Kinetic-simulating experiment combined with GC-IRMS analysis: application to identification and assessment of coal-derived methane from Zhongba Gas Field (Sichuan Basin, China)   总被引：2，自引：0，他引：2  

Yongqiang Xiong  Ansong Geng  Jingzhong Liu 《Chemical Geology》2004,213(4):325-338

The main purpose of this study is to model the δ¹³C values of methane derived from coal by combining kinetic-simulating experiment with the gas chromatography-isotope ratio mass spectrum (GC-IRMS) analysis. The stable carbon isotopic variation of methane in pyrolysates with heating temperature indicates that the assumptions for both a constant kinetic isotope effect (α) and a uniform initial isotopic composition (δ¹³C_o) are impractical for explaining the carbon isotopic fractionation during coalification. For purposes of simplification, two approaches are used in this paper to deal with the heterogeneity of terrestrial organic matter. One is that, assuming a uniform initial isotopic composition (i.e., δ¹³C_{i, o}=δ¹³C_o) for all methane-generating precursors in coal, the isotopic variation of methane is fitted by adjusting ΔE_{a, i} (E_{a¹³C, i}−E_{a¹²C, i}) for each hypothetical reaction. The other is that, assuming a constant kinetic isotope effect during the whole gas formation, that is all ΔE_{a, i} values are identical, the modeling of methane isotopic composition is achieved by changing the ¹³CH₄ generation potential of each reaction (f_{i, ¹³C}), namely, by adjusting the initial δ¹³C value (δ¹³C_{i, o}) for each methane-generating precursor. Results of the kinetic calculation shows that the two simulating methods can yield a similar result at a geological heating rate of 2 °C/My, which further demonstrates that those natural gases with methane δ¹³C value being approximately −36‰ are possibly sourced from the upper Triassic coal measure strata in the Northwestern Sichuan Basin.  相似文献   

On the long-term seismic hazard analysis in the Zhangjiakou–Penglai seismotectonic zone, China     

Zhengxiang Fu  Jie Liu  Guiping Liu 《Tectonophysics》2004,390(1-4):75-83

The Zhangjiakou–Penglai seismotectonic zone (ZPSZ) lies in the northern part of North China and extends along the Zhangjiakou–Beijing–Tianjin–Bohai Bay–Penglai–Yellow Sea. It is about 900 km long and some 250 km wide in a northwest direction. The great Sanhe-Pinggu (M_S=8.0) earthquake occurred on September 1679 and the Tangshan (M_S=7.8) earthquake on July 1976 caused serious economic and life losses. According to some differences in crust structure and regional tectonic stress field, the ZPSZ is divided into western and eastern segment by the 117°E line for study on long-term seismic hazard analysis. An analysis of Gutenberg–Richter's empirical relation of earthquake-frequency and time process of historic and recent earthquakes along the eastern and western segments shows that the earthquake activity obeys a Poisson process, and these calculations indicate that the earthquake occurrence probability of M_S=6.0–6.9 is 0.77–0.83 in the eastern segment and the earthquake occurrence probability of M_S=7.0–7.9 is 0.78–0.80 in the western segment of the ZPSZ during a period from 2005 to 2015.  相似文献   

A Physical and Numerical Investigation on the Stability of Shallow Tunnels in Strain Softening Media   总被引：11，自引：0，他引：11  

D. Sterpi  A. Cividini 《Rock Mechanics and Rock Engineering》2004,37(4):277-298

Summary The behaviour up to failure of shallow underground openings is discussed on the basis of some laboratory, small-scale model tests and of finite element simulation. The experimental results are first illustrated. They were obtained from two-dimensional (plane strain) and three-dimensional tunnel models tested under standard gravity conditions. Then, the phenomenon of strain localisation that characterizes the medium surrounding the model tunnels is discussed, recalling two alternative approaches for its numerical interpretation. On this basis, a finite element procedure for strain softening analyses is outlined and applied to the simulation of the tests in both two- and three-dimensional conditions. The comparison between experimental and numerical results leads to some conclusions on the influence of strain localisation on the overall behaviour of shallow tunnels and on the stability of their headings.  相似文献   

A time-space based approach for mapping rainfall-induced shallow landslide hazard   总被引：2，自引：0，他引：2  

