288.15 K-323.15 K下氯化锂、硫酸锂溶液的密度及摩尔体积研究          下载免费PDF全文

马修臻  胡斌  高丹丹  李武  董亚萍 《盐湖研究》2017,25(4):32-32

用振荡管密度计测定了常压下,温度在288.15-323.15 K范围内不同离子强度的LiCl和 Li₂SO₄溶液的密度,计算了两种锂盐在不同温度下的表观摩尔体积,溶液的浓度范围分别为(0.1~18.9) mol·kg-1及(0.03~3.0)mol·kg-1。用Pitzer离子相互作用模型拟合了LiCl和Li₂SO₄不同温度下的的Pitzer单电解质体积参数,模型的计算值与实验值相吻合良好。  相似文献   

氯与硫酸根比值对硫酸盐渍土工程性质影响的研究   总被引：8，自引：0，他引：8  

杨丽英  李斌 《冰川冻土》1997,19(1):84-89

对含氯化钠硫酸盐渍土的盐胀量，液限，塑限进行了试验分析，提出了不同硫酸钠含量水平下氯与硫酸根比值，即Ｃｌ＾－／ＳＯ４＾２－与盐胀率，Ｃｌ＾－／ＳＯ４＾２－与液限、塑限之间的计算公式，对从Ｃｌ＾－／ＳＯ４＾２－角度评判盐渍土的工程性质具有一定参考意义。  相似文献   

德国联邦地学研究中心与全德天然气水合物研究     

许红 《海洋地质前沿》2006,22(10):20-21

简要介绍了德国联邦地学研究中心及全德天然气水合物调查研究现状与成果,特别是对“太阳号”在“水合物海脊”和SO177-1航次在中国南海等的科学调查及研究成果进行了介绍。  相似文献   

硫酸-抗坏血酸-氯化钠体系示波极谱法测定矿石中的锡     

王丽莉  刘忠胜  高明姬  尹春梅 《吉林地质》2010,29(4):103-105

示波极谱法测定矿石中锡的方法试验,底液的组成为硫酸-抗坏血酸-氯化钠,于-430 mV处测量锡的峰电流,对试液中锡的质量浓度在0.25～7.5 mg/L之间与峰电流呈线性关系。锡的相对标准偏差分别为0.5%～6.91%,检出限为0.25 mg/L。  相似文献   

Variation of Cl and SO₃ Contents of Microphenocrystic Apatite in Intermediate to Silicic Igneous Rocks of Cenozoic Japanese Island Arcs: Implications for Porphyry Cu Metallogenesis in the Western Pacific Island Arcs     

Akira Imai 《Resource Geology》2004,54(3):357-372

Abstract. Determinations of SO₃ and Cl contents of igneous accessory apatite were carried out on Late Cenozoic intermediate to silicic intrusive and volcanic rocks in the Japanese island arcs of the western Pacific rim including the southwestern Kuril arc (eastern Hokkaido), Northeast Japan arc (southwestern Hokkaido through northeastern Honshu to central Honshu), Izu‐Bonin arc, Kyushu‐Palau ridge, Southwest Japan arc (northern Kyushu) and northern Ryukyu arc (southern Kyushu). These were compared to those from the Western Luzon arc, Philippines, to better understand the metallogenesis of porphyry Cu deposits in the western Pacific island arcs. In addition, SO₃ and Cl contents of accessory apatite in the Cretaceous magnetite‐series granitic rocks in the Kitakami belt (northeastern Honshu) and the Miocene ilmenite‐series granitic rocks in the Outer Zone of Southwest Japan (southern Kyushu) were also examined. Microphenocrystic apatites in shallow intrusions associated with porphyry Cu deposits in the Western Luzon arc contain >0.1 wt% S as SO₃. Such high SO₃ contents of microphenocrystic apatite are a common characteristic of hydrous mag‐matism in the Western Luzon arc, from 15 Ma old tonalitic plutonic rocks of the Luzon Central Cordillera to present‐day volcanism at Mount Pinatubo. The accessory apatite in intrusive rocks associated with porphyry Cu deposits, especially those at the Santo Tomas II deposit, show significantly high Cl contents (>2 wt%). The SO₃ contents of microphenocrystic apatite in most of the hydrous silicic rocks along the volcanic front, in andesites related to native sulfur deposits, and in Miocene and younger shallow granitic intrusions in northeastern Honshu, are generally <0.1 wt%. On the other hand, the SO₃ contents of apatite in such rocks from eastern Hokkaido, southwestern Hokkaido, Izu, northern Kyushu and southern Kyushu are similar to those from the Western Luzon arc. The SO₃ contents of accessory apatite in the Cretaceous magnetite‐series granitic rocks in the Kitakami belt are variable, whereas those of the Miocene ilmenite‐series granitic rocks in southern Kyushu are extremely low. The Cl contents of accessory apatite in some rocks of the Northeast Japan arc, Izu‐Bonin arc and Southwest Japan arc are significantly high. In terms of the Cl and SO₃ contents of microphenocrystic apatite, Cenozoic Japanese arc magmatism show similarities with arc magmatism associated elsewhere with porphyry Cu mineralization, except for the most of northeastern Honshu of the Northeast Japan arc. Apatite commonly occurs as inclusions in other phenocrystic phases. Thus the variation in SO₃ contents of apatite is a feature of early stage magmatic differentiation. The SO₃ contents of microphenocrystic apatite are considered to reflect the redox state of the magma source region or fluids encountered during magma generation.  相似文献   

