Investigating the Halogen Chemistry From High-Latitude Nighttime Stratospheric Measurements of OClO and NO2     

Emmanuel Damien Rivière  Michel Pirre  Gwenaël Berthet  Jean-Baptiste Renard  Franck Lefèvre 《Journal of Atmospheric Chemistry》2004,48(3):261-282

Two cases of simultaneous nighttime measurements of NO₂ and OClO in the winter polar stratosphere are analyzed in order to test our present knowledge of halogen chemistry in the presence of high amount of NO₂ at low temperature. Comparisons with Lagrangian model calculations using several hypotheses are performed. First simulations, using the admitted constant rates of chemical reaction, strongly underestimate the measured OClO while the NO₂ profiles are correctly reproduced. If uncertainties in actinic fluxes calculations are taken into account, simulation results do not show a significant reduction of the underestimation. A better agreement can be achieved if the formation of unstable isomers of ClONO₂ and of BrONO₂ occurs in the cold conditions of the polar stratosphere. An approximate value of the branching ratios of the channels leading to ClONO₂ and ClOONO, and to BrONO₂ and BrOONO, necessary to reproduce both OClO and NO₂ is given and discussed.  相似文献   

The Influence of Advection on the Short Term CO 2 -Budget in and Above a Forest Canopy     

C. Feigenwinter  C. Bernhofer  R. Vogt 《Boundary-Layer Meteorology》2004,113(2):201-224

An experimental micrometeorological set-up was established at the CARBOEURO-FLUX site in Tharandt, Germany, to measure all relevant variables for the calculation of the vertical and horizontal advective fluxes of carbon dioxide. The set-up includes two auxiliary towers to measure horizontal and vertical CO₂ and H₂O gradients through the canopy, and to make ultrasonic wind measurements in the trunk space. In combination with the long-term flux tower an approximately even-sided prism with a typical side-length of 50 m was established. It is shown that under stable (nighttime) conditions the mean advective fluxes have magnitudes on the same order as the daily eddy covariance (EC) flux, which implies that they play a significant, but not yet fully understood, role in the carbon budget equation. The two advective fluxes are opposite and seem to cancel each other at night (at least for these measurements). During the day, vertical advection tends to zero, while horizontal advection is still present implying a flow of CO₂ out of the control volume. From our measurements, a mean daily gain of 2.2 gC m^–2 d^–1 for the horizontal advection and a mean daily loss of 2.5 gC m^–2d^–1 for the vertical advection is calculated for a period of 20 days. However the large scatter of the advective fluxes has to be further investigated. It is not clear yet whether the large variability is natural or due to measurement errors and conceptual deficiencies of the experiment. Similar results are found in the few comparable studies.  相似文献   

贵州百花湖分层晚期有机质降解过程与溶解N₂O循环   总被引：7，自引：0，他引：7       下载免费PDF全文

王仕禄  刘丛强  万国江  陶发祥  李军  朱兆洲  吕迎春 《第四纪研究》2004,24(5):569-577

百花湖是一个具有季节性分层的富营养小型湖泊,在秋季湖水倒转期经常发生水质恶化事件,碳氮循环出现异常。文章研究特选择在秋初,湖泊分层开始消失时,测定了湖水中不同深度的N₂O,CH₄,CO₂,有机和无机碳同位素以及其他化学参数变化。结果发现:采样时百花湖在约6m和16m深度附近出现了两个温度不连续层(SDL和PDL),并影响到有机颗粒的沉降和分解。相对而言,有较多的有机质在这两个层内发生降解,但降解的途径有所不同,上部主要是有氧降解,下部则主要是无氧降解过程。N₂O的产生和消耗与有机质的降解过程完全对应:PDL层以上,ΔN₂O与AOU的线性关系反映了N₂O主要形成于硝化作用;PDL层以下反硝化作用导致N₂O严重不饱和;PDL内位于硝化作用和反硝化作用过渡带的N₂O峰,显然是硝化与反硝化联合作用的结果。PDL层内较大的CH₄浓度变化梯度,说明嗜甲烷细菌可能通过氧化NH+4贡献了部分N₂O。百花湖秋、冬季表层湖水N₂O都是过饱和的,都是大气N₂O的源,依据分子扩散模型计算湖泊N₂O的释放通量在12～14μmol/m·day之间,秋、冬季没有明显的差别。秋季底层湖水的反硝化作用是湖泊N₂O的汇,其消耗通量与表层的释放通量基本相当。  相似文献   

Experimental research on reservoir sensitivity to stress and impacts on productivity in Kela 2 Gas Field     

Sun Longde  Song Wenjie  Jiang Tongwen 《中国科学D辑(英文版)》2004,47(Z2)

Kela 2 Gas Field, with high formation pressure (74.35MPa), high pressure coefficient (2.022) and difficulty of potential test and evaluation, is the largest integrated proved dry gas reservoir in China so far and the principal source for West-East Gas Development Project. In order to correctly evaluate the elastic-plastic deformation of rocks caused by the pressure decline during production, some researches, as the experiment on reservoir sensitivity to stress of gas filed with abnormal high pressure, are made. By testing the rock mechanic properties, porosities and permeabilities at different temperature and pressure of 342 core samples from 5 wells in this area, the variations of petro-physical properties at changing pressure are analyzed, and the applicable inspection relationship is concluded. The average productivity curve with the reservoir sensitivity to stress is plotted on the basis of the research, integrated with the field-wide productivity equation. The knowledge lays a foundation for the gas well productivity evaluation in the field and the gas field development plan, and provides effective techniques and measures for basic research on the development of similar gas fields.  相似文献   

Determination of S-wave velocity structure using microtremors and spac method applied in Thessaloniki (Greece)     