Mowen Xie  Tetsuro Esaki  Meifeng Cai 《Environmental Geology》2004,46(6-7):840-850

A rainfall-induced shallow landslide is a major hazard in mountainous terrain, but a time-space based approach is still an unsettled issue for mapping rainfall-induced shallow landslide hazards. Rain induces a rise of the groundwater level and an increase in pore water pressure that results in slope failures. In this study, an integrated infinite slope analysis model has been developed to evaluate the influence of infiltration on surficial stability of slopes by the limit equilibrium method. Based on this new integrated infinite slope analysis model, a time-space based approach has been implemented to map the distributed landslide hazard in a GIS (Geographic Information Systems) and to evaluate the shallow slope failure induced by a particular rainfall event that accounts for the rainfall intensity and duration. The case study results in a comprehensive time-space landslide hazard map that illustrates the change of the safety factor and the depth of the wetting front over time.  相似文献   

Inferring the mass fraction of floc-deposited mud: application to fine-grained turbidites   总被引：1，自引：0，他引：1  

K. J. Curran  P. S. Hill  T. M. Schell  T. G. Milligan†  D. J. W. Piper‡ 《Sedimentology》2004,51(5):927-944

Fine sediment deposition in the ocean is complicated by the cohesive nature of muds and their tendency to flocculate. The result is disaggregated inorganic grain size (DIGS) distributions of bottom sediment that are influenced by single‐grain and floc deposition. This study outlines a parametric model that characterizes bottom sediment DIGS distributions. Modelled parameters are then used to infer depositional conditions that account for the regional variation in the grain sizes deposited by turbidity currents on the Laurentian Fan–Sohm Abyssal Plain, offshore south‐eastern Canada. Results indicate that, on the channellized Laurentian Fan, the mass fraction of floc‐deposited mud increases only slightly downslope. The small evolution in this fraction arises because sediment concentration and turbulent energy are associated in turbidity currents. On the Sohm Abyssal Plain, however, the mass fraction of floc‐deposited mud decreases, probably as a result of lower sediment concentration at this source‐distal site. Estimates of the mass fraction of mud deposited as flocs suggest that floc deposition is the dominant mode by which sediment is lost from suspension, although single‐grain deposition contributes more to the depositional flux in proximal areas where high energy breaks flocs and in distal areas where low sediment concentration limits floc formation. It is concluded that, throughout the dispersal system, changes in the fraction of flocculated mud deposited from turbidity currents reflect changes in sediment concentration and energy downslope.  相似文献   

Application of AVO Analysis to Seismic Data for Detection of Gas below Methane Hydrate Stability Zone in Nankai Trough Area     

Masami Hato    Takao Inamori    Alfian Bahar  Toshifumi Matsuoka 《Resource Geology》2004,54(1):105-113

Abstract. For the purpose of development of methane hydrate, occurring in the deep marine subsurface, as a resource, the most important issue is to understand the methane hydrate system (generation, migration and accumulation) as well as to delineate the methane hydrate reservoir properties. We have applied the Amplitude Versus Offset (AVO) analysis to the seismic data acquired in the Nankai Trough, offshore Japan, in order to confirm the occurrence of gas just below the methane hydrate-bearing zone, assuming that gas will show a so-called Class-3 AVO response. Knowledge of the amount and occurrence of gas in the sediment below methane hydrate-bearing zone is one of the keys to understand the methane hydrate system.
We have utilized the qualitative analysis of AVO methodology to delineate how gas is located below the BSR, which is thought to be the reflection event from the interface between the methane hydrate-bearing zone and the underlying gas-bearing zone. In the region of MITI Nankai Trough Well PSW-3, we observe two BSRs separated by 25 ms. After AVO modeling using well data, we applied AVO attribute analysis and attribute crossplot analysis to the seismic data. Finally we applied an offset-amplitude analysis to CMP gather data at specific locations to confirm the results of AVO attribute analysis. The AVO analysis shows that there is very little gas located in the underlying sediment below methane hydrate-bearing zone. This result supports the fact that we could not obtain any clear evidence of gas occurrence just below the methane hydrate-bearing zone in the Nankai Trough well drilling.  相似文献   

