PM10 and Pb evolution in an industrial area of the Mediterranean basin     

A.?B.?Vicente  M.?M.?JordánEmail author  S.?Pallarés  T.?Sanfeliu 《Environmental Geology》2007,51(8):1413-1424

The study area is highly industrialized, with businesses involved in the non-metal mineral products sector and ceramic industries (colors, frits and enamel manufacturing) standing out. Air quality evaluation was performed regarding atmospheric particles (PM10 fraction) and Pb in a Spanish coastal area during 2001 and 2002 in order to compare these values with other areas in the Mediterranean basin. Once the samples were collected, their PM10 fraction concentration levels were determined gravimetrically. A Pb analysis in air pollution filters was carried out by ICP-MS. The seasonal and weekly variabilities of these contaminants were also studied, with the objective of being able to explain their origin and thus minimize their possible damaging effects. A similar evolution of PM10 and Pb was observed in both years of the study. Higher PM10 concentrations have been detected during the months of June and July, lower values between March–May, August and October–December, and intermediate values in January and February. A similar tendency has been observed by other authors in European industrialized cities. Regarding Pb, the monthly mean remains constant during the entire year. In the study area, Pb represents 0.6% as a mean of the total PM10 mass, with a variation range between 0.1 and 5.1%. The major crystalline phases in PM10 were quartz, calcite, dolomite, illite, kaolinite and feldspars.  相似文献   

Petrography and mineralogy of new lunar meteorite MIL090036     

XIE Lanfang  CHEN Hongyi  MIAO Bingkui  XIA Zhipeng  YAO Jie 《极地研究(英文版)》2014,(1):17-25

MIL090036 is a previously unknown meteorite （a feldspathic lunar breccia） that was discovered in Antarctica. The detailed petrography and mineralogy of this meteorite forms the subject of this paper. It has a typical clastic texture that consists of various types of rock debris （e.g. anorthosite, gabbroic anorthosite, gabbro, regolith breccia, troctolite, microporphyritic crystalline impact melt and compound clasts）, mineral crystal fragments （e.g. pyroxenes, plagioclase, olivine and ilmenite） and feldspathic glass clasts. The ifne-grained recrystallized minerals and mineral clasts are cemented together in a glassy groundmass. The anorthite content of plagioclase in the gabbro （An81-83） and anorthosite （An88-93） both have relatively low calcium content compared to those from other breccias （An90-98）. The pyroxene composition （Fs12-35 Wo3-44 En22-79） in the rock debris, crystal mineral clasts and anorthositic glass clasts are relatively iron-deifcient compared to those from gabbro debris with melt glass （Fs37-65 Wo10-29 En21-49） and groundmass （Fs18-69 Wo3-45 En14-50）. In contrast, the pyroxene grains in the gabbroic anorthosite display a narrow compositional range （Fs24-27 Wo7-14 En59-69）. Olivine grains in mineral fragments and the groundmass have a wider compositional range （Fo57-79） than those in the rock debris （Fo67-77）. The Fe/Mn ratio in olivine is in the range of 47 to 83 （average 76） and 76 to 112 （average 73） in pyroxenes, and hence classify within the lunar ifeld. The characteristics of texture, mineral assemblage and compositions suggest that MIL090036 possibly originated from a region beyond that of the Apollo and Luna samples. Further study of MIL090036 is therefore likely to lead to a better understanding of the geological processes on the Moon and the chemical composition of the lunar crust.  相似文献   

Geochemistry and origin of the Cretaceous sedimentary kaolin deposits,Red Sea,Egypt     

