Energy transfer among Pb, Ce and Mn in fluorescent calcite from Kuerle, Xinjiang, China     

Aierken Sidike  X.-M. Wang  Alifu Sawuti  H.-J. Zhu  I. Kusachi  N. Yamashita 《Physics and Chemistry of Minerals》2006,33(8-9):559-566

Natural calcite from Kuerle, Xinjiang, China, shows orange-red fluorescence when exposed to short-wave ultraviolet (UV) light (Hg 253.7 nm). Photoluminescence (PL) emission and excitation spectra of the calcite are observed at room temperature in detail. The PL emission spectrum under 208 nm excitation consists of three bands: two UV bands at 325 and 355 nm and an orange-red band at 620 nm. The three bands are ascribed to Pb²⁺, Ce³⁺ and Mn²⁺, respectively, as activators. The Pb²⁺ excitation band is observed at 243 nm, and the Ce³⁺ excitation band at 295 nm. The Pb²⁺ excitation band is also observed by monitoring the Ce³⁺ fluorescence, and the Pb²⁺ and Ce³⁺ excitation bands, in addition to six Mn²⁺ excitation bands, are also observed by monitoring the Mn²⁺ fluorescence. These indicate that four types of the energy transfer can occur in calcite through the following processes: (1) Pb²⁺ → Ce³⁺, (2) Pb²⁺ → Mn²⁺, (3) Ce³⁺ → Mn²⁺ and (4) Pb²⁺ → Ce³⁺ → Mn²⁺.  相似文献   

Superdense CO2 inclusions in Cretaceous quartz–stibnite veins hosted in low-grade Variscan basement of the Western Carpathians, Slovakia     

Márian Urban  Rainer Thomas  Vratislav Hurai  Patrik Koneèný  Martin Chovan 《Mineralium Deposita》2006,40(8):867-873

CO₂ inclusions with density up to 1,197 kg m⁻³ occur in quartz–stibnite veins hosted in the low-grade Palaeozoic basement of the Gemericum tectonic unit in the Western Carpathians. Raman microanalysis corroborated CO₂ as dominant gas species accompanied by small amounts of nitrogen (<7.3 mol%) and methane (<2.5 mol%). The superdense CO₂ phase exsolved from an aqueous bulk fluid at temperatures of 183–237°C and pressures between 1.6 and 3.5 kbar, possibly up to 4.5 kbar. Low thermal gradients (∼12–13°C km⁻¹) and the CO₂–CH₄–N₂ fluid composition rule out a genetic link with the subjacent Permian granites and indicate an external, either metamorphogenic (oxidation of siderite, dedolomitization) or lower crustal/mantle, source of the ore-forming fluids.According to microprobe U–Pb–Th dating of monazite, the stibnite-bearing veins formed during early Cretaceous thrusting of the Gemeric basement over the adjacent Veporic unit. The 15- to 18-km depth of burial estimated from the fluid inclusion trapping PT parameters indicates a 8- to 11-km-thick Upper Palaeozoic–Jurassic accretionary complex overlying the Gemeric basement and its Permo-Triassic autochthonous cover.  相似文献   

Decarbonation reaction of magnesite in subducting slabs at the lower mantle     

N. Takafuji  K. Fujino  T. Nagai  Y. Seto  D. Hamane 《Physics and Chemistry of Minerals》2006,33(10):651-654

High-pressure and temperature experiments (28–62 GPa, and 1,490–2,000 K, corresponding to approximately 770–1,500 km depth in the mantle) have been conducted on a MgCO₃ + SiO₂ mixture using a laser-heated diamond anvil cell combined with analytical transmission electron microscope observation of the product phases to constrain the fate of carbonates carried on the subducting basalt into the lower mantle. At these conditions, the decarbonation reaction MgCO₃ (magnesite) + SiO₂ (stishovite) → MgSiO₃ (perovskite) + CO₂ (solid) has been recognized. This indicates that above reaction takes place as a candidate for decarbonation of the carbonated subducting mid ocean ridge basalts in the Earth’s lower mantle.  相似文献   

