The crystal chemistry of lithium and Fe3+ in synthetic orthopyroxene     

Fernando Cámara  Gianluca Iezzi  Massimo Tiepolo  Roberta Oberti 《Physics and Chemistry of Minerals》2006,33(7):475-483

Lithian ferrian enstatite with Li₂O = 1.39 wt% and Fe₂O₃ 7.54 wt% was synthesised in the (MgO–Li₂O–FeO–SiO₂–H₂O) system at P = 0.3 GPa, T = 1,000°C, fO₂ = +2 Pbca, and a = 18.2113(7), b = 8.8172(3), c = 5.2050(2) Å, V = 835.79(9) Å³. The composition of the orthopyroxene was determined combining EMP, LA-ICP-MS and single-crystal XRD analysis, yielding the unit formula ^M2(Mg_0.59Fe _0.21 ²⁺ Li_0.20) ^M1(Mg_0.74Fe _0.20 ³⁺ Fe _0.06 ²⁺ ) Si₂O₆. Structure refinements done on crystals obtained from synthesis runs with variable Mg-content show that the orthopyroxene is virtually constant in composition and hence in structure, whereas coexisting clinopyroxenes occurring both as individual grains or thin rims around the orthopyroxene crystals have variable amounts of Li, Fe³⁺ and Mg contents. Structure refinement shows that Li is ordered at the M2 site and Fe³⁺ is ordered at the M1 site of the orthopyroxene, whereas Mg (and Fe²⁺) distributes over both octahedral sites. The main geometrical variations observed for Li-rich samples are actually due to the presence of Fe³⁺, which affects significantly the geometry of the M1 site; changes in the geometry of the M2 site due to the lower coordination of Li are likely to affect both the degree and the kinetics of the non-convergent Fe²⁺-Mg ordering process in octahedral sites.  相似文献   

kSZ from patchy reionization: The view from the simulations     

Ilian T. Iliev  Ue-Li Pen  J. Richard Bond  Garrelt Mellema  Paul R. Shapiro   《New Astronomy Reviews》2006,50(11-12):909

We present the first calculation of the kinetic Sunyaev–Zel’dovich (kSZ) effect due to the inhomogeneus reionization of the universe based on detailed large-scale radiative transfer simulations of reionization. The resulting sky power spectra peak at ℓ = 2000–8000 with maximum values of [ℓ(ℓ + 1)C_ℓ/(2π)]_max  4–7 × 10 ⁻¹³. The scale roughly corresponds to the typical ionized bubble sizes observed in our simulations, of 5–20 Mpc. The kSZ anisotropy signal from reionization dominates the primary CMB signal above ℓ = 3000. At large-scales the patchy kSZ signal depends only on the source efficiencies. It is higher when sources are more efficient at producing ionizing photons, since such sources produce larger ionized regions, on average, than less efficient sources. The introduction of sub-grid gas clumping in the radiative transfer simulations produce significantly more power at small-scales, but has little effect at large-scales. The patchy reionization kSZ signal is dominated by the post-reionization signal from fully-ionized gas, but the two contributions are of similar order at scales ℓ  3000 − 10⁴, indicating that the kSZ anisotropies from reionization are an important component of the total kSZ signal at these scales.  相似文献   

孟加拉湾风暴Mala结构及对云南强降水的影响   总被引：1，自引：0，他引：1  

金少华  杨明  李华宏  艾永智 《气象科学》2010,30(1):74-81

利用实时观测资料和NCEP(1°×1°)的6 h再分析资料,对2006年春季发生在孟加拉湾的超强风暴Mala的移动路径、强度变化、环流背景以及风暴温湿场、动力场特征等进行分析。结果表明:Mala在阿拉伯副热带高压和西太平洋副热带高压两高间辐合区生成、加强,并沿西太平洋副热带高压西侧西南或偏南气流移动。风暴发展、成熟到消亡,湿度对风暴的作用比温度明显;动力场结构除具有台风结构的一般特征外,在风暴发展期,中心附近散度场从低层到高层为辐合和辐散交替结构,表明风暴内部高空辐散抽吸作用对于风暴发展起到重要作用。登陆后风暴低压内自身能量和水汽与冷空气共同作用下,在冷暖交汇处出现强烈的上升运动和激发出中尺度辐合线是造成云南强降水主要原因。  相似文献   

Spatial and short-term temporal variations in Uranus’ near-infrared spectrum     

J.W. Norwood  N.J. Chanover 《Icarus》2009,203(1):331-335

We obtained near-infrared spectra of Uranus at NASA’s Infrared Telescope Facility during the planet’s September 2006 and September 2007 oppositions. Ratios between the spectra indicate that in 2006, Uranus’ methane windows appeared much brighter in the south than in the north, and that between 2006 and 2007 they grew dimmer in the south and brighter in the north; we interpret these variations to be primarily caused by changing brightness in Uranus’ upper cloud layer near 2 bars.  相似文献   

文章已录用：阴山晚中生代板内造山特征及其动力机制-以内蒙古大青山为例     

杜菊民 《地质学报》2009,83(7):910-922

内蒙古大青山属我国典型的板内造山带阴山山脉的南部山系,其西段缺少大型低角度推覆构造及大型深成岩对前期演化历史的干扰,是研究阴山板内造山特点及过程的理想区域。通过对大青山西段的构造进行几何学和运动学的分析表明,古老结晶基底以逆冲推覆及基底褶皱的形式广泛的巻入中生代构造变形,以及先存构造样式的广泛复活并对后期地层沉积和断层发育的控制作用是内蒙古大青山地区中生代板内造山的两个基本特征。这些变形特征反映了阴山带板内造山过程中,是以结晶基底为受力层,并控制上覆盖层进行构造变形的,进而表明板内造山主要是由水平挤压应力造成的。结合研究区构造变形特点及邻区中生代构造地质情况的分析认为,晚侏罗世时期之所以在阴山带形成强烈的板内造山运动,是由其北部西伯利亚板块与蒙古褶皱带碰撞产生的板缘应力的远程传递,以及其南侧强硬的鄂尔多斯地块的阻挡共同作用而形成的。  相似文献   