Hassan M. Baioumy 《Chemie der Erde / Geochemistry》2014

This work reports, for the first time, the mineralogical and geochemical characteristics of the Cretaceous sedimentary kaolin deposits in the Red Sea area, Egypt and sheds the light on their source. Mineralogical and geochemical analyses of both bulk deposits and the sand and clay fractions of these deposits indicated that they are composed of kaolinite (average of 75 wt.%) and quartz (average of 22 wt.%). Traces of anatase (average of 1 wt.%) were identified in all kaolin samples, while traces of halite (average of 2 wt.%) and hematite (average of 1 wt.%) were reported in the majority of the analyzed samples. The clay fractions show relatively high contents of TiO₂ (average of 2.1%), Ni (average of 103 ppm), Nb (average of 98 ppm), Y (average of 67 ppm), and Zr (average of 630 ppm). Sum of the rare earth elements (ΣREE) in the clay fractions varies between 193 and 352 ppm. Chondrite-normalized REE patterns show enrichment of the light REE relative to the heavy REE ((La/Yb)_N = 9) and negative Eu anomaly (Eu*/Eu = 0.67).  相似文献   

Detection and discrimination of sulfate minerals using reflectance spectroscopy   总被引：1，自引：0，他引：1  

Edward A. Cloutis  Frank C. Hawthorne  Katherine Krenn  Dionne Marcino  Johnathon Strong  Diana L. Blaney  Faith Vilas 《Icarus》2006,184(1):121-157

A suite of sulfate minerals were characterized spectrally, compositionally, and structurally in order to develop spectral reflectance-compositional-structural relations for this group of minerals. Sulfates exhibit diverse spectral properties, and absorption-band assignments have been developed for the 0.3-26 μm range. Sulfate absorption features can be related to the presence of transition elements, OH, H₂O, and SO₄ groups. The number, wavelength position, and intensity of these bands are a function of both composition and structure. Cation substitutions can affect the wavelength positions of all major absorption bands. Hydroxo-bridged Fe³⁺ results in absorption bands in the 0.43, 0.5, and 0.9 μm regions, while the presence of Fe²⁺ results in absorption features in the 0.9-1.2 μm interval. Fundamental SO bending and stretching vibration absorption bands occur in the 8-10, 13-18, and 19-24 μm regions (1000-1250, 550-770, and 420-530 cm⁻¹). The most intense combinations and overtones of these fundamentals are found in the 4-5 μm (2000-2500 cm⁻¹) region. Absorption features seen in the 1.7-1.85 μm interval are attributable to HOH/OH bending and translation/rotation combinations, while bands in the 2.1-2.7 μm regions can be attributed to H₂O- and OH-combinations as well as overtones of SO bending fundamentals. OH- and H₂O-bearing sulfate spectra are fundamentally different from each other at wavelengths below ∼6 μm. Changes in H₂O/OH content can shift SO band positions due to change in bond lengths and structural rearrangement. Differences in absorption band wavelength positions enable discrimination of all the sulfate minerals used in this study in a number of wavelength intervals. Of the major absorption band regions, the 4-5 μm region seems best for identifying and discriminating sulfates in the presence of other major rock-forming minerals.  相似文献   

Investigation on mineralogy,geochemistry and fluid inclusions of the Goushti hydrothermal magnetite deposit,Fars Province,SW Iran: A comparison with IOCGs     

《Ore Geology Reviews》2017

The Goushti iron deposit from Dehbid area located in the Sanandaj-Sirjan metamorphic Belt (SSB), SW Iran is hosted by the Early Mesozoic silicified dolomite. Mineralized zones are lithostructurally controlled and oriented NW-SE parallel to the Zagros Orogenic Belt (ZOB). Magnetite, the major ore mineral, occurs as open space fillings and is accompanied by the secondary mineral phases hematite, goethite and martite. Gangue minerals mainly include quartz, dolomite and K-feldspar are associated with minor hydrosilicates. Calc-silicates such as wollastonite and diopside, minerals typical of skarns, are virtually absent from the ore zones. Fe₂O₃ content in the mineralized zones varies in the range of 38–75 wt%. The concentrations of Au, Cu, P, Ti, Cr and V as well as Co/Ni, Cr/V, (LREE)/(HREE), Eu/Sm and La/Lu values and Eu-Ce anomalies of the studied ores indicate that the Goushti deposit is a hydrothermal magnetite type. The subvolcanic rhyolite and basalt in this area are regarded as the source of iron and heat in the mineralizing system. The fluid inclusion data showed that magnetite deposited from the ore-bearing fluid with salinities 1–7 wt% NaCl equivalent at temperatures of 130–200 °C. A decrease in temperature and pressure, supplemented by fluid mixing, is the major controlling factor in iron oxide precipitation. The field relationships and mineralogical–geochemical characteristics of iron ores indicate that the Goushti hydrothermal deposit could not be classified as a member of the IOCG (Iron Oxide-Copper-Gold) deposits.  相似文献   