光催化降解乐果的动力学研究     

梁喜珍  黄国林  周跃明  李香枝 《华东地质学院学报》2006,29(1):80-83

采用30 W石英紫外灯作为光源,研究了乐果在二氧化钛悬浮体系中光催化降解反应的动力学规律。考察了乐果起始浓度、TiO2用量、溶液pH值及温度对乐果光催化降解速率的影响,结果表明,乐果光催化降解符合表观零级动力学规律。由于速率常数k与乐果起始浓度有关,表明乐果光催化降解反应不是一个简单的零级反应。  相似文献   

邻苯二酚螯合树脂的合成及水样中铝的测定     

于涛  耿伟  杨枝  曹维鹏 《华东地质学院学报》2006,29(3):265-268

合成并表征了新螯合树脂———邻苯二酚螯合树脂(XAD-2-Catechol),研究了XAD-2-Catechol吸附铝的特性和茜素红-铝的显色反应,在pH4.5的HAc-NaAc缓冲介质中,茜素红和铝(Ⅲ)反应生成红色络合物,λm ax=500 nm,铝的含量在0-50μg/25 mL内符合比耳定律。建立了邻苯二酚螯合树脂分离/富集-茜素红分光光度法测定天然水样中铝的新方法,对水样中铝形态进行测定,结果满意。  相似文献   

济阳坳陷CO0_2气藏同位素地球化学特征及成因     

林治家  陈衍景  黄智龙  申宝剑 《矿物岩石地球化学通报》2006,(3)

济阳坳陷CO2气藏主要发育在高青-平南深断裂中南段和阳信次级凹陷西北缘及商店火山岩穹隆构造内。气藏中CO2气体浓度为69%~97%,δ13CCO2值为-5.67‰~-3.35‰,CH4/3He值为(1.01~5.65)×108,3He/4He值为(2.80~4.49)×10-6,即R/Ra为2.00~3.21,40Ar/36Ar值为317~1791,CO2/3He值为(0.25~2.61)×109。以上地球化学数据表明,济阳坳陷气藏中CO2主要来源于地幔,且幔源CO2在成藏过程中有损失,或者有壳源CO2的加入,特别是部分碳酸盐岩变质成因CO2的加入。在对CO2气来源定性分析的基础上,还需要在各来源的定量区分和CO2气藏的成藏及其与岩浆活动的时空匹配关系等方面作进一步的研究。  相似文献   

二维地震观测系统合理性的论证方法     

SUN Xiao-jie LI Chao-lin WANG Li-bin REN Ri-chun LI Hai-yan ZHUANG Yi-ming LIU Ying-xin SUN Ke .Daqing Petroleum Institute  Daqing  Heilongjiang  China .Coalfield Geological  Geophysical Exploration Company of Jilin Province  Changchun  China .Coal Field Geology Bureun of Jilin Province  Changchun  China 《吉林大学学报(地球科学版)》2006,(Z2)

已知勘查区深度范围前提下,最大炮检X和道间距ΔX,不可以太大也不可以太小,施工前能够计算出它的允许值范围。  相似文献   

政府办公自动化系统建设和应用浅谈     

冯伊宁 《国土资源信息化》2005,(2):42-44,33

本文简要地介绍了办公自动化的发展过程,分析了其常用的功能、特点,以及内容分类,论述了目前办公自动化系统的技术支撑和实现,并指出政府办公自动化系统在开发和应用中存在的问题和解决思路。对系统的推广使用具有一定的参考意义。  相似文献   

Practical Research of IKONOS-2 Geopositioning and Its Accuracy in Tibet of China     

CHENChujiang LIDeren ZHUQing 《地球空间信息科学学报》2005,8(1):33-38

This paper presents the studies of the refining of IKONOS-2 RPC, the transform of the datum, the mode of the control point distribution and the method of IKONOS stereo triangulation, so that IKONOS imagery can be used to collect the precise geospatial data and produce the large scale map. The transform between the IKONOS-2 image space and the national coordinate system based on the RPC have been developed, and the results of block adjustment with various control schemes in a practical project near Himalayas have been examined and analysed. The encouraging results of high positioning accuracy have been obtained.  相似文献   

二维电子地图和三维虚拟场景的互响应     

苗青 《四川测绘》2005,28(3):103-105

本文提出了基于二维电子地图与三维虚拟场景之间相互响应的思想来克服它们各自的局限性.简要的描述了相互响应的原理、表现形式、实现流程及实现方法.最后提出了一些结论和展望.  相似文献