有机质对纳米级磁铁矿热稳定性的影响   总被引：2，自引：1，他引：1       下载免费PDF全文

吴文芳  李金华  张春霞  潘永信 《地球物理学报》2010,53(10):2427-2434

单畴磁铁矿颗粒是地质样品中最重要的磁性载体,其稳定性一直备受关注.为了认识有机质对纳米级磁铁矿颗粒热稳定性的影响,本文对比研究了趋磁细菌AMB-1合成的单畴磁铁矿分别在全细胞中和经去胞提纯后的纯化磁小体中的热磁性质,以及热处理后样品的磁滞参数和低温磁性的变化.发现仅有磁小体膜包裹的纯化磁小体中单畴磁铁矿热稳定性极强,而全细胞中的单畴磁铁矿加热过程中发生了显著的热变化:磁铁矿在约270℃即开始转化,400℃以前几乎完全被有机质还原为顺磁性物质;同时在400℃以前,有机质的还原作用与有机质热分解引起磁小体链的坍塌,共同导致了样品矫顽力(B_c)、剩磁矫顽力(B_cr)和剩磁比(M_rs/M_s)的减小,以及矫顽力比(B_cr/B_c)的增加. 我们的实验结果清楚地表明,当地质样品中含有较多有机质组分并受热事件影响时,其中的单畴磁铁矿难以得到保存.  相似文献   

大荔人遗址黄土-古土壤剖面岩石磁学性质研究   总被引：1，自引：0，他引：1       下载免费PDF全文

霍俊杰  Reidar Lovlie  李斌  苏朴 《地球物理学报》2010,53(6):1463-1474

自从大荔人化石被发现以来,其遗址剖面便成为研究热点.先前的研究主要集中在地层的对比划分与头盖骨年龄的推断方面,然而对于载磁矿物的鉴定及其古气候含义方面的研究却相对较少.鉴于此,本文运用热磁分析、饱和等温剩磁和剩磁矫顽力谱分析、磁滞回线分析、频率磁化率分析、热退磁分析等方法,对大荔人遗址剖面进行了系统的岩石磁学性质研究,鉴定出其主要载磁矿物为磁铁矿,赤铁矿,磁赤铁矿,磁畴状态主要是似单畴.磁铁矿,赤铁矿是样品中特征剩磁的携带者;主要起源于成土作用的超顺磁颗粒和新生成的亚铁磁性矿物,是古土壤样品磁化率增强的主要贡献者;古土壤中软磁性矿物的含量高于黄土.样品中磁赤铁矿的含量并不高.黄土-古土壤样品的频率磁化率曲线,古里雅冰芯氧同位素、细微粒浓度曲线,岐山五里铺剖面有机质含量曲线在古气候记录方面具有一致性,都展示出至少从MIS5以来,气候从冰期到间冰期的变化是渐变的,反之则表现了突变特征.上述岩石磁学研究丰富了大荔剖面的磁学领域研究内容,为相关课题的深入研究提供了依据.  相似文献   

Coastal sediments under the influence of multiple organic enrichment sources: An evaluation using carbon and nitrogen stable isotopes   总被引：2，自引：0，他引：2  

Leandro Sampaio  Cristina Máguas  Victor Quintino 《Marine pollution bulletin》2010,60(2):272-282

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Rhizosphere Effect of Salix viminalis L. on Soil Enzyme Activity in a Wastewater Treatment Wetland          下载免费PDF全文

Maria Swiontek Brzezinska  Agnieszka Kalwasińska  Elżbieta Lalke‐Porczyk  Aleksandra Burkowska‐But  Urszula Jankiewicz 《洁净——土壤、空气、水》2016,44(5):563-571

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Phosphorus Runoff Losses After Application of Organic Waste          下载免费PDF全文

Marta García‐Albacete  María Isabel Requejo  María Carmen Cartagena 《洁净——土壤、空气、水》2016,44(12):1628-1635

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甘肃省阳山超大型金矿床的有机地球化学特征研究   总被引：7，自引：4，他引：3  