川西义敦岛弧中生代典型花岗岩体矿物学、地球化学特征及岩浆来源探讨   总被引：2，自引：0，他引：2  

王楠  吴才来  秦海鹏 《地质论评》2017,63(4):981-1000

义敦岛弧是位于松潘—甘孜褶皱带和羌塘地体之间的三叠纪火山岛弧。稻城岩体和海子山岩体分别为义敦岛弧上出露的晚三叠世和白垩纪花岗质岩体。结合岩石地球化学,以及偏光显微镜和电子探针(EPMA)、扫描电镜(SEM)对上述岩体进行了系统的矿物学研究,结果表明:两个岩体的主要造岩矿物为斜长石(中长石—更长石),钾长石(正长石)、石英和黑云母(铁叶云母—铁质黑云母),副矿物为锆石、榍石、磁铁矿和磷灰石等;黑云母的成分表明两个岩体的源区均为壳幔混源。稻城岩体属高钾钙碱性系列,具过铝质特征的花岗岩,海子山岩体为高钾钙碱性—钾玄岩系列,同样具过铝质特征。根据锆元素饱和浓度温度计和稀土元素饱和浓度温度计对两个岩体进行了温度限定,稻城岩体岩浆形成的平均上限温度为783℃,海子山岩体岩浆形成时的平均上限温度为844℃。结合前人研究结果,笔者等认为稻城岩体为高分异I型花岗岩,可能为与扬子克拉通有关的晚古元古代至早中元古代的下地壳物质,在甘孜—理塘洋向西俯冲和闭合之后的弧—陆同碰撞背景下,因幔源岩浆的底侵作用而发生部分熔融,同时伴有少量的亏损地幔成分加入,因密度上升至中上—上地壳深度侵位,并且侵位后经历了快速的冷却过程,在侏罗纪之初冷却至300℃以下;海子山岩体为与俯冲有关的造山后伸展环境下形成的白垩纪A2型花岗岩,岩浆来源同样为地壳物质伴有少量地幔物质混合而成,且在地壳中侵位深度较浅,之后经历快速的冷却过程。  相似文献   

