原子荧光光谱法测定芦荟中砷和硒   总被引：5，自引：1，他引：5       下载免费PDF全文

林章金 《岩矿测试》2003,22(3):237-238

应用AFS 820型双道原子荧光仪测定芦荟中砷和硒,方法检出限分别为As0.51μg/L;Se0.42μg/L。经国家一级植物标准物质分析验证,结果与标准值相符。5次测定相对标准偏差As<2.3%;Se<3.1%。  相似文献   

原子荧光光谱法测定化探样品时有机质对As,Sb,Bi的干扰   总被引：1，自引：0，他引：1  

汪明启  刘应汉 《地质科技情报》2003,22(1):105-109

通过研究黑龙江省森林沼泽景观区有机水系沉积物（泥炭）、土壤中As,Sb,Bi的测定结果，发现样品中的有机质对王水消解氢化物原子荧光法测定上述元素存在极大的干扰，提出采用低温（＜450℃）灰化处理可完全消除干扰。对比研究还发现，过去森林沼泽景观区的区域化探扫面资料中的As,Sb,Bi数据存在问题，应专门对其进行评价研究。  相似文献   

Enhanced red fluorescence emission in the oxygen minimum zone of the Arabian Sea     

Wiebke Breves  Rüdiger Heuermann  Rainer Reuter 《Ocean Dynamics》2003,53(2):86-97

 Depth profiles of fluorescence at several excitation and emission wavelengths were measured along with CTD data during the cruise So119 of RV Sonne in the Arabian Sea from 12 May to 10 June 1997. In addition to chlorophyll fluorescence from phytoplankton in the near-surface layer, the profiles in the oxygen minimum region well below the euphotic zone show enhanced red fluorescence. Red fluorescence intensity is inversely related to the oxygen concentration in intermediate and deep waters. A relationship to characteristic water masses of the region cannot be found in the data, and this holds also with chemical data such as DOC. Absorbance spectra of water samples taken in the oxygen minimum zone show an absorption band at 420 nm wavelength with about 50 nm bandwidth, much weaker than gelbstoff absorbance in the same wavelength range. The absorption band remains stable after sample filtration with 0.45 μm glass fibre filters. Hence, the size of the absorbing matter is in the range of dissolved molecules or particles much smaller than 1 μm. Fluorescence spectra of unfiltered samples with 420 nm excitation show a weak emission band at 600 nm and a more pronounced one at 660 nm wavelength. The trailing edge of the 660 nm band falls into the range of chlorophyll emission, thus giving rise to the observed depth profiles of red fluorescence in the oxygen minimum zone. Red fluorescence measured on samples remain stable during a few hours after sampling even in the presence of oxygen. It is not detectable after several weeks of sample storage in the dark and cannot be reproduced even after depletion of dissolved oxygen. Received: 22 May 2002 / Accepted: 18 February 2003 Responsible Editor: Andreas Oschlies Acknowledgements. This work was supported by a grant from the Federal Minister of Education and Technology, Bonn, within the frame work of the JGOFS Arabian Sea program. We are grateful to the captain and the crew of RV Sonne for their support. We are indebted to Mrs. Kirsten Neumann from the Institute of Marine Chemistry and Biogeochemistry of the University of Hamburg for providing the oxygen data, and to Mr. Nikolai Delling from the same institute for making the DOC and chlorophyll data available to us.  相似文献   

基于人工神经网络的赤潮卫星遥感方法研究   总被引：7，自引：1，他引：7  

楼琇林  黄韦艮 《遥感学报》2003,7(2):125-130

根据赤潮的卫星遥感探测机理，应用人工神经网络技术，建立和利用NOAA AVHRR可见光和热红外波段遥感数据的BP神经网络赤潮信息提取模型。应用实例显示。基于该人工神经网络方法可以提取赤潮发生地点和范围等信息，赤潮探测正确率达到78.5%。研究结果表明，应用人工神经网络方法提取赤潮信息是可行的。本文中建立的BP赤潮信息提取模型适当修改后可移植应用于其它传感器遥感数据进行赤潮信息提取。  相似文献   

Advances in energy-dispersive X-ray fluorescence   总被引：1，自引：0，他引：1  

Utz Kramar 《Journal of Geochemical Exploration》1997,58(1):73-80

Recently, two new instruments for X-ray fluorescence analysis (XRF) with interesting features for geochemical applications came to the market. Both instruments were designed to improve the peak to background ratio, the principal factor limiting the sensitivity of XRF. Total reflection XRF (TXRF) was designed to analyse extremely small sample amounts. An instrument, using polarised X-rays (P-XRF) for excitation, is designed to reduce scattered background in spectra of bulk samples. The performance of both instruments was compared with conventional XRF-methods and ICP/MS. Results for GXR-1, GXR-2, GXR-3, GXR-4 and GXR-6 obtained with TXRF and P-XRF are in good agreement with literature data. The effective amount of sample, analysed by TXRF was 200 μg only and detection limits of ~ l μg/g were achieved. P-XRF shows considerable improved detection limits (0.25–0.5 μg/g) for bulk samples for elements with atomic numbers 42–51 (Mo-Sb) compared with conventional XRF-methods.  相似文献   