Curve-Fitting Schemes for Fragmentation Data     

D. P. Blair 《Fragblast: International Journal for Blasting and Fragmentation》2004,8(3):137-150

Fragmentation measurements in the form of sieve passing and mass fraction data were used to test the capability of three different distributions to fit the observed data over a wide range in fragment size and mass. These distributions were based on Rosin-Rammler, lognormal and simple sigmoidal (S-shaped) functions, having 2 input parameters for the single-component versions and 5 input parameters for the two-component versions. Provided convergence was achieved in the non-linear curve-fitting technique, the two-component versions always provided superior fits to the observed data. However, these versions were very sensitive to variations in the values chosen for the input parameters. In this particular regard, the two-component sigmoidal function was the most robust. The present results also show that the two-component lognormal function provided the best fit to the fragmentation data in a general sense, and the two-component Rosin-Rammler function provided the worst fit. However, there was not a significant difference between any of the three methods.  相似文献   

Curie Point Depths Beneath Precordillera Cuyana and Sierras Pampeanas Obtained from Spectral Analysis of Magnetic Anomalies   总被引：1，自引：0，他引：1  

Francisco Ruiz  Antonio Introcaso   《Gondwana Research》2004,7(4):1133-1142

A gravity and magnetic survey has been carried out with the purpose of investigating geophysical features of the crusts beneath three geological provinces in western Argentina: Cuyo Precordillera, the Sierras Pampeanas of San Juan and La Rioja, and Famatina System, the results of which are displayed in three maps: Bouguer anomaly, total field magnetic anomaly and total field reduced to the pole.

The top and bottom boundaries of the magnetized crust were calculated from power-density spectra of the total-field anomalies from our terrestrial database in 90 2D windows. The depths obtained for the bottom of magnetized crust are assumed to correspond to Curie point depths. The values thus obtained for the Precordillera range between 29 and 40 km, whereas for the Sierras Pampeanas, in the Sierra de Pie de Palo, and other mountain chains along the Bermejo-Desaguadero lineament or Valle Fértil lineament, such depth ranges between 20 and 35 km. These results are consistent with Curie point depths determined on different continental regions in the world.

A map of regional heat flow has been prepared in the present work based on the depth of the Curie point isotherm, which shows that heat flow patterns in Precordillera are different from those found in Sierras Pampeanas.

A significant heat flow extending in Northeast-Southwest direction seems to be directly related to Juan Fernández Ridge trace.

The results of the present investigations also point out a possible relationship between the base of the magnetized crust and the boundary separating the brittle from the ductile crustal regime.  相似文献   

Proposed support design, Kaletepe tunnel, Turkey     

D. Sari  A. G. Pasamehmetoglu 《Engineering Geology》2004,72(3-4):201-216

In this paper, preliminary support design of Kaletepe tunnel, located on Bilecik-Istanbul highway, Turkey, was analyzed by empirical and numerical methods. The rock mass rating (RMR) and rock mass quality (Q) systems were employed for empirical rock mass quality determination. Numerical analysis for the stress–strain distribution of the tunnel excavation and support systems was also carried out. The applied support performance was investigated at different sections of the tunnel route. It was seen that empirical and numerical approaches showed similar results. This indicates that when the empirical method is supported by numerical method, the preliminary support design will be more reliable.  相似文献   

Time-Frequency Variations of Plio-Pleistocene Foraminiferal Isotopes： A Case Study from Southern South China Sea     

TianJun WangPinxian ChengXinrong 《中国地质大学学报(英文版)》2004,15(3):283-289

The continuous wavelet transform (CWT) analysis reveals the instantaneous variability of the foraminiferal δ18O and δ13C of Site 1143 for the past 5 Ma at the eccentricity, obliquity and precession bands. The cross CWT analysis further demonstrates nonstationary phases of the benthic -δ18O relative to ETP at the three primary Milankovitch bands in the last 5 Ma. The instantaneous phases between benthic -δ18O and δ13C at the precession band display a prominent 128 ka period, probably the cyclicity of the nonstationary climate close to the eccentricity. To explain these nonstationary phases, it is desirable to introduce a nonlinear response model to the global climate system, in which the output has a prominent cycle around 100 ka to match the 128 ka cycle of the instantaneous phase of the δ13C and -δ18O on the precession band.  相似文献