滇西北铜厂沟Mo-Cu矿床成矿流体和成矿物质来源:矽卡岩矿物学与稳定同位素证据   总被引：4，自引：1，他引：3  

高雪  孟健寅 《岩石学报》2017,33(7):2161-2174

义敦地体位于三江特提斯成矿域中北段,晚三叠世和晚白垩世斑岩-矽卡岩型Mo-Cu多金属成矿作用强烈。铜厂沟Mo-Cu矿床位于义敦地体最南端,是近年来该区新探明的Mo-Cu矿床之一,已探明资源量142.5Mt。矽卡岩在铜厂沟矿区广泛出露,是该矿区最主要的赋矿岩石。根据矿物组合及共生关系,可将矽卡岩划分为石榴子石矽卡岩、透辉石矽卡岩和透闪石矽卡岩三种类型。通过详细的地质填图和钻孔岩心编录,发现铜厂沟矿区矽卡岩矿物组合受花岗闪长斑岩体与大理岩空间分布的控制:(1)由大理岩向外依次发育透辉石矽卡岩→透闪石矽卡岩→石榴子石矽卡岩;(2)由浅至深,石榴子石粒度逐渐变大;③矿化与透闪石、绿帘石等退化蚀变矿物密切相关,矿体多形成于外接触带。矽卡岩中最主要的矿物是石榴子石,多呈自形粒状或粒状集合体产出,颜色较深,均质性,以钙铝榴石为主(62.2%~78.3%),其次为钙铁榴石(16.7%~34.2%),少量锰铝榴石、铁铝榴石和镁铝榴石,属于钙铝榴石-钙铁榴石固溶体系列(Gro62-78And17-34Spe+Pyr+Alm2-6)。石榴子石Fe~(2+)/Fe~(3+)比值变化范围为0.00~0.20,平均值为0.06,指示石榴子石形成于酸性的氧化环境。石榴子石的δ~(18)OSMOW变化范围为5.2‰~9.5‰,反映矽卡岩可能直接继承斑岩体的氧同位素组成;金属硫化物具有较为均一的S-Pb同位素范围(δ~(34)S(CDT)=-0.7‰~1.4‰;~(206)Pb/~(204)Pb=18.332~18.694,~(208)Pb/~(204)Pb=38.454~39.088,~(207)Pb/~(204)Pb=15.588~15.663),表明成矿流体和成矿物质均来源于壳源的长英质岩浆。  相似文献   

Mineralogical signatures and sources of recent sediment in a large tropical lake     

Jorge Feliciano Ontiveros-Cuadras  Ana Carolina Ruiz-Fernández  Joan-Albert Sanchez-Cabeza  Libia Hascibe Pérez-Bernal  Michel Preda  Federico Páez-Osuna 《国际泥沙研究》2018,33(2):183-190

Two lead-210 (²¹⁰Pb) dated sediment cores from Chapala Lake were studied to identify the mineral composition of the sediments and to discuss its relation with trace metals. Minerals and trace metals reflected the domain of volcanic rocks (i.e. basalts, rhyolite and andesite) that characterize Chapala Lake and the Lerma River watershed. Redundancy analyses (RDA) were used to identify the sedimentary variables (magnetic susceptibility, organic matter, sand content, and mineral composition) that could be related to elemental composition. Despite the distance between the two cores (7.3 km) and hydrodynamic circulation the RDA showed that the main mechanism that controls the input of mineral species, and, therefore, element distributions in the lacustrine sediment of Chapala Lake, is related to the weathering of volcanic rocks in the Lerma-Chapala watershed, the consequent runoff and transport of fine grained catchment materials, and later in-lake processes. These findings highlight the importance of controlling watershed erosion to contribute to the improvement of the environmental quality of the lake.  相似文献   

Mapping of bauxite mineral deposits in the northern region of Saudi Arabia by using Advanced Spaceborne Thermal Emission and Reflection Radiometer satellite data     

P. Sheik Mujabar  S. Dajkumar 《地球空间信息科学学报》2019,22(1):35-44

Mineral deposit mapping is very essential for sustainable and eco-friendly exploitation of natural resources. The Kingdom of Saudi Arabia has abundant natural resources such as natural gas, oil and minerals. It reserves high quantity of minerals such as phosphates, bauxites, copper, gold and other industrial minerals. The red soil regions located in Hail and Qassim provinces of Saudi Arabia have rich amount of bauxite (major aluminum ore) deposits. In order to initiate the focus on mapping of mineral deposits along this area, standardized hyper-spectral analysis has been carried out by using Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) satellite data. The spectral signature of gibbsite (major element in bauxite) samples is analyzed with reference to the spectral features of gibbsite in the visible near infrared and short-wave infrared bands electromagnetic spectrum. Advanced hyper-spectral transformations such as minimum noise fraction function and pixel purity index have been performed to identify the target end-member. The existence of the mineral is confirmed by comparing the spectral signatures of the end-member with the predefined spectral plots of ASTER and United States Geological Survey spectral libraries. Finally, the end-members are mapped and their abundance is estimated in 0–1 scale. The study has opened up new areas for mapping of bauxite deposits in the area and leads to eco-friendly exploitation of natural resources. It also validates the high potential of ASTER multispectral satellite data for the exploration and mapping of mineral resources.  相似文献