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31.
系统岩心观察和高密度薄片鉴定等分析测试资料研究结果显示,济阳坳陷沙三下-沙四上泥页岩成分组成及构造类型主要受沉积作用控制,岩石结构特征主要受成岩作用控制。根据泥页岩中方解石成因及重结晶程度,结合岩石成分及构造特征,将济阳坳陷沙三下-沙四上泥页岩划分为沉积主控型、沉积-成岩双控型及成岩主控型三大成因相。沉积主控型分布最为广泛,岩相类型多样,构造特征反映成因环境;沉积-成岩双控型主要见于纹层状岩相,由泥质纹层与显晶粒状方解石纹层互层构成;成岩主控型以柱状、柱纤状方解石垂直层面呈脉状、透镜状产出为特征。成岩主控型和沉积-成岩双控型泥页岩与页岩油气关系密切,是重要的有利成因相类型。  相似文献   
32.
不同岩性的火山岩其储集性能差异甚远,准确识别火山岩岩性对于火山岩储层的研究具有重要意义。研究区春风油田石炭系储层以火山岩为主,过渡类型较多,岩性较为复杂。利用岩心观察、薄片鉴定、地化分析等方法确定研究区发育火山熔岩类和火山碎屑岩类两类火山岩,其中,火山熔岩包括玄武岩、安山玄武岩、玄武安山岩以及安山岩,火山碎屑岩有凝灰岩和火山角砾岩等。通过识别出的岩性标定测井,分析每种岩性的测井响应特征,利用交会图法和星形图法,建立了不同岩性的识别标准。  相似文献   
33.
Experimental study of enhanced in-situ micro-ecological remediation of petroleum contaminated loess soil was carried out in Zhongyuan oil production areas, and the enhanced in-situ micro-ecological remediation technique includes optimistic in-situ microbial communities, physical chemistry methods, alfalfa planting and regulation of soil environmental elements. Experiments showed that the oil content in the contaminated soil with oil content about 2 898.25 mg/kg can be reduced about 98.61% after in-situ micro-ecological remediation for 99 days, which demonstrated the effectiveness of in-situ micro-ecological remediation methods for petroleum contaminated soil in central plains of China, and explored the practical and feasible application of these methods.  相似文献   
34.
ABSTRACT

Oil spill forecast modelling is typically used immediately after a spill to predict oil dispersal and promote mobilisation of more effective response operations. The aim of this work was to map oil dispersal after the grounding of the MV Rena on Astrolabe Reef and to verify the results against observations. Model predictions were broadly consistent with observed distribution of oil contamination. However, some hot spots of oil accumulation, likely due to surf-zone and rip current circulation, were not well represented. Additionally, the model was run with 81 differing wind conditions to show that the events occurring during the grounding represented the typical likely behaviour of an oil spill on Astrolabe Reef. Oil dispersal was highly dependent on prevailing wind patterns; more accurate prediction would require better observations of local wind patterns. However, comparison of predictions with observations indicated that the GNOME model was an effective low-cost approach.  相似文献   
35.
ABSTRACT

The sinking of the MV Rena on Astrolabe Reef (Otaiti) in the Bay of Plenty, New Zealand, resulted in the release of oil and ship debris, including dangerous goods carried as cargo. Two key questions of concern to the public and environmental managers were posed immediately: what was the impact of the Rena oil spill and how long would it take for the marine environment to recover? The research that began immediately after the ship grounded provided answers, as documented in this special issue.  相似文献   
36.
ABSTRACT

The October 2011 sinking of the container ship MV Rena on Astrolabe Reef, New Zealand, provided a rare opportunity to examine the fate of shipwreck-derived contaminants on an offshore rocky reef and food chain. Analyses of trace metals, polycyclic aromatic hydrocarbons (PAHs) and organotins indicated significant but localised contamination of Astrolabe Reef but not of nearby Mōtītī Island. Three years after the grounding, PAH concentrations were greater in sediments at Astrolabe (up to 131?mg kg?1) than at control locations, while organotins from the ship's antifouling hull paint were found exclusively in Astrolabe Reef sediments and biota. Over 80% of Astrolabe sediment samples contained tributyltin at concentrations above guideline sediment levels (>0.07?mg kg?1). Tributyltin and its decomposition products were also recorded in sea urchins, gastropods, lobster and fishes at concentrations up to 0.2?mg kg?1. Wreck and cargo-derived metals, particularly copper, tin and zinc, were present in some Astrolabe sediment samples above Australia and New Zealand Environment and Conservation Council guideline concentrations. However, there appeared to be only limited transmission of metals through the food chain. Copper, tin and zinc were recorded at greater concentrations in Astrolabe sea urchins and gastropods compared to control specimens, while metal concentrations in other biota were comparable across impact and control sites. Despite over 3 years having passed since the Rena grounding, the data series does not show any upward or downward trends in contaminant concentrations on Astrolabe Reef. Consequently, there is uncertainty about the long-term implications of the Rena grounding for the ecology of Astrolabe Reef.  相似文献   
37.
ABSTRACT