太原市大气SO2浓度分布及污染趋势     

曹玲娴  李伟 《华北地质矿产杂志》1996,11(2):213-215

根据太原市１９８９年至１９９２年的大气例行监测数据。分析了６个监测点的ＳＯ２点日均值的频率分布特征，并比较了各监测点的ＳＯ２污染水平及污染趋趋势。  相似文献   

山区复杂地形上区域大气质量模式的试验研究   总被引：3，自引：3，他引：3  

阎宇平  陈长和 《高原气象》1997,16(2):130-139

由于复杂地形上的气流多变，所以，进行区域空气质量模拟是比较困难的。根据大气污染总量控制和环境规划的需要，发展了一种可适用于山谷城市的大气质量模式，该模式的主要特点；（１）采用目前尚少的复杂地形上的三维边界层模式作为大气扩散模式所需城三维边界层要素场；（２）用复杂地形上的三维以模式和斯扩散氏架源（包括面源）和主架源所造在的地面ＳＯ２浓度，然后将两者的模拟浓度在相应网各上叠加。验证结果表明，该混合模式  相似文献   

The mass estimation of volatile emission during 1199-1200 AD eruption of Baitoushan volcano and its significance   总被引：2，自引：1，他引：2  

郭正府  刘嘉麒  隋淑珍  刘强  贺怀宇  倪云燕 《中国科学D辑(英文版)》2002,45(6)

On the basis of the study of volcanic products during 1199-1200AD eruption of Baitou Mountain (Baitoushan), the released volatile content was estimated by comparing Cl, F, S, H2O concentrations of undegassed glass inclusions with those of degassed matrix glasses. The calculations show that volatile yields, released from the melt, are 109.88×106 ton of HCl, 196.80×106 ton of HF, 1477.84×106 ton of H2O, 23.14×106 ton of SO2, which could have formed 35.43×106 ton of H2SO4 aerosol in the atmosphere. They could have substantial effect on paleoclimate and paleo-environment.  相似文献   

黄河流域空气污染的空间格局演化及影响因素   总被引：3，自引：2，他引：1  

滕堂伟  谌丹华  胡森林 《地理科学》2021,41(10):1852-1861

基于2008—2017年黄河流域工业SO₂和PM_2.5两类典型空气污染物数据,首先刻画了两者的空间演化格局,并运用空间面板杜宾模型（SPDM）从直接效应和间接效应两方面对两者的影响因素进行对比分析。结果表明：① 工业SO₂和PM_2.5污染均存在显著的空间集聚特征,从东南至西北方向呈现梯度递减趋势;二者在城市尺度均存在显著的正向空间关联性,但PM_2.5污染的空间关联性比工业SO₂更强;② 2008—2017年,工业SO₂和PM_2.5污染有所缓解,其中工业SO₂排放强度迅速下降;而PM_2.5质量浓度下降相对缓慢,仍是黄河流域主要的空气污染源。③ 产业结构、技术创新、能源效率、人口规模、经济发展、工业规模等是影响黄河流域空气污染的主要因素,但PM_2.5的影响因素更加复杂多样化。其中,技术创新能力和经济发展水平的提升虽然在研究期内加剧了本地工业SO₂污染的排放强度,但却能缓解周边城市的工业SO₂和PM_2.5污染;工业规模的扩大会加剧本地和邻近城市的PM_2.5污染。  相似文献   

宣城市大气污染与气象分析     

吴有训  彭慕平  吴晓东  王克强 《气象科学》2007,27(Z1):152-155

用 2003-2005 年宣城市环境保护监测中心PM10、NO2、SO2自动监测资料、宣城市气象台地面观测资料和美国NCEP/NCAR全球日平均再分析资料,分析了宣城市区空气污染浓度、典型大气持续高污染过程形成的气象条件.结果表明,PM10、SO2平均浓度从春季到冬季逐渐增大,NO2平均浓度冬季明显偏小;PM10、NO2、SO2浓度存在准12 d周期变化.典型大气持续高污染过程的环流形势是500 hPa沿海为低槽,槽后为弱冷平流区;地面为宽广的均压区.1000～925 hPa主要为下沉气流;且上层增温明显大于低层,气层稳定度增大,这两种因素均使污染物扩散受阻;1000～700 hPa各层风力微弱,不能将污染物输送至远处,造成污染大气长时间维持.  相似文献