Paschalis Apostolidis  Dimitrios Raptakis  Zafeiria Roumelioti  Kyriazis Pitilakis 《Soil Dynamics and Earthquake Engineering》2004,24(1):49-67

Array measurements of microtremors at 16 sites in the city of Thessaloniki were performed to estimate the V_s velocity of soil formations for site effect analysis. The spatial autocorrelation method was used to determine phase velocity dispersion curves in the frequency range from 0.8–1.5 to 6–7 Hz. A Rayleigh wave inversion technique (stochastic method) was subsequently applied to determine the Vs profiles at all the examined sites. The determination of V_s profiles reached a depth of 320 m. Comparisons with V_s values from cross-hole tests at the same sites proved the reliability of the SPAC method. The accuracy of the V_s profiles, the ability to reach large penetration depths in densely populated urban areas and its low cost compared to conventional geophysical prospecting, make Mictrotremor Exploration Method very attractive and useful for microzonation and site effects studies. An example of its application for the site characterization in Thessaloniki is presented herein.  相似文献   

Optimizing a layered and laterally constrained 2D inversion of resistivity data using Broyden's update and 1D derivatives     

Anders V. Christiansen  Esben Auken   《Journal of Applied Geophysics》2004,56(4):247

Dense profile-oriented resistivity data allows for 2D and 3D inversions. However, huge amounts of data make it practically impossible to do full 2D or 3D inversions on a routine basis. Therefore, a number of approximations have been suggested over the years to speed up computations. We suggest using a combination of Broyden's update on the Jacobian matrix with derivatives calculated using a 1D formulation on a parameterized 2D model of locally 1D layered models. The approximations bring down the effective number of 2D forward responses to a minimum, which again gives us the ability to invert very large sections. Broyden's update is not as useful with a parameterized problem as is the case with a smooth minimum structure problem that has been the usual application. 1D derivatives, however, seem to be very effective when initiating a full 2D solution with Broyden's update. We compare the different methods using two different kinds of data on two synthetic models and on two field examples. The most effective and reliable optimization combines 1D derivatives with a full 2D solution and Broyden's update. When using Broyden's update the Jacobian matrix needs to be reset every once in a while. We do this whenever the difference in data residual from the previous iteration is less than 5%. This combined inversion method reduces the computation time approximately a factor of 3 without losing model resolution.  相似文献   

风云2号卫星云图在短时强对流天气预报中的应用     

傅丙珊 《气象科技》2004,32(5):363-366

利用风云2号水汽通道的云图进行强对流天气的临近预警，发现每小时1次的风云2号云图对强对流天气有着重要指示作用，尤其水汽图反映了大气中上层的水汽分布，水汽区的活动、干湿区边界、暗区等都与强对流的发生发展有着密切关系，并找出了可以作为临近预警的关键指标，在2003年的几次强对流天气预报中，风云2号云图发挥了很好的作用。  相似文献   

CAPPS1和CAPPS2数值预报模式对比分析   总被引：6，自引：0，他引：6  

李雄 《气象科技》2004,32(6):414-416424

对CAPPS1模式和CAPPS2模式预报广西污染物进行了对比分析。主要对比了其污染扩散原理、气象预报模式、操作系统、运行时间、预报时效及预报效果。分析表明：CAPPS1和CAPPS2模式对各种污染物预报的相关系数均在0．44以上，两种模式预报广西空气污染都是可行的；两种模式均对SO2的预报效果最好，NO2次之，PM10相对最差；CAPPS2模式对各种污染物的预报值与实测值相关系数均比CAPPS1高，其中NO2的相关系数提高幅度最大；CAPPS2模式对NO2和PM10的预报准确率比CAPPS1偏高，而对SO2的预报准确率比CAPPS1偏低；CAPPS2预报首要污染物正确率比CAPPS1高出11个百分点，而预报首要污染物等级正确率则高出9个百分点。  相似文献   

利用敦煌辐射校正场对FY-2B静止气象卫星进行可见光通道的在轨辐射定标   总被引：12，自引：0，他引：12       下载免费PDF全文

戎志国张玉香  邱康睦胡秀清　张立军 《应用气象学报》2004,15(3):266-272

FY-2B由于杂散光的影响，其可见光通道的发射前定标存在较大误差。利用敦煌戈壁滩辐射校正场可进行FY-2B可见光通道的在轨绝对定标。由于FY-2B对于敦煌场区的卫星天顶角接近50°，需要进行场地的方向特性BRDF修正。2002年7月对FY-2B进行了场地地表反射率、大气消光、探空等项同步测量，并对场地的方向特性进行了测量。资料处理结果表明，FY-2B可见光通道杂散光可影响定标精度达20%。长期监视表明FY-2B可见光通道探测器输出十分稳定。该文将4个可见光通道探测器场地定标得出的定标查找表列出，供用户参考使用。  相似文献   

6-硝基-2-苯并噻唑重氮氨基偶氮苯与铜的显色反应及其应用   总被引：10，自引：0，他引：10  

张春牛  杨明华  郑云法  王智敏 《岩矿测试》2004,23(1):77-78

在pH10～12的Na2B4O7-NaOH缓冲溶液中,TritonX-100表面活性剂存在下,6-硝基-2-苯并噻唑重氮氨基偶氮苯与铜发生显色反应,生成2∶1的深红色配合物。配合物的最大吸收峰位于535nm处,表观摩尔吸光系数1.42×105L·mol-1·cm-1。Cu2+的浓度在0～400μg/L符合比尔定律。用拟定方法测定铝合金及铜矿石样品中的微量铜,结果与原子吸收法结果相符,6次测定的RSD<3%。  相似文献