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21.
文章对泸定海子坪昔格达组重新进行了详细的古地磁测试,结果显示昔格达组发育时代为4.2~2.6MaB.P.,地质时代属上新世中、晚期,与前人的研究结果一致。泸定海子坪剖面是目前所知的记录昔格达古湖沉积起始年代最早的剖面。泸定海子坪剖面记录了5个大的从粗→细的沉积旋回,15个沉积阶段。沉积物中值粒径的值直接指示了各旋回的沉积阶段,值小,水动力较强,为动荡的沉积环境;值大,水动力较弱,为稳定的沉积环境。另外,沉积记录显示在约2.8MaB.P.青藏高原的强烈隆升就已开始,昔格达古湖为过水湖;至2.6MaB.P.,昔格达古湖完全消失,与黄土高原风尘沉积环境由红粘土堆积转变为黄土堆积的显著的改变相一致。海子坪剖面TOC高值段,沉积物的值也较大,沉积物为粘土、粉砂质粘土沉积;TOC低值段,沉积物的值也较小,沉积物为中、粗砂沉积,表明昔格达古湖沉积物有机质含量主要受岩性控制。 相似文献
22.
舞阳盆地是一个早第三纪的陆相拗陷。在核桃园组沉积了碎屑和蒸发岩。为了重建沉积环境,研究了该盆地WK1井1222—1253m及1401—1405m段岩心。它们属核桃园组,由几套沉积韵律组成。硬石膏泥岩代表含盐泥坪环境,石盐岩代表盐湖环境。该类泥岩发育泥裂。WK1井内陆沙布哈沉积有机质的含量和类型变化大。在泥裂泥岩中,总有机碳低到0.24—0.34%,有机质多为Ⅲ型,纹层状泥岩的有机碳高到2.52—3.10%,有机质多为Ⅱ型。这类内陆沙布哈岩石有机质的丰度明显受沉积环境控制。该盆地WK1井内陆沙布哈沉积具有中等生油潜力。 相似文献
23.
ZHONG Ningning Lu Shuangfang HUANG ZHILONG Zhang Yousheng XUE Haitao PAN Changchun 《中国科学D辑(英文版)》2004,47(Z2)
Through geological observation, simulation in laboratory and numerical modeling, the factors that control the changes in total organic content (TOC) of source rock have been studied. When the formula DTOC=(TOC0-TOC)/TOC0 (original organic carbon content in the rock) is used to measure the TOC (total organic carbon content) changes in the source rock through geological time, the degrees and directions of such changes are determined by losses and relative amounts both of organic and inorganic matter in the source rock. The DTOC equation, which is used to calculate the loss rate in the process of maturation for the source rock, is therefore obtained by analyzing the mass balance relations. For a certain type of source rock with a certain maturation history, the changes of its TOC respond only to the rates of hydrocarbon generation and expulsion. In actual cases of geological entities, DTOC generally ranges from -0.05 to 0.2, while the calculated reconversion coefficient (k) for organic carbon content remains between 0.90 and 1.25. Only in an ideal situation where there are extremely high rates of hydrocarbon generation and expulsion can the DTOC value experience significant changes, with k reaching up to 2.5. It is concluded, therefore, that the criterion for carbonates source rock assessment, based on reconverting the TOC to the value of its original state, may have overestimated the course of the "carbon-reduction", which is likely in many cases to make a poor source rock sound better. 相似文献
24.
In this paper, calculations have been performed about gas quantity of generation, adsorption, dissolving in oil, dissolving in water, diffusion of unit area carbonate rocks at different geologic conditions in the Tarim basin. According to the material balance principle, the corresponding organic carbon content when gas started expelling from source rocks with separate phases has been worked out. We regard it as the theoretical threshold value (TOCmin) of gas source rocks under the same geologic condition. Based on the simulating calculation, a fact has been discovered that TOCmin decreases with the increasing source rocks thickness, decreases at the beginning and then increases with the increasing maturity and decreases with the better type of organic matter. TOCmin evaluation table of carbonate gas source rocks in the Tarim basin has been established. Investigations indicate that the TOCmin of carbonate gas source rocks varies greatly with the differences of geologic conditions, and gas source rocks cannot be evaluated with a unified TOC threshold value. And we also establish a preliminary evaluation table of TOC industrial threshold value, TOCgy, of carbonate gas source rocks in the Tarim basin. 相似文献
25.