To investigate the uptake and depuration of polycyclic aromatic hydrocarbons associated with the Rena oil spill we sampled the surf clam Paphies subtriangulata at two open coast locations (6?km apart) just prior to oil coming ashore (7 October 2011), then at 1–3 week intervals for the next 4 months. Total polycyclic aromatic hydrocarbons (tPAH) increased at both sites from 1 to 96–124?µg?kg?1 (wet weight) by 18 October before declining to low levels (<4?µg?kg?1) by February 2012. Ongoing sampling throughout 2012–2014 included three additional sites to the north east (up to 30?km away) and a site 5?km to the south east revealing tPAH levels generally <10?µg?kg?1 except in October 2013 where levels ranged between 39–45?µg?kg?1 at all sites. A comparison of PAH component profiles with oil-contaminated beach sediment indicated that the high levels observed in surf clams between October–December 2011 were clearly associated with the Rena spill. However, the October 2013 peak had a PAH profile inconsistent with weathered Rena oil, suggesting an alternative source of contamination. Our results highlight the potential for P. subtriangulata as a PAH monitoring tool but recognise more study is needed to better quantify baseline levels and uptake and depuration dynamics.  相似文献   
38.
Compared to conventional reservoirs, pore structure and diagenetic alterations of unconventional tight sand oil reservoirs are highly heterogeneous. The Upper Triassic Yanchang Formation is a major tight-oil-bearing formation in the Ordos Basin, providing an opportunity to study the factors that control reservoir heterogeneity and the heterogeneity of oil accumulation in tight oil sandstones.The Chang 8 tight oil sandstone in the study area is comprised of fine-to medium-grained, moderately to well-sorted lithic arkose and feldspathic litharenite. The reservoir quality is extremely heterogeneous due to large heterogeneities in the depositional facies, pore structures and diagenetic alterations. Small throat size is believed to be responsible for the ultra-low permeability in tight oil reservoirs. Most reservoirs with good reservoir quality, larger pore-throat size, lower pore-throat radius ratio and well pore connectivity were deposited in high-energy environments, such as distributary channels and mouth bars. For a given depositional facies, reservoir quality varies with the bedding structures. Massive- or parallel-bedded sandstones are more favorable for the development of porosity and permeability sweet zones for oil charging and accumulation than cross-bedded sandstones.Authigenic chlorite rim cementation and dissolution of unstable detrital grains are two major diagenetic processes that preserve porosity and permeability sweet zones in oil-bearing intervals. Nevertheless, chlorite rims cannot effectively preserve porosity-permeability when the chlorite content is greater than a threshold value of 7%, and compaction played a minor role in porosity destruction in the situation. Intensive cementation of pore-lining chlorites significantly reduces reservoir permeability by obstructing the pore-throats and reducing their connectivity. Stratigraphically, sandstones within 1 m from adjacent sandstone-mudstone contacts are usually tightly cemented (carbonate cement > 10%) with low porosity and permeability (lower than 10% and 0.1 mD, respectively). The carbonate cement most likely originates from external sources, probably derived from the surrounding mudstone. Most late carbonate cements filled the previously dissolved intra-feldspar pores and the residual intergranular pores, and finally formed the tight reservoirs.The petrophysical properties significantly control the fluid flow capability and the oil charging/accumulation capability of the Chang 8 tight sandstones. Oil layers usually have oil saturation greater than 40%. A pore-throat radius of less than 0.4 μm is not effective for producible oil to flow, and the cut off of porosity and permeability for the net pay are 7% and 0.1 mD, respectively.  相似文献   
39.
Understanding the oil distribution characteristics in unconventional tight reservoirs is crucial for hydrocarbon evaluation and oil/gas extraction from such reservoirs. Previous studies on tight oil distribution characteristics are mostly concerned with the basin scale. Based on Lucaogou core samples, geochemical approaches including Soxhlet extraction, total organic carbon (TOC), and Rock-Eval are combined with reservoir physical approaches including mercury injection capillary pressure (MICP) and porosity-permeability analysis, to quantitatively evaluate oil distribution of tight reservoirs on micro scale. The emphasis is to identify the key geological control factors of micro oil distribution in such tight reservoirs. Dolomicrites and non-detrital mudstones have excellent hydrocarbon generation capacity while detritus-containing dolomites, siltstones, and silty mudstones have higher porosity and oil content, and coarser pore throat radius. Oil content is mainly controlled by porosity, pore throat radius, and hydrocarbon generation capacity. Porosity is positively correlated with oil content in almost all samples including various lithologies, indicating that it is a primary constraint for providing storage space. Pore throat radius is also an important factor, as oil migration is inhibited by the capillary pressure which must be overcome. If the reservoir rock with suitable porosity has no hydrocarbon generation capacity, pore throat radius will be decisive. As tight reservoirs are generally characterized by widely distributed nanoscale pore throats and high capillary pressure, hydrocarbon generation capacity plays an important role in reservoir rocks with suitable porosity and fine pore throats. Because such reservoir rocks cannot be charged completely. The positive correlation between hydrocarbon generation capacity and oil content in three types of high porosity lithologies (detritus-containing dolomites, siltstones, and silty mudstones) supports this assertion.  相似文献   
40.
以海水青鳉(Oryzias melastigma)胚胎为研究对象,比较了120#燃料油分散液(water-accommodated fractions,WAFs)与乳化液(biologically enhanced water-accommodated fractions,BE-WAFs)的急性毒性效应,并研究了不同浓度(40、100、250 mg/L)下WAFs、BE-WAFs对胚胎内超氧化物歧化酶(SOD)、过氧化氢酶(CAT)、谷胱甘肽硫转移酶(GST)活性的影响。结果表明:在受到石油烃的氧化胁迫后,海水青鳉胚胎内3种抗氧化酶活性变化明显。随着石油烃浓度的升高和暴露时间的延长,3种酶表现出程度不同的诱导效应和抑制效应。其中受石油烃污染影响最为明显的为SOD酶;而GST酶则对消油剂单独暴露表现较为敏感。实验证明,海水青鳉体内SOD酶活性对石油烃污染反应最为敏感,适合作为监测石油烃污染程度的生物标志物。  相似文献   
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