcanism has been associated with an evolution from felsic to basaltic composition.  相似文献