Arctic glaciers are rapidly responding to global warming by releasing organic carbon (OC) to downstream ecosystems. The glacier surface is arguably the most biologically active and biodiverse glacial habitat and therefore the site of important OC transformation and storage, although rates and magnitudes are poorly constrained. In this paper, we present measurements of OC fluxes associated with atmospheric deposition, ice melt, biological growth, fluvial transport and storage (in superimposed ice and cryoconite debris) for a supraglacial catchment on Foxfonna glacier, Svalbard (Norway), across two consecutive years. We found that in general atmospheric OC input (averaging 0.63 ± 0.25 Mg a-1 total organic carbon, i.e. TOC, and 0.40 ± 0.22 Mg a-1 dissolved organic carbon, i.e. DOC) exceeded fluvial OC export (0.46 ± 0.04 Mg a-1 TOC and 0.36 ± 0.03 Mg a-1 DOC). Early in the summer, OC was mobilised in snowmelt but its release was delayed by temporary storage in superimposed ice on the glacier surface. This delayed the export of 28.5% of the TOC in runoff. Biological production in cryoconite deposits was a negligible potential source of OC to runoff, while englacial ice melt was far more important on account of the glacier's negative ice mass balance (–0.89 and –0.42 m a-1 in 2011 and 2012, respectively). However, construction of a detailed OC budget using these fluxes shows an excess of inputs over outputs, resulting in a net retention of OC on the glacier surface at a rate that would require c. 3 years to account for the OC stored as cryoconite debris. © 2018 John Wiley & Sons, Ltd. 相似文献
26.
可可西里库赛湖揭示的青藏高原北部近4000年来的干湿变化 总被引:3,自引:0,他引:3
通过青藏高原北部可可西里库赛湖KS-2006孔(深637cm)沉积岩芯总有机碳、总氮含量及沉积物粒度变化的研究,恢复了该地区近4000年来的干湿变化历史.结果表明,该地区近4000年来经历了显著的干湿变化,干旱时段出现在3900-3590cal aBP、3320-2630cal aBP、1720-1420cal aBP及1100-840cal aBP期间:湿润时段出现在3590-3320cal aBP、2630-1720cal aBP、1420-1100cal aBP以及840cal aBP之后小冰期有效降水升高的相对湿润时期.区域对比分析表明库赛湖地区近4000年来的干湿变化受亚洲季风影响;同时,该地区存在明显的中世纪暖期及小冰期的三次降温事件记录. 相似文献
27.
Polycyclic aromatic hydrocarbons (PAH) were measured in sediment cores from 13 locations in South-Western Barents Sea as part of a detailed study of the Norwegian seabed under the MAREANO program. The generally low PAH levels found, an average around 200 ng g−1 dry weight for sum PAH, indicate low inputs of petroleum hydrocarbons to the marine environment in the area. Differences in PAH composition and various PAH ratios indicate a natural, mostly petrogenic origin of PAH in sediments from the open sea locations, while the fjord locations show higher pyrogenic PAH contents with an increase towards upper sediment layers, indicating low inputs from human activities. Petrogenic PAH levels increase in deeper sediments at open sea locations, also when normalised to total organic carbon (TOC) contents, suggesting natural leakages of oil-related hydrocarbons in the area. 相似文献
28.