Ab initio quantum mechanical study of γ-AlOOH boehmite: structure and vibrational spectrum     

Yves Noel  Raffaella Demichelis  Fabien Pascale  Piero Ugliengo  Roberto Orlando  Roberto Dovesi 《Physics and Chemistry of Minerals》2009,36(1):47-59

The structure and vibrational spectrum of boehmite have been investigated at the quantum-mechanical level with the CRYSTAL code, using a Gaussian-type basis set and the B3LYP Hamiltonian. Three space groups are considered in this study: Cmcm, Cmc2₁, P2₁/c. Cmcm turns out to correspond to a transition state, whereas Cmc2₁ and P2₁/c are minimum energy structures. The difference among them is the position of H atoms only, the Al-O frame being essentially the same. Harmonic frequencies at the Γ point have been computed. The comparison between calculated and experimental frequencies shows a good agreement for the Al-O part of the spectrum (under 790 cm⁻¹). For the Al-OH bending modes (800–1,300 cm⁻¹) an absolute differences of 50–100 cm⁻¹ is observed; for the OH stretching modes (3,200–3,500 cm⁻¹) it increases to 120–200 cm⁻¹: anharmonicity is large because OH groups are involved in strong hydrogen bonds.  相似文献   

北京西山煤田滑脱构造的遥感研究     

夏炎  王文侠  张大顺 《国土资源遥感》1995,6(4):26-31

本文利用多种遥感资料提供的大量的新的构造信息,对北京西山煤田已有的地质认识和成果进行了重要补充和修改,划分出推覆型和滑型两种基本类型的滑脱构造,并详细研究了各个滑脱构造系统的影像特征、展布规律、几何形态、成因机制、演化历史以及控煤作用。  相似文献   

略阳县农居房屋抗震现状调查与评价研究     

郭光玲  郭瑞  徐乾 《震灾防御技术》2021,16(3):492-500

为精准识别贫困山区农居房屋结构现状完好程度,本文开展略阳县境内41894栋农居房屋抗震现状实地调查,搜集整理域内孕灾环境和致灾因子强度,统计分析域内各行政镇（办）经济水平、农居房屋抗震结构类型和震害等级,预测震害矩阵,计算平均震害指数,并评价抗震能力。研究结果表明:域内农居房屋抗震结构类型包括土木结构、砖木结构和砖混结构;域内农居房屋在VI度地震作用下基本完好的比例为74.04%,在VII度地震作用下发生轻微破坏以下震害等级的比例为83.45%,在VIII度地震作用下发生中等破坏以下震害等级的比例为85.46%;域内农居房屋在地震烈度为VI、VII、VIII、IX、X度时的平均震害指数分别为0.13、0.23、0.32、0.49、0.71,抗震性能较差,不满足“小震不坏、中震可修、大震不倒”的抗震设防目标。  相似文献   

油气田开发中油气藏地质成因分析          下载免费PDF全文

陈欢庆  胡海燕  吴洪彪  曹晨 《地质科学》2019,(1):192-212

本文从油气藏地质成因分析的基础资料入手,总结该项研究的主要内容包括:构造、储层和油气水分布特征等3方面.结合自身科研实践,认为油气藏地质成因分析方法主要包括:野外露头和现代沉积考察、岩心观察描述、显微镜下薄片观察鉴定、地球物理解释预测、地质统计学分析、分析测试、各种物理模拟和数值模拟、油气藏动态监测和生产动态等,并阐述了不同研究方法的优缺点.目前油气藏地质成因分析存在的主要问题包括:对油气藏地质成因分析重视程度不够、研究方法偏定性、地质成因分析和油气藏表征结合不紧密、油气藏表征精度制约了地质成因分析的准确度、油气藏地质成因分析综合性不强、特殊类型油气藏地质成因分析还存在诸多难题等.本文指出了该研究未来发展方向.主要包括:依靠油气藏地质成因分析解决油气田开发中的难题、通过各种模拟方法提高油气藏地质成因分析定量化水平、加强地质成因分析以提高油气藏表征水平、利用油气藏表征促进地质成因分析进步、拓展油气藏地质成因分析在油气田开发中应用的领域、特殊类型油气藏地质成因分析等.  相似文献   

葡萄石的热膨胀性与压缩性及其地质意义     

秦善  顾婷婷  巫翔 《岩石学报》2019,35(1):146-152

利用同步辐射X射线衍射及拉曼光谱技术对葡萄石分别进行了原位高温及原位高压实验。原位高温实验结果表明葡萄石的热膨胀系数为K=1. 77(3)×10~(-5)K~(-1),轴向热膨胀系数具有各向异性(α_aα_bα_c),葡萄石在1073K时开始发生脱水反应,分解为钙长石及硅灰石。原位高压X射线衍射实验结果表明,在大于12. 4GPa时,葡萄石的晶胞参数发生不连续变化,可能发生了相变;在24. 0GPa左右,葡萄石发生不可逆的非晶化转变。原位高压拉曼光谱表明,葡萄石在12. 6GPa左右发生相变,这一相变很可能与其[(Si,Al)O_4]四面体中的Si发生有序排列有关。结合葡萄石的热膨胀性及压缩性,我们确定了葡萄石在高温高压下的稳定范围,这一结果对认识上地幔中含水矿物的状态以及地幔中水的来源有重要意义。  相似文献