秦艳  周振菊 《岩石学报》2009,25(11):2801-2810

甘肃省文县阳山金矿是我国地质勘查储量最大的卡林-类卡林型金矿床,赋矿地层为泥盆系一套碳-硅-泥质地层.矿区发育了大量碳质千枚岩,富含有机碳.本文研究了矿石和围岩可溶有机质的生物标志物、有机质的来源和成熟度、干酪根的碳同位素等,论述了阳山金矿床的有机地球化学特征及有机质与成矿的关系,查明了参与成矿的有机质主要是菌藻类等低等生物.生物标志化合物参数和干酪根的H/C-O/C原子比值指示阳山金矿有机质成熟度较高,达到了无烟煤的演化阶段.在热演化的过程中,有机质裂解产生的CH_4和C-2H_6等进入成矿流体中,参与了成矿过程.阳山金矿赋矿地层中含有生物成因的草莓状黄铁矿,显示生物-有机质参与了地层的预富集作用.有机碳含量、有机质的类型和金的丰度之间相关性不明显,说明在阳山金矿的成矿过程中有机质对金的沉淀贡献不大,但是有机质可能参与了金的预富集和运移.  相似文献   

Is organic matter a source or redox driver or both for arsenic release in groundwater?     

《Physics and Chemistry of the Earth》2013

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塔里木盆地西克尔中奥陶统礁滩相储层成岩特征与系统划分          下载免费PDF全文

周 刚 郑荣才 罗 平 赵先超 刘 伟宋金民  饶红娟 《中国地质》2012,39(1):135-145

通过对塔里木盆地西克尔地区中奥陶统生物礁滩成岩作用方式、成岩演化序列和相对应的地质作用产物、组合及稀土元素和碳、氧、锶稳定同位素地球化学特征综合研究,按"水文体制"将生物礁滩地层划分为不同成岩阶段的近地表海水-海源地层水、大气淡水、温压水和油田卤水4个成岩系统。各成岩系统流体来源、性质、水-岩石相互作用过程及其对储层的影响各不相同,其中与储层发育密切相关的成岩体系和成岩方式主要为:古表生期大气水成岩系统的岩溶作用、再埋藏成岩阶段温压水成岩系统和油田卤水成岩系统的深部溶蚀和各期构造破裂作用。  相似文献   

Soil Organic Carbon mapping of partially vegetated agricultural fields with imaging spectroscopy     

Harm Bartholomeus  Lammert Kooistra  Antoine Stevens  Martin van Leeuwen  Bas van Wesemael  Eyal Ben-Dor  Bernard Tychon 《International Journal of Applied Earth Observation and Geoinformation》2011

Soil Organic Carbon (SOC) is one of the key soil properties, but the large spatial variation makes continuous mapping a complex task. Imaging spectroscopy has proven to be an useful technique for mapping of soil properties, but the applicability decreases rapidly when fields are partially covered with vegetation. In this paper we show that with only a few percent fractional maize cover the accuracy of a Partial Least Square Regression (PLSR) based SOC prediction model drops dramatically. However, this problem can be solved with the use of spectral unmixing techniques. First, the fractional maize cover is determined with linear spectral unmixing, taking the illumination and observation angles into account. In a next step the influence of maize is filtered out from the spectral signal by a new procedure termed Residual Spectral Unmixing (RSU). The residual soil spectra resulting from this procedure are used for mapping of SOC using PLSR, which could be done with accuracies comparable to studies performed on bare soil surfaces (Root Mean Standard Error of Calibration = 1.34 g/kg and Root Mean Standard Error of Prediction = 1.65 g/kg). With the presented RSU approach it is possible to filter out the influence of maize from the mixed spectra, and the residual soil spectra contain enough information for mapping of the SOC distribution within agricultural fields. This can improve the applicability of airborne imaging spectroscopy for soil studies in temperate climates, since the use of the RSU approach can extend the flight-window which is often constrained by the presence of vegetation.  相似文献   

Benthic foraminifera distribution in a tourist lagoon in Rio de Janeiro, Brazil: a response to anthropogenic impacts     

Vilela CG  Batista DS  Baptista Neto JA  Ghiselli RO 《Marine pollution bulletin》2011,62(10):2055-2074

Rodrigo de Freitas Lagoon, located in the Rio de Janeiro City, receives several types of polluted discharges. The knowledge of the sediment microfauna correlated with heavy metal and organic matter concentrations could supply important data about the conditions of the lagoon. The benthic foraminiferal assemblage presented larger diversity and more abundant samples in the lagoon entrance than in the inner area. The Ammonia tepida - Elphidiumexcavatum foraminiferal assemblage is characterized by dwarf, corroded and weak organisms. Agglutinated species were found only near the entrance. Low abundance values and sterility of five samples in the inner area (north/northeast) can be caused by high levels of heavy metals and organic matter. A. tepida shows negative correlation with increasing heavy metals values. PAHs and coprostanol high indexes, and the absence or low presence of microfauna in samples around the lagoon margin confirm illegal flows from gas stations and domestic sewage.  相似文献