大亚湾海水中总有机碳的时空分布及其影响因素 总被引:4,自引:1,他引:3
于2006—2007年夏季、冬季、春季和秋季对大亚湾总有机碳(TOC)进行采样调查,分析了TOC的季节变化特征和空间分布特征,并讨论了TOC与盐度、叶绿素a及石油类等环境因子之间的关系。2006—2007年TOC的浓度范围在1.30~6.30 mg/dm3,平均值为2.78 mg/dm3,TOC的浓度从大到小的趋势是春季、夏季、秋季、冬季。TOC垂直分布趋势不明显,春季和秋季垂直分布比较均匀,且中层TOC浓度比较高;而夏季、冬季垂直分布不够均匀。春季TOC平面分布比较均匀,在大辣甲的西北部有高值,而夏季、秋季、冬季的TOC在大辣甲的西北部都呈现低值;夏季的TOC分布呈现西高东低,自小湾内向小湾外递减的特征;秋季的TOC分布呈现出东西高,中部低,近岸大于离岸的特征;冬季的TOC分布呈现西高东低,西部海域分布线比较密集的特征。研究表明,大亚湾TOC与叶绿素a、石油类显著正相关,与盐度负相关,但不显著。大亚湾TOC浓度、时空分布与季节性径流、季风、水动力、生物地球化学、生物等环境因子密切相关,特别是受到季节性河流径流输入、浮游植物、石油类的影响较大。 相似文献
29.
We have conducted elemental, isotopic, and Rock-Eval analyses of Cenomanian–Santonian sediment samples from ODP Site 1138 in the southern Indian Ocean to assess the origin and thermal maturity of organic matter in mid-Cretaceous black shales found at this high-latitude location. Total organic carbon (TOC) concentrations range between 1 and 20 wt% in black to medium-gray sediments deposited around the Cenomanian–Turonian boundary. Results of Rock-Eval pyrolysis indicate that the organic matter is algal Type II material that has experienced modest alteration. Important contributions of nitrogen-fixing bacteria to the amplified production of organic matter implied by the high TOC concentrations is recorded in δ15N values between −5 and 1‰, and the existence of a near-surface intensified oxygen minimum zone that favored organic carbon preservation is implied by TOC/TN ratios between 20 and 40. In contrast to the marine nature of the organic matter in the Cenomanian–Turonian boundary section, deeper sediments at Site 1138 contain evidence of contributions land-derived organic matter that implies the former presence of forests on the Kerguelen Plateau until the earliest Cenomanian. 相似文献
30.
On the basis of the results of hydropyrolysis simulations for about 90 different types of immature to mature source rocks
selected from about 5 000 marine source rocks in China, along with the natural thermal evolution profiles, the following conclusions
were obtained. (1) Total organic carbon (TOC) content of excellent marine source rocks does not change obviously when Ro < 0.8% or Ro > 1.3%, and the residual TOC content is decreasing gradually with the maturity increase at 0.8% < Ro < 1.3%. (2) At the high-post mature stage (Ro > 1.3%), the decreased maximums of residual TOC content for the kerogen of sapropel (I), II1, and II are usually 40%, 32% and 24%, respectively, and their TOC restitution coefficient is, respectively, 1.68, 1.48 and
1.32. (3) Both the TOC decreasing amplitude and the restitution coefficient decrease gradually with the decrease of TOC content
for the source rocks with low organic matter abundance (usually 0.3% < TOC < 1.0%). The TOC restitution coefficients are,
respectively, 1.20 and 1.0, when 0.3% < TOC < 0.5% and TOC < 0.3%. (4) TOCres of solid bitumen and shale with high organic matter abundance (TOC > 30%) also require no restitution at the high mature
stage. Such kind of TOC restitution is further supported by the coincidence of the decrease of residual TOC with the decreasing
of S1 + S2 and the increasing of hydrocarbon quantity during the experimental simulation of hydrocarbon generation and expulsion for
marine source rocks (0.3% < TOC < 30%) in natural thermal evolution profiles.
__________
Translated from Earth Science—Journal of China University of Geosciences, 2007, 32(6): 853–860 [译自: 地球科学—中国地质大学学报] 相似文献