雷州半岛英峰岭剖面多期红土矿物学特征初步研究   总被引：3，自引：0，他引：3  

文国高  文启忠  朱照宇  徐义芳 《矿物岩石地球化学通报》1997,(3)

雷州半岛英峰岭剖面多期红土矿物学特征初步研究＊文国高文启忠朱照宇徐义芳（中国科学院广州地球化学研究所，广州５１０６４０）关键词多期红土矿物学红土化雷州半岛我国南方热带－亚热带广泛发育的红土（包括红色风化壳和红色古土壤），记录了形成过程环境变迁的重要信...  相似文献   

甘肃窑街寺湾沟－炭洞沟红层孢粉组合、地质时代与生态环境   总被引：2，自引：0，他引：2  

马玉贞  陶明信  陈发源 《沉积学报》1996,(1)

对窑街寺湾沟－炭洞沟红层孢粉和地层层序及时代进行了系统分析与对比研究。在该剖面中划分出２个孢粉组合：①双束松粉属－无口器粉属－杉粉属－栎粉属－瘤面海金砂孢属组合，时代为早渐新世；②双束松粉属－拟桦粉属－栎粉属－藜粉属－瘤面海金沙孢属组合，属中渐新世。研究表明：窑街寺湾沟－炭洞沟红层剖面的层位位于朱儿庄剖面之上，整个窑街地区的红层剖面属始新统－中渐新统；窑街地区始新世孢粉组合与中国东、西部地区孢粉组合相似，均发育以亚热带和暖温带植物为主的亚热带型落叶阔叶林，气候炎热；始新世晚期至早渐新世则演变为以暖温带落叶阔叶树种为主的针阔叶混交林植被，气候温暖湿润；中渐新世为暖温带落叶阔叶林，气候较温暖湿润。区域对比分析表明，从渐新世早期中国东、西部植被开始出现差异并逐渐加大，该时期也许是中国新构造运动的一个重要时期。  相似文献   

黄土高原黄土、红色粘土与古湖盆沉积物关系   总被引：7，自引：0，他引：7  

岳乐平 《沉积学报》1996,14(4):148-153

本文通过磁性地层学、古生物地层学、沉积学的对比研究，讨论了中国黄土高原地区黄土，红色粘土与该区重要古湖盆之一，古三门湖堆积物之间关系，并分析气候环境对它们的影响。主要结论如下：１）红色粘土与上覆黄土可以是连续沉积，并呈相渐变关系。２）中国黄土与三门组记录了布容正极性带与松山负极性带。Ｂ／Ｍ界限位于Ｌ８，Ｊ亚带位于标志层Ｌ９与Ｌ１５之间，大约Ｓ１０－Ｓ１３之间，Ｏ亚带位于Ｓ２２－Ｓ３３，或三门组之中。Ｍ／Ｇａ界限对应于黄土与红土界限。并基本对应于三门组与游河组界限。３）红色粘土（三趾马红粘土）并非仅仅是中新世保德期沉积物。它包括上新统与中新统，上新世静乐组记录了高斯正极性带，吉尔伯特负极性带，中新世蓝田组记录了Ｅｐｏｃｈ５。４）古三门湖堆积包括早更新世早期三门组（１．２０—２．５０Ｍａ，松山负极性带），上新世晚期游河组（２．５０—３．５０Ｍａ，高斯正极性带），更早期的三门湖沉积未出露。三门组与午域黄土为同期异相沉积，记录了松山负极性带，游河组则与该区上部红色粘土（静乐组上段）为同期异相沉积，记录了高斯正极性带  相似文献   

红粘土的磁学性质研究   总被引：17，自引：2，他引：17  

朱日祥  潘永信  丁仲礼 《第四纪研究》1996,16(3):232-238

本文对陕西宝鸡剖面红粘土上部进行了详细的岩石磁学研究，确定了该地区红粘土的主要磁性矿物是磁铁矿。赤铁矿相对含量很少，对剩余磁性贡献较小。磁性质不稳定的磁赤铁矿存在于红粘土中，但不影响剩磁稳定性。特征剩磁载体主要是磁铁矿。磁性矿物的粒度是以准单畴为主。红粘土的短时间弛豫粘滞剩磁很强，因此在零磁空间进行退磁和剩磁测量是非常重要的。  相似文献   

长沙黄花国际机场水源地的水文地质条件     

刘振忠  徐定芳 《湖南地质》1996,15(4):209-216,238

长（沙）－平（江）白垩系红层盆地，公认为贫水地区。我院在机场附近找到了单井日产水量〉５３００ｍ＾３的优质地下水，一举解决了长沙黄花国际机场的供水问题。这项勘察成果，不仅解决了机场的水源地，而且对长－平红层盆地的水文地质研究、勘查和找水建井等，均具有现实意义